专利号:US-4422970-A 优先权日:1982-05-20 标题 :Method of synthesis of 1-dodecylazacycloheptan-2-one 发明人:RAJADHYAKSHA VITHAL J; PECK JAMES V; MINASKANIAN GEVORK 权利人:NELSON RES & DEV 摘要:In a method of synthesis of 1-substituted azacycloalkan-2-ones with primary alkyl halides and aralkyl halides as alkylating agents, the improvement comprising carrying out the N-alkylation in the presence of a phase transfer catalyst having the structural formula where X is suitable anion; and R1, R2, R3 and R4 are each alkyl or aralkyl groups having 1-18 carbon atoms, or R2, R3 and R4 can form a part of a heterocyclic ring, with the proviso that the combined total of carbon atoms is between 16 and 40.
专利号:US-4365094-A 优先权日:1979-12-28 标 题 :Process for the synthesis of tertiary phosphine oxides, and new tertiary phosphine oxides 发明人:BOILEAU SYLVIE L; N GUYEN THANH-DUNG; GAUTIER JEAN-CLAUDE C 权利人:POUDRES & EXPLOSIFS STE NALE 摘要:The invention relates to the synthesis of tertiary phosphine oxides and also to certain tertiary phosphine oxides. According to the invention, an organic phase containing a halogenomethyl derivative, a secondary phosphine oxide and a phase transfer catalyst in an organic medium is reacted with an aqueous phase containing an inorganic base. The halogenomethyl derivative can be a micromolecule or a macromolecule. The tertiary phosphine oxides are substances which are useful, in particular, in fireproofing, in hydrometallurgy and in the field of plant health.
专利号:US-4451679-A 优先权日:1982-10-21 标题 :Alcohols and aldehydes prepared from olefins and synthesis gas 发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRIGSBY JR ROBERT A; BRADER JR WALTER H 权利人:TEXACO INC 摘要:This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols and aldehydes.
专利号:US-2008214386-A1 优先权日:2004-03-01 标题:Catalyst for Cyclic Carbonate Synthesis 发明人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU 权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU 摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.
专利号:EP-0095096-A2 优先权日:1982-05-20 标题 :Improved method of synthesis of 1-substituted azacycloalkan-2-ones
专利号:CA-1169082-A 优先权日:1979-12-28 标题 :Process for the synthesis of tertiary phosphine oxides, and new tertiary phosphine oxides
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