CAS: 85721-25-1; 2-(Oct-7-En-1-yl)Oxirane

该化合物是一种环状醚和不饱和的氧化物.这种化合物具有三环的四氧化环,由于环的累累性而闻名.在十环链中存在双环,导致其不饱和,使其有可能成为各种化学反应,包括聚合物和环状开关反应的候选体.一般而言,四氧化物的特征是它们有能力进行核循环性攻击,这可能导致酒精或其他功能组的形成.1,2-环-九-九-十色可被用于合成更复杂的分子,包括表面活性剂,涂层和粘合剂,因为其反应性过氧化物组.此外,该化合物的物理特性,如沸点和溶解度,可能因其分子结构和功能组的存在而不同.在处理这一化合物时,应当采取安全防范措施,因为五氧化物可以是刺激剂和构成健康的风险.

结构式图片

相似化合物

1883429-78-4 2855-19-8 2984-50-1

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上下游产品

CAS号1647-16-1 1,9-癸二烯 | CAS号112-38-9 十一烯酸 | CAS号2404-44-6 1,2-环氧癸烷 | CAS号112-30-1 正癸醇 | CAS号24854-67-9 Oxirane,2,2'-(1... | CAS号85866-05-3 9-decene-1,2-diol | CAS号39770-05-3 9-癸烯醛 | CAS号35194-30-0 9-Decen-2-one | CAS号39770-04-2 8-壬烯醛

合成工艺路线路线简述

  • 1779-49-3 + 115785-45-0 = 85721-25-1
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; Rt; Overnight,Rt1.2 Solvents: Tetrahydrofuran; 60 °C
    标题:Olefin Functionalization/isomerization Enables Stereoselective Alkene Synthesis
    作者:Liu,Chen-Fei; Et Al
    参考文献:Nature Catalysis 日期:2021 卷标:4(8) 页码:674-683]

    = 85721-25-1
    反应条件:1.1 Reagents: Isobutyraldehyde,Oxygen Catalysts: Aspartic Acid,Homopolymer,Sodium Salt (Cobalt Or Copper Complex) Solvents: Acetonitrile; 30 H,Rt -> 60 °C
    标题:Poly(Aspartic Acid)-Supported Cobalt Or Copper (Ii) Catalysts For The Oxidations Reactions Of Alkenes
    作者:Blaz,Edyta; Et Al
    参考文献:Modern Polymeric Materials For Environmental Applications 日期:2008 卷标:3 页码:9-12]

    1647-16-1 = 85721-25-1 + 24854-67-9
    反应条件:1.1 Reagents: Peracetic Acid
    标题:Manufacture Of Epoxidized α,ω-Diolefins
    参考文献:Japan]

    1647-16-1 = 85721-25-1
    反应条件:1.1 Reagents: Sodium Bicarbonate,Benzaldehyde,2-Hydroxy-,Homopolymer,Tetrabutylammonium Hydrogen Sulfate,Potassium Peroxymonosulfate Sulfate (2Khso5.Khso4.K2So4) Solvents: Dichloromethane,Water; 3.1 H,Ph 7 - 7.5,Rt
    标题:Preparation Of Dioxirane Via Epoxidation Of Terminal Alkenes By Heterogeneous Polydioxiranein Mild Conditions.
    作者:Kazemnejadi,M.; Et Al
    参考文献:Royal Society Open Science 日期:2018 卷标:5(5) 页码:171541/1-171541/13]

    1647-16-1 = 85721-25-1
    反应条件:1.1 Reagents: Oxygen Catalysts: Iron Oxide (Fe3O4),Cobalt (Complexes With Poly α-Amino Acidsupported On Magnetite Graphene Oxide),Benzaldehyde,5-(Chloromethyl)-2-Hydroxy-,Homopolymer (Reaction Products With Sodium Cyanide,Hydrolyzed,Complexes With Coba...),Graphene (Fe3O4-Doped) Solvents: Acetonitrile; 1 H,60 °C
    标题:Synthesis And Characterization Of A New Poly α-Amino Acid Co(Ii)-Complex Supported On Magnetite Graphene Oxide As An Efficient Heterogeneous Magnetically Recyclable Catalyst For Efficient Free-Coreductant Gram-Scale Epoxidation Of Olefins With Molecular Oxygen
    作者:Kazemnejadi,Milad; Et Al
    参考文献:Journal Of Organometallic Chemistry 日期:2019 卷标:896 页码:59-69]

    1647-16-1 = 85721-25-1
    反应条件:1.1 Reagents: Oxygen Catalysts: Cobalt Diacetate,2-Aminophenol,Benzaldehyde,5-(Chloromethyl)-2-Hydroxy-,Homopolymer Solvents: Acetonitrile; 1.5 H,1 Atm,60 °C
    标题:Co(Ii) Schiff Base Complex Decorated On Polysalicylaldehyde As An Efficient,Selective,Heterogeneous And Reusable Catalyst For Epoxidation Of Olefins In Mild And Self-Coreductant Conditions
    作者:Kazemnejadi,Milad; Et Al
    参考文献:Research On Chemical Intermediates 日期:2017 卷标:43(12) 页码:6889-6910]

    142986-44-5 + 85721-25-1 = 85721-25-1
    反应条件:1.1 Solvents: Methanol; 4 D,Rt
    标题:Nitric Oxide-Releasing Amphiphilic Poly(Amidoamine) (Pamam) Dendrimers As Antibacterial Agents
    作者:Lu,Yuan; Et Al
    参考文献:Biomacromolecules 日期:2013 卷标:14(10) 页码:3589-3598]

    1647-16-1 = 85721-25-1 + 24854-67-9
    反应条件:1.1 Catalysts: 1-Octadecanaminium,N,N-Dimethyl-N-Octadecyl-,Stereoisomer Of Tetraoxotetrakis[...,1-Hexadecanaminium,N-Hexadecyl-N,N-Dimethyl-,Stereoisomer Of Tetraoxotetrakis[... Solvents: 1,2-Dichloroethane,Water; 6 H,50 °C1.2 Reagents: Hydrogen Peroxide Solvents: Water; 50 °C; 1 H,50 °C; Cooled
    标题:Synthesis Of α,ω-Alkanediols From Terminal Alkadienes As Intermediates For Polymers
    参考文献:Italy]

    1647-16-1 = 85721-25-1 + 24854-67-9
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Titanium,Silica Solvents: (Trifluoromethyl)Benzene; 7 H,363 K
    标题:An Efficient Epoxidation Of Terminal Aliphatic Alkenes Over Heterogeneous Catalysts: When Solvent Matters
    作者:Palumbo,C.; Et Al
    参考文献:Catalysis Science & Technology 日期:2016 卷标:6(11) 页码:3832-3839
📜1,9-癸二烯置于氧气体系中,用 乙腈 作为反应溶剂,化学反应 1.0H,以90%的收率获得产物1,2-环氧-9-癸烯
参考文献:磁铁矿氧化石墨烯上负载的新型聚α-氨基酸co(II)配合物的合成与表征
标题:磁铁矿氧化石墨烯上负载的新型聚α-氨基酸co(II)配合物的合成与表征
摘要:通过将合成的聚α-氨基酸的钴配合物固定在掺杂fe 3 O 4的氧化石墨烯(go / Fe 3 O 4)上,制备了一种新型的磁性纳米复合材料.@paa Co(II)),被证明是在温和条件下烯烃环氧化的高效催化剂.paa是通过多步合成法合成的,首先是水杨醛的缩聚反应,然后是strecker合成法.通过多种分析和光谱方法对合成的纳米复合材料进行了表征,包括ftir,Icp,Xrd,Edx,Xps,Fe-Sem,Tem,Tga,Vsm和dls分析.在分子氧存在下,可以耐受多种烯烃进行环氧化而无需任何助还原剂.磁性纳米复合材料很容易被磁体从混合物中分离出来,并重复使用几次,而没有任何明显的反应活性损失,这代表了其在实际和工业应用中的潜力.还,
DOI:10.1016/j.Jorganchem.2019.05.030

海关参考信息

专利信息


专利号:US-5395992-A
优先权日:1993-02-06
标 题:Synthesis of diols, for use as intermediates for polymeric materials, by starting from terminal diolefins
发明人:RICCI MARCO; GEMENTI FRANCESCO; PANELLA FRANCESCO; QUERCI CECILIA; UNGARELLI RAFFAELE
权利人:ENICHEM SPA
摘要:Disclosed is the synthesis of terminal diols, which are organic intermediates used in order to produce polymeric materials, by starting from terminal diolefins, which synthesis is based on the oxidation of diolefins to yield diepoxides, in a double-phase aqueous-organic system with hydrogen peroxide and in the presence of catalysts soluble in the organic phase, followed by a reaction of reduction of the resulting diepoxides.

专利号:US-8921580-B2
优先权日:2012-05-09
标 题 :Methods and systems for the formation of cyclic carbonates
发明人:HATTON TREVOR ALAN; JAMISON TIMOTHY F; KOZAK JENNIFER AIDEN; SIMEON FRITZ; WU JIE
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Described herein are inventive methods for synthesis of cyclic carbonates from CO 2 and epoxide. In some embodiments, the methods are carried out in the presence of a catalyst comprising an electrophilic halogen. In some embodiments, the methods are carried out in a flow reactor.

专利号:US-9139504-B2
优先权日:2001-07-02
标 题 :Lanolin substitute, production method thereof and applications of same
发明人:CHARLIER DE CHILY PIERRE; RAYNARD MIKAELE
权利人:ALDIVIA SA
摘要:This invention proposes a lanolin substitute, capable of absorbing up to at least twice its weight of water or aqueous solution or aqueous suspension. It forms true emulsions, stable over time with a capacity for water absorption superior to that of lanolin. n It also possesses the known emollient, moisturizing and occlusive properties of lanolin. n This substitute is usable in all the present and future areas of application of lanolin: in the cosmetics industry, dermatology, and in industrial applications (polishes, lubricants . . . ). n It is obtained by hemi-synthesis from a mixture of unsaturated fatty acids, esters of unsaturated fatty acids, unsaturated hydrocarbons or unsaturated derivatives of the latter and compounds comprising or generating hydroxyl functions, such as glycerol, preferably without a catalyst and in an atmosphere devoid of oxygen. n Classical thermal treatment or preferably treatment by dielectric heating.

专利号:US-9756687-B2
优先权日:2002-12-23
标 题:Chemical synthesis comprising heat treatment by intermittent dielectric heating combined with a recycling system
发明人:CHARLIER DE CHILY PIERRE; RAYNARD MIKAELE
权利人:ALDIVIA SAS
摘要:This invention relates to the design of a process by intermittent dielectric heating combined with a recycling system. n This process consists in subjecting reagents to electromagnetic waves selected in the frequencies ranging between 300 GHz and 3 MHz intermittently using a recycling system. n This process enables the treatment of oils that are hardly absorbent as well as great investment savings. n This process enables operation on different scales, whether in laboratories, on a semi-industrial or industrial scale, without forfeiting the advantages of continuous dielectric heating.

专利号:EP-0610600-A1
优先权日:1993-02-06
标 题:Synthesis of diols, for use as intermediates for polymeric materials, by starting from terminal diolefins

专利号:US-9329158-B2
优先权日:2013-03-15
标 题:Epoxy chemistry derived materials as mixed mode chromatography media, method for their synthesis and use
发明人:LIU XIAODONG; CAO LIANG; POHL CHRISTOPHER A
权利人:LIU XIAODONG; CAO LIANG; POHL CHRISTOPHER A; DIONEX CORP
摘要:This invention provides mixed-mode stationary phase compositions, devices and systems comprising the stationary phases as well as methods of producing these compositions using epoxide ring-opening reactions. Also provided are methods of using the stationary phases of the invention in separations.

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📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Yuan Lu, Et Al. Nitric Oxide-Releasing Amphiphilic Poly(Amidoamine) (Pamam) Dendrimers As Antibacterial Agents. Biomacromolecules. 2013 Oct 14;14(10):3589-98.
[参考文献]: Yuan Lu, Et Al. Structurally Diverse Nitric Oxide-Releasing Poly(Propylene Imine) Dendrimers. Chem Mater. 2011 Sep 27;23(18):4227-4233.

合成参考文献


摘要:Okamoto, K.; Ohe, K., Science of Synthesis Knowledge Updates, (2020) 1, 51.
摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 205.
摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 221.
摘要:Xia, F.; Ye, S., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 2, 28.
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