tert-butoxy-chloro-silanetri-tert-butoxy-chloro-silanesodium t-butanolate(tert-butoxy)B[tris(tert-butoxy)siloxy]2water36H64O10Si3C36H64O10Si330H62N2O8Si3C30H62N2O8Si3silica gel
专利号:US-2016168283-A1 优先权日:2013-07-18 标题:Chromium(iii) silicate catalysts suitable for pe synthesis 发明人:COPÉRET CHRISTOPHE; CONLEY MATTHEW; DELLEY MURIELLE 权利人:ETH ZUERICH 摘要:Molecular precursor chromium compounds and chromium on silica catalyst precursors suitable for sure in producing chromium on silica catalysts are disclosed. The molecular precursor compounds can be chromium(II) and/or chromium(III) and/or chromium (IV) compounds wherein all ligands are easily removable, in particular ligands selected from the group consisting of anionic ligands of the type —O—CR 3 R 4 —CH—R 1 —R 2 or —O—Si—(O—CR 3 R 4 —CH—R 1 R 2 ) 3 wherein R1, R2, R3 and R4 may be the same or different and may be any group that does not affect decomposition of the ligand via elimination of beta-hydrogen from —CR 3 R 4 —CH—R 1 R 2 , amide anionic ligands of the type —N—Si—R 5 R 6 R 7 and/or —N—C—R 5 R 6 R 7 , wherein R 5 , R 6 and R 7 can be the same or different and are preferably selected from hydrogen, methyl groups, ethyl groups, n-propyl groups, iso-propyl groups, tert-butyl groups or aromatic groups; as well as coordinating solvents. These molecular precursors can be grafted to silica and—if need be—either before or after heat treatment during which the ligands are removed, oxidized to Cr(III). The chromium on silica catalyst is characterized by the absence of any organic ligands.
专利号:US-7064227-B1 优先权日:2004-12-09 标 题:Precursors for silica or metal silicate films 发明人:LEI XINJIAN; RULKENS RON 权利人:AIR PROD & CHEM 摘要:A composition selected from the group consisting of bis(tert-butoxy)(isopropoxy)silanol, bis(isopropoxy)(tert-butoxy)silanol, bis(tert-pentoxy)(isopropoxy)silanol, bis(isopropoxy)(tert-pentoxy)silanol, bis(tert-pentoxy)(tert-butoxy)silanol, bis(tert-butoxy)(tert-pentoxy)silanol and mixtures thereof; its use to form a metal or metalloid silicate layer on a substrate and the synthesis of the mixed alkoxysilanols.
专利号:US-12043893-B2 优先权日:2017-08-24 标题:Manufacturing processes to synthesize, functionalize, surface treat and/or encapsulate powders, and applications thereof 发明人:KING DAVID; DAMERON ARRELAINE; TREVEY JAMES; LICHTY PAUL; ARGO ANDREW; BOURGOIS KYLE; RAGONESI JAMES; INGHAM KYLE; JACKSON DAVID; TRACY RYON; NGUYEN NGHI; LYON ADAM; VILLAGOMEZ JOSE; CURRY GARRETT 权利人:FORGE NANO INC 摘要:A system, apparatus and method are provided for processing articles. The system includes subsystems for synthesizing, pre-treating, conducting a vapor phase coating process and post-treating articles in the form of powders and solid or porous workpieces. The apparatus permits vapor phase synthesis, treatment and deposition processes to be performed with high efficiency and at high overall throughput. The methods include converting solids, liquids or gases into gaseous and solid streams that can be separated or exchanged with or without treatment and/or coating steps, and produce optimized composite articles for specific applications.
专利号:CN-111279015-B 优先权日:2017-08-24 标 题 :Manufacturing processes for synthesis, functionalization, surface treatment and/or encapsulation of powders and their applications
专利号:CN-116284096-B 优先权日:2023-05-19 标题 :A kind of synthesis method of tri(tert-butoxy)silanol with ultra-low chloride ion content
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合成参考文献
参考文献:10.1002/aoc.380 摘要:Beckmann J, Dakternieks D, Duthie A, Larchin ML, Tiekink ERT. tert‐Butoxysilanols as model compounds for labile key intermediates of the sol–gel process: crystal and molecular structures of (t‐BuO)3SiOH and HO[(t‐BuO)2SiO]2H. Applied Organom Chemis. 2002 Dec 06;17(1):52–62. doi: 10.1002/aoc.380.