1-碘-3-硝基苯置于sodium Tetrahydroborate体系中,用 水 作为反应溶剂,化学反应 0.5H,以90%的收率获得产物3-碘苯胺 参考文献:卵黄/壳fe 3 O 4 @聚离子液体衍生的氮掺杂石墨多孔碳材料的合成及其作为镍催化剂的载体† 标题:卵黄/壳fe 3 O 4 @聚离子液体衍生的氮掺杂石墨多孔碳材料的合成及其作为镍催化剂的载体† 摘要:报道了卵黄/壳球的合成,包括活动磁芯,聚离子液体衍生的多孔碳壳和限制在多孔壳内的镍纳米粒子.x射线衍射,Brunauer-Emmett-Teller方程和透射电子显微镜表征证明,所制备的碳壳是石墨的且是多孔的.随后的催化剂已用于硼氢化钠的串联脱氢和水性介质中几种硝基/腈化合物的氢化,这以非常低的催化剂量获得了高收率. DOI:10.1039/c4Ra10374B
专利信息
专利号:US-7713446-B2 优先权日:2004-06-28 标 题:Synthesis of nanofibers of polyaniline and substituted derivatives 发明人:EPSTEIN ARTHUR J; CHIOU NAN-RONG 权利人:OHIO STATE UNIVERISTY 摘要:Novel, simple methods are presented directed to the synthesis of nanofibers of polyaniline and substituted derivatives. The production of these fibers is achieved via various methods by controlling the concentration of aniline monomer or substituted aniline derivatives or an oxidant in the reaction medium and maintaining said concentration at a level much lower than conventional polyaniline synthesis methods. Methods are disclosed relating to the use of a permeable membrane to control the release of a monomer and/or oxidant as well as a bulk polymerization method.
专利号:US-11459427-B1 优先权日:2021-10-07 标题 :Synthesis of polyaniline or derivatives thereof 发明人:ALAMRY KHALID A; KHAN AJAHAR; ASIRI ABDULLAH MOHAMED 权利人:UNIV KING ABDULAZIZ 摘要:Provided are synthesis methods of polymerizing aniline or derivatives thereof. The production of polyaniline or polyaniline derivatives is controlled by the type of oxidant added in the reaction medium. The methods include the step of using a safe and environmentally friendly carbomethyl cellulose (CMC) or modified CMC as an oxidant in the polymerization reaction to produce polyaniline or aniline derivatives. Synthesis methods of producing O-CMC and O-CMC-S oxidants are also provided herein.
专利号:US-8293140-B2 优先权日:2005-06-28 标题:Aligned nanostructured polymers 发明人:EPSTEIN ARTHUR J; CHIOU NAN-RONG; LEE LY JAMES; LU CHUNMENG 权利人:EPSTEIN ARTHUR J; CHIOU NAN-RONG; LEE LY JAMES; LU CHUNMENG; UNIV OHIO STATE RES FOUND 摘要:Novel, simple methods are presented directed to the synthesis of aligned nanofibers of polyaniline and substituted derivatives on a substrate. The production of these fibers is achieved via various methods by controlling the concentration of aniline monomer or substituted aniline derivatives or an oxidant in the reaction medium and maintaining said concentration at a level much lower than conventional polyaniline synthesis methods. Methods are disclosed relating to the use of a permeable membrane to control the release of a monomer and/or oxidant as well as a bulk polymerization method.
专利号:US-2007034836-A1 优先权日:2004-06-28 标 题 :Synthesis of nanofibers of polyaniline and substituted derivatives
专利号:US-2008197326-A1 优先权日:2004-06-28 标 题:Synthesis of nanofibers of polyaniline and substituted derivatives
专利号:US-7374703-B2 优先权日:2004-06-28 标 题 :Synthesis of nanofibers of polyaniline and substituted derivatives
[参考文献]: Dimitrios E Lizos, Et Al. Concise Synthesis Of (+/-)-Horsfiline And (+/-)-Coerulescine By Tandem Cyclisation Of Iodoaryl Alkenyl Azides. Org Biomol Chem. 2003 Jan 7;1(1):117-22. [参考文献]: Fangguo Ye, Et Al. Ionic-Liquid-Promoted Palladium-Catalyzed Multicomponent Cyclocarbonylation Of O-Iodoanilines And Allenes To Form Methylene-2,3-Dihydro-1H-Quinolin-4-Ones. J Org Chem. 2007 Apr 27;72(9):3218-22. [参考文献]: Karin Dooleweerdt, Et Al. Application Of Ynamides In The Synthesis Of 2-Amidoindoles. Org Lett. 2009 Jan 1;11(1):221-4. [参考文献]: L A Khawli, Et Al. M-[参考文献]: Pan Dang, Et Al. Copper-Catalyzed Three-Component Synthesis Of Benzothiazolethiones From O-Iodoanilines, Isocyanide, And Potassium Sulfide. Org Lett. 2015 Jan 2;17(1):34-7.
合成参考文献
摘要:Shimada, K., Science of Synthesis Knowledge Updates, (2010) 1, 461. 摘要:Undheim, K., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 721. 摘要:Petit, C.; Montchamp, J.-L., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 347. 摘要:Primer, D. N.; Molander, G. A., Science of Synthesis, (2019) , 306. 摘要:Bellanger, C.; Chelli, S.; Lakhdar, S., Science of Synthesis, (2021) , 253.