CAS: 696-41-3; 3-Iodobenzaldehyde

上下游产品

CAS号57455-06-8 3-碘苄醇 | CAS号100-52-7 苯甲醛 | CAS号625-95-6 3-甲碘苯 | CAS号626-00-6 1,3-二碘苯 | CAS号68-12-2 N,N-二甲基甲酰胺 | CAS号884507-44-2 1-(3-碘苄基)吡咯烷 | CAS号696-40-2 3-碘苄胺 | CAS号1711-10-0 3-碘苯甲酰氯 | CAS号10602-07-0 (3-乙炔基苯基)甲醇 | CAS号454-89-7 间三氟甲基苯甲醛 | CAS号201851-03-8 Benzaldehyde, 3... | CAS号57455-06-8 3-碘苄醇 | CAS号618-51-9 间碘苯甲酸 | CAS号77123-55-8 3-[2-(三甲基甲硅烷基)乙... | CAS号68034-75-3 3-(3-碘苯基)丙酸 | CAS号77123-56-9 3-炔基苯甲醛 | CAS号1305320-66-4 5-(4-Chlorophen... | CAS号126485-58-3 3-(3-甲氧基苯基)苯甲醛

苯甲醛置于sodium Periodate,硫酸,碘体系中,化学反应 1.0H,以63%的收率获得产物3-碘苯甲醛
参考文献:I2/naio4 和 Ki/naio4 碘化体系对浓硫酸中失活芳烃的氧化碘化
标题:I2/naio4 和 Ki/naio4 碘化体系对浓硫酸中失活芳烃的氧化碘化
摘要:用强亲电 I + 试剂对失活的芳烃进行单碘化或二碘化,这些试剂由 Naio 4 和 I 2 或 Ki 在浓 H 2 So 4 中制备(至少 95% 重量).通常使用稍微过量的深棕色碘化溶液(1.1/1.5 当量,对于硝基苯需要两个当量).碘化在 25-30 oc 下进行,反应时间为 1-2 小时,使用芳香族碘化的"直接"或"反向"方法以 31-91% 的优化产率得到单碘化或二碘化纯产物.
DOI:10.1055/s-2006-926374

专利信息

专利号:US-5861532-A
优先权日:1997-03-04
标 题:Solid-phase synthesis of N-alkyl amides
发明人：BROWN EDWARD G; NUSS JOHN M
权利人:CHIRON CORP
摘要:Methods for solid phase synthesis of N-alkyl amides comprise reductive amination of carbonyl compounds using a reducing agent and an amine-containing linker bound to a solid support. The methods afford high yields of linker-bound, monoalkylated amines, and subsequent coupling with acid derivatives provide derivatized N-substituted amides in excellent yields after cleavage from the solid-phase. Compositions useful in solid phase synthesis are also described.

专利号:US-2018208775-A1
优先权日:2014-06-23
标 题:New aromatic macrocyclic metal complex dyes and the synthesis thereof with active nano metal powders
发明人：OLGUN UGURSOY; YILDIZ SALIH ZEKI
权利人:OLGUN UGURSOY; YILDIZ SALIH ZEKI
摘要:The present invention relates to a new type of inorganic coordination compound dyes having advanced technology optical, electronic and medical characteristics and relates to production of these dyes by means of new synthesis methods. The present invention relates to dyes which are metal (M: Li, Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Si, Ge, Sn, Pb, Sb, Bi, Se, Te) complexes of aromatic macrocyclic compounds of the type Phtalocyanine (Pc), Naphtalocyanine (Nc), Porphyrazine (Pz), Porphyrin (Pr), sub-Phtalocyanine (subPc), sub-Naphtalocyanine (subNc), sub-Porphyrazine (subPz), sub-Porphyrine (subPr), and relates to the synthesis of these complexes and derivatives. The subject matter dyes can be used in solar cell photovoltaic (PV) panels, in OLEDS which are organic structured light emitting diodes, in polymers, in textile and in photodynamic therapy PDT applications. Moreover, industrial applications are possible which depend on strong fluorescence characteristics.

专利号:US-7109377-B2
优先权日:1996-10-16
标 题:Synthesis of combinatorial libraries of compounds reminiscent of natural products
发明人：SCHREIBER STUART L; SHAIR MATTHEW D; TAN DEREK S; FOLEY MICHAEL A; STOCKWELL BRENT R
权利人:HARVARD COLLEGE
摘要:The present invention provides complex compounds reminiscent of natural products and libraries thereof, as well as methods for their production. The inventive compounds and libraries of compounds are reminiscent of natural products in that they contain one or more stereocenters, and a high density and diversity of functionality. In general, the inventive libraries are synthesized from diversifiable scaffold structures, which are synthesized from readily available or easily synthesizable template structures. In certain embodiments, the inventive compounds and libraries are generated from diversifiable scaffolds synthesized from a shikimic acid based epoxyol template. In other embodiments, the inventive compounds and libraries are generated from diversifiable scaffolds synthesized from the pyridine-based template isonicotinamide. The present invention also provides a novel ortho-nitrobenzyl photolinker and a method for its synthesis. Furthermore, the present invention provides methods and kits for determining one or more biological activities of members of the inventive libraries. Additionally, the present invention provides pharmaceutical compositions containing one or more library members.

专利号:US-8697032-B2
优先权日:2003-05-02
标题:Prosthetic groups attached to stannyl polymer in the synthesis of radiopharmaceuticals
发明人：HUNTER DUNCAN; GAGNON M KAREN J
权利人:UNIV WESTERN ONTARIO
摘要:The present invention relates to compositions and methods for preparing radiopharmaceutical compounds in high chemical-purity and isotopic-purity. The present invention provides polymer-bound precursors to radiopharmaceutical compounds that can be converted to radiopharmaceutical compounds in one step. In a preferred embodiment, a radiopharmaceutical precursor is bound to a polymeric support via a prosthetic group comprising an alkenyl-tin bond. The radiopharmaceutical precursor is converted to a radiopharmaceutical compound in one step involving cleavage of the alkenyl-tin bond and incorporation of a radioisotope to form the radiopharmaceutical compound. Importantly, the polymeric support containing the toxic tin by-product can be easily removed from the radiopharmaceutical compound by filtration. The present invention can be used to install a large number of different radioisotopes. In a preferred embodiment, the radioisotope is 211 At, 123 I, or 131 I.

专利号:WO-0006525-A9
优先权日:1998-07-25
标题:Synthesis of combinatorial libraries of compounds reminiscent of natural products

专利号:WO-0006525-A2
优先权日:1998-07-25
标 题:Synthesis of combinatorial libraries of compounds reminiscent of natural products