CAS: 98064-96-1; (2R,3R,4S,5S,6R)-2-(((2R,3S,4R,5R,6R)-6-(Hexadecyloxy)-4,5-Dihydroxy-2-(Hydroxymethyl)Tetrahydro-2H-Pyran-3-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol
该化合物是一种非离子表面活性剂和胶片,其特点是长的氢离子烷基链和盐碱麦芽,通常用于生物化学和生物物理应用,特别是薄膜蛋白和其他生物分子的溶解和稳定,其结构由与麦芽糖糖单位相连的六十二(C16)脂肪酸链组成,它既能给水溶液带来非生物特性,又能形成小鼠. N-Hexcevy B-D-maltoside以其轻度和低毒性闻名,适于在各种实验室环境中使用,在有机溶剂中溶解,可形成稳定的水散落,有利于药物的交付和配方.此外,它可以在保持其功能完整性的同时促进提取薄膜蛋白,使它成为膜生物化学及相关领域的宝贵工具.
- 英文名称(2R,3R,4S,5S,6R)-2-(((2R,3S,4R,5R,6R)-6-(Hexadecyloxy)-4,5-Dihydroxy-2-(Hydroxymethyl)Tetrahydro-2H-Pyran-3-yl)Oxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol
- 中文名称十六烷基β-D-吡喃麦芽糖苷
- IUPAC名称(2R,3R,4S,5S,6R)-2-(((2R,3S,4R,5R,6R)-6-(hexadecyloxy)-4,5-dihydroxy-2-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
- 其它别名Hexadecylb-D-maltoside; Hexadecyl b-maltoside; n-Hexadecyl b-D-maltoside
- CAS编号98064-96-1
- MFCD编号:MFCD01310880
- 分子式:C28H54O11
- 分子量:566.73
- 产品CID: 2024286
- 产品分类有机原料→生命科学→糖类
- 相似结构搜索
- InChIKey: GTQCHJYVKDXMRU-YMEALESQSA-N
- GTQCHJYVKDXMRU-YMEALESQSA-N…
- 计算化学: 氢键受体数11.0氢键供体数7.0可旋转键数20.0
相似化合物
82494-08-4 82494-09-5 93911-12-7物理性质
MSDS等安全信息
合成工艺路线路线简述
- 36653-82-4 + 69-79-4 = 98064-96-1
反应条件:1.1R:Acona2.1R:Phch2Nh2,S:Thf,6 H,Rt2.2R:Acoh,Rt,Ph 6-73.1R:Dbu,S:Ch2Cl2,0°C; 7 H,0°C4.1R:Bf3-Et2O,S:Ch2Cl2,0°C; 6 H,0°C5.1R:Naome,S:Meoh,3 H,Rt,Ph 105.2Rt,Ph 7
标题:Solution Properties Of Alkyl β-D-Maltosides
作者:By Li,Zhencao Et Al
参考文献:Journal Of Surfactants And Detergents 日期:2019 卷标:22(4) 页码:731-742]
36653-82-4 + 22352-19-8 = 98064-96-1
反应条件:1.1R:Bf3-Et2O,S:Ch2Cl2,2 H,0°C; 0°C -> Rt2.1R:Naome,S:Meoh,1 H,Rt2.2R:Dowex 50W,Rt,Neutralized
标题:Hydrophobic Tail Length,Degree Of Fluorination And Headgroup Stereochemistry Are Determinants Of The Biocompatibility Of (Fluorinated) Carbohydrate Surfactants
作者:By Li,Xueshu Et Al
参考文献:Colloids And Surfaces 日期:2009 卷标:73(1) 页码:65-74]
36653-82-4 + 69-79-4 = 98064-96-1 + 793668-50-5
反应条件:1.1R:Acetyl Bromide,R:Acoh,S:H2O,0.5 H,Rt1.2R:Fecl3,S:Mecn,1 H,Rt1.3R:Kbr,S:Phme,Rt1.4R:Naome,S:Meoh,Overnight,Rt1.5R:Acoh,S:H2O,Rt
标题:Simple Preparations Of Alkyl And Cycloalkyl α-Glycosides Of Maltose,Cellobiose,And Lactose
作者:By Koto,Shinkiti Et Al
参考文献:Carbohydrate Research 日期:2004 卷标:339(14) 页码:2415-2424
1-Hexadecyl-2,3,6-Tri-O-Acetyl-4-O-(2,3,4,6-Tetra-O-Acetyl-α-D-Glucopyranosyl)-β-D-Glucopyranoside置于sodium Methylate体系中,化学反应生成 十六烷基-β-D-麦芽糖苷
参考文献:烷基β-D-麦芽糖苷的溶液性质
标题:烷基β-D-麦芽糖苷的溶液性质
摘要:烷基β-D-麦芽糖苷是一类重要的基于糖的非离子表面活性剂,已得到广泛研究.然而,仍然有必要进一步研究它们的两亲结构-表面性质关系.在本文中,我们报告了合成烷基β-D-麦芽糖苷(6A-6I,N = 6-18),包括其亲水亲脂平衡(hlb)值,水溶性,吸湿性,保湿能力,起泡能力,表面张力,热致变相行为和皮肤刺激性.它们的hlb值和水溶性随着烷基链长度的增加而降低.己基β-D-麦芽糖苷表现出最强的吸湿性和保湿能力.癸基β-D-麦芽糖苷和十二烷基β-D-麦芽糖苷具有出色的发泡能力和发泡稳定性.此外,烷基β-D-麦芽糖苷的临界胶束浓度(cmc)(6A-6G,N = 6-14)及其在cmc处的表面张力随着烷基链长度的增加而降低.最后,烷基β-D-麦芽糖苷(6A-6G)在皮肤刺激性评估中应被视为安全的表面活性剂.
DOI:10.1002/jsde.12281
海关参考信息
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专利信息
专利号:US-2012190064-A1
优先权日:2004-10-01
标题 :Feeding buffers, systems, and methods for in vitro synthesis of biomolecules
发明人：KUDLICKI WIESLAW ANTONI; KEPPETIPOLA SHIRANTHI; FLETCHER JULIA; GETBEHEAD ASHLEY ELAINE; KATZEN FEDERICO; VOZZA-BROWN LAURA
权利人:KUDLICKI WIESLAW ANTONI; KEPPETIPOLA SHIRANTHI; FLETCHER JULIA; GETBEHEAD ASHLEY ELAINE; KATZEN FEDERICO; VOZZA-BROWN LAURA; LIFE TECHNOLOGIES CORP
摘要:Compositions, methods and kits for in vitro systems for synthesis of biomolecules such as polypeptides, are provided herein. Cell extracts that provide enhanced yields of soluble proteins using in vitro protein synthesis methods are provided. The invention also includes methods for producing high yields of proteins by the addition of a feeding solution that includes amino acids and an energy source to an ongoing in vitro synthesis system. The invention also includes methods of using a high-yield in vitro synthesis system to produce large quantities of proteins with incorporated labeled amino acids for analysis by methods such as by NMR. The invention further includes vectors for enhanced production of proteins from nucleic acid templates using in vitro synthesis systems.
专利号:US-2009209032-A1
优先权日:2004-10-01
标 题 :Feeding buffers, systems, and methods for in vitro synthesis of biomolecules
专利号:WO-2006039622-A2
优先权日:2004-10-01
标 题 :Feeding buffers, systems, and methods for in vitro synthesis of biomolecules
专利号:WO-2010097421-A1
优先权日:2009-02-25
标题 :Synthesis of long-chain alkyl glycosides
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主要参考文献
[参考文献]: Fu F, Et Al. Surface Properties Of Alkyldi(Oxyethylene) β-D-Maltoside. J Agric Food Chem. 2022 Mar 2;70(8):2643-2655.合成参考文献
参考文献:10.1038/s41477-017-0092-7
摘要:Wood WHJ, MacGregor-Chatwin C, Barnett SFH, Mayneord GE, Huang X, Hobbs JK, Hunter CN, Johnson MP. Dynamic thylakoid stacking regulates the balance between linear and cyclic photosynthetic electron transfer. Nat Plants. 2018 Feb;4(2):116–27. doi: 10.1038/s41477-017-0092-7.
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