CAS: 142-09-6; Hexyl Methacrylate

该化合物是被归类为甲基丙烯酸和六氟硝酸酯酯的有机化合物,其特点是一种无色的淡黄色液体,其特征为一种令人愉快的水果味;该化合物以有机溶剂中的低粘度和高溶性而著称,使其在各种应用中有用;Hexyl 甲基丙酸酯主要用作聚合物和共聚物生产中的单体,由于它能够增强灵活性和抗力,因此有助于粘合剂,涂层和密封剂的配制;它具有良好的热稳定性,可以通过自由基机制进行聚合,而自由基体机制对于使用它来制造耐用材料至关重要;此外,Hexyn methacryate被认为具有中度毒性,在处理时应采取适当的安全措施,包括使用个人防护设备避免吸入或皮肤接触.总体而言,它的独特性使得它成为聚合物化学领域的宝贵成分.

结构式图片

相似化合物

142-90-5 32360-05-7 2495-27-4

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号80-62-6 甲基丙烯酸甲酯 | CAS号4245-37-8 甲基丙烯酸乙烯酯 | CAS号111-27-3 正己醇 | CAS号62247-20-5 hexyl 2-hydroxy... | CAS号79-41-4 甲基丙烯酸

合成工艺路线路线简述

    甲基丙烯酸甲酯 反应生成甲基丙烯酸正己酯
    参考文献:Nail Polishes
    标题:Nail Polishes
    摘要:新的指甲油配方包括树脂,增塑剂,溶剂系统,成膜剂和可选的着色剂,其中树脂是甲基丙烯酸甲酯和己基甲基丙烯酸甲酯的共聚物.

    海关参考信息

    专利信息


    专利号:WO-2023102600-A1
    优先权日:2021-12-06
    标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
    发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
    权利人:NEWSOUTH INNOVATIONS PTY LTD
    摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

    专利号:US-5420237-A
    优先权日:1991-08-29
    标 题:Enzymatic synthesis of polyaniline
    发明人:ZEMEL HAYA; QUINN JOHN F
    权利人:ALLIED SIGNAL INC
    摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

    专利号:EP-2128179-B1
    优先权日:2008-05-26
    标 题:Solid-phase support for nucleic acid synthesis
    发明人:MORI KENJIRO; MAETA ERI
    权利人:NITTO DENKO CORP
    摘要:According to the invention, there is provided a solid-phase support for nucleic acid synthesis, which is constituted of a porous copolymer particle containing a multifunctional vinyl monomer unit having two or more vinyl groups in one molecule and a monofunctional vinyl monomer unit having one vinyl group in one molecule, in which the solid-phase support has a swelling volume when soaked in acetonitrile of 3.5 ml/g or more and has a median particle diameter measured by a laser scattering particle size distribution measuring method within a range of from 50 to 120 µm. According to the solid-phase support for nucleic acid synthesis of the invention, a high-purity nucleic acid can be synthesized with a high yield.

    专利号:US-10465033-B2
    优先权日:2016-11-10
    标题:One step synthesis of ultrahigh molecular weight block copolymers
    发明人:URBAN MAREK W
    权利人:UNIV CLEMSON; UNIV CLEMSON RES FOUNDATION
    摘要:Single-step synthesis processes for production of ultrahigh molecular weight block copolymers are described. The ultrahigh molecular weight copolymers can have a molecular weight of about 10 6 or greater and can be formed within a few hours in a surfactant-free environment. The formation process is controlled by initiator-starvation conditions in a sequential polymerization of monomers exhibiting different solubility in the solvent.

    专利号:US-9512250-B2
    优先权日:2012-02-23
    标 题 :Manganese catalyzed photopolymerization of fluorinated monomers
    发明人:ASANDEI ALEXANDRU D
    权利人:UNIV CONNECTICUT
    摘要:The disclosure discloses initiating systems for the radical polymerization of alkenes, and especially fluorine substituted alkenes. The polymerization is catalyzed by a metal carbonyl, preferably manganese carbonyl. The polymerization is initiated directly from alkyl halides at room temperature under visible white light. The polymers also allow the synthesis of block copolymers. The process comprises polymerizing at least one alkene monomer in the presence of a halide radical initiator, carbonyl catalyst and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one alkene monomer to form a polymer. The present disclosure provides a method for living polymerization of alkene monomers which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products. This disclosure also provides a method for activating any halide (Cl, Br, I) chain ends of such polymers for the synthesis of block copolymerizations.

    专利号:US-2023348707-A1
    优先权日:2022-04-28
    标题:Random bipolymers of controlled molecular mass based on hydroxyacrylates and their use as destabilizers of water/oil emulsions in crude oils
    发明人:SANDOVAL CÉSAR ANDRÉS FLORES; MORENO FLAVIO SALVADOR VÃ?ZQUEZ; OLIVARES GERARDO ZAVALA; RAMÃ?REZ FERNANDO Ã?LVAREZ; SANTIAGO JESSICA VALERIA FUENTES; ZAMORA GUERRERO EDGAR BENEDICTO; MAYA ENRIQUE CEVADA
    权利人:MEXICANO INST PETROL
    摘要:The present disclosure provide bipolymers, based on alkyl acrylate and hydroxyalkyl acrylate, with high randomness and controlled molecular mass, that are useful as demulsifying and dehydrating agents for crude oil. The synthesis of these bipolymers is carried out in a single stage by emulsion polymerization, a process that, in addition to having moderate reaction conditions, allows the control of the homogeneity of the chain size, the molecular mass, and the demulsifying efficiency. These random bipolymers are soluble in organic phase; therefore, these cannot be carried away by the removed water, and are eliminated in the atmospheric distillation stage. An additional advantage is the superior demulsifying and clarifying efficiency of these random bipolymers compared with the polyether formulations widely used at industrial level. In addition, these random bipolymers provide single molecule that performs three functions: breaker, coalescer and clarifier, in contrast to formulations based on at least three different polyethers.
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    主要参考文献

    [参考文献]: Jing-Wei Xu, Et Al. Effects Of Quaternization On The Morphological Stability And Antibacterial Activity Of Electrospun Poly(Dmaema-Co-Ama) Nanofibers. Colloids Surf B Biointerfaces. 2015 Sep 1:133:148-55.

    合成参考文献


    摘要:Clayton, G.D., F.E. Clayton (eds.) Patty's Industrial Hygiene and Toxicology. Volumes 2A, 2B, 2C, 2D, 2E, 2F: Toxicology. 4th ed. New York, NY: John Wiley & Sons Inc., 1993-1994., p. 3008
    摘要:DHHS/National Toxicology Program, Salmonella Study Summary for n-Hexyl methacrylate (142-09-6) (1983).
    参考文献:10.4012/dmj.2010-163
    摘要:Ikemura K, Fujii T, Negoro N, Endo T, Kadoma Y. Design of a metal primer containing a dithiooctanoate monomer and a phosphonic acid monomer for bonding of prosthetic light-curing resin composite to gold, dental precious and non-precious metal alloys. Dent Mater J. 2011;30(3):300–7. doi: 10.4012/dmj.2010-163.
    参考文献:10.1016/j.chroma.2018.04.045
    摘要:Obbed MS, Aqel A, Al Othman ZA, Badjah-Hadj-Ahmed AY. Preparation, characterization and application of polymethacrylate-based monolithic columns for fast and efficient separation of alkanes, alcohols, alkylbenzenes and isomeric mixtures by gas chromatography. J Chromatogr A. 2018 Jun 22;1555():89–99. doi: 10.1016/j.chroma.2018.04.045.
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