CAS: 84783-64-2; 2,2'-Bis(Diphenylphosphino)-1,1'-Biphenyl
该化合物是一个多用途的离子体,在有机金属化学中具有重要的应用作用,其独特的结构和含有磷的功能组有助于形成与过渡金属有关的稳定复合体,增强催化活动和各种反应中的选择性. 这一离子因其能够促进高效和选择性的转化而备受高度评价,使它成为合成复杂有机分子的宝贵工具.
- 英文名称2,2'-Bis(Diphenylphosphino)-1,1'-Biphenyl
- 中文名称2,2'-双(二苯基磷)联苯
- IUPAC名称2,2'-bis(diphenylphosphaneyl)-1,1'-biphenyl
- 其它别名[2'-(Diphenylphosphanyl)-[1,1'-Biphenyl]-2-Yl]Diphenylphosphane; 2,2 Inverted Exclamation Mark -Bis(Diphenylphosphino)-1,1 Inverted Exclamation Mark -Biphenyl; 2-Bromophenoxyaceticacid; [2-(2-Diphenylphosphinophenyl)Phenyl]-Diphenylphosphine; Schembl1
- CAS编号84783-64-2
- MFCD编号:MFCD03094574
- EINECS号:677-052-1
- 分子式:C36H28P2分子量:522.56
- 产品CID: 1838056
- 产品分类有机原料 → 有机膦化合物
物理性质
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号62336-24-7 (2-溴苯基)二苯基膦 | CAS号1806-29-7 2,2'-二羟基联苯 | CAS号17763-95-0 2,2''-双(三氟甲磺酰氧基... | CAS号829-85-6 二苯基膦 | CAS号2236-52-4 2,2'-二碘代联苯 | CAS号1079-66-9 氯代二苯基膦 | CAS号88652-75-9 1-diphenylphosp... | CAS号791-28-6 三苯基氧化膦合成工艺路线路线简述
- 174467-54-0 = 84783-64-2
反应条件:1.1 Reagents: N,N-Dimethylaniline,Trichlorosilane Solvents: Toluene
标题:General Synthetic Route To Chiral Flexible Biphenylphosphine Ligands: The Use Of A Chiral Additive Enables The Preparation And Observation Of Metal Complexes Incorporating The Enantiopure Form
作者:Mikami,Koichi; Aikawa,Kohsuke; Korenaga,Toshinobu
参考文献:Organic Letters 日期:2001 卷标:3(2) 页码:243-245]
174467-54-0 = 84783-64-2
反应条件:1.1 Reagents: Triethylamine,Trichlorosilane Solvents: Xylene
标题:2,2'-Bis(Diphenylphosphino)Biphenyl Revisited
作者:Desponds,Olivier; Schlosser,Manfred
参考文献:Journal Of Organometallic Chemistry 日期:1996 卷标:507(1-2) 页码:257-61]
829-85-6 + 2236-52-4 = 84783-64-2
反应条件:1.1 Reagents: Potassium Acetate Catalysts: Palladium Diacetate Solvents: Dimethylacetamide; 3 H,130 °C
标题:Catalytic Palladium Phosphination: Modular Synthesis Of C1-Symmetric Biaryl-Based Diphosphines
作者:Bonnafoux,Laurence; Gramage-Doria,Rafael; Colobert,Francoise; Leroux,Frederic R.
参考文献:Chemistry - A European Journal 日期:2011 卷标:17(39) 页码:11008-11016]
219669-07-5 = 84783-64-2
反应条件:1.1 Reagents: Bis(Dibenzylideneacetone)Palladium
标题:Bis{(2-Diphenylphosphino)Phenyl}Mercury: A P-Donor Ligand And Precursor To Mixed Metal-Mercury (D8-D10) Cyclometalated Complexes Containing 2-C6H4Pph2
作者:Bennett,Martin A.; Contel,Maria; Hockless,David C. R.; Welling,Lee L.; Willis,Anthony C.
参考文献:Inorganic Chemistry 日期:2002 卷标:41(4) 页码:844-855]
62336-24-7 = 84783-64-2
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 1 H,-78 °C1.2 Reagents: Iron(Iii) Acetylacetonate Solvents: Tetrahydrofuran; 1 H,-78 °C1.3 Solvents: Water
标题:Synthesis,Characterization And Luminescent Properties Of Copper(I) Halide Complexes Containing Biphenyl Bidentate Phosphine Ligand
作者:Chen,Bu-Lin; Liu,Li; Zhong,Xin-Xin; Asiri,Abdullah M.; Alamry,Khalid A.; Et Al
参考文献:Journal Of Coordination Chemistry 日期:2017 卷标:70(23) 页码:3907-3919]
791-28-6 = 84783-64-2
反应条件:1.1 Reagents: Sec-Butyllithium Solvents: Tetrahydrofuran1.2 Reagents: Propanoic Acid,2,2-Dimethyl-,Copper(2+) Salt (2:1) Solvents: Tetrahydrofuran1.3 Reagents: Triethylamine,Trichlorosilane Solvents: Xylene1.4 Reagents: Diglyme Solvents: Water
标题:Diastereoisomer Interconversion In Chiral Biphepptx2 Complexes
作者:Tudor,Melanie D.; Becker,Jennifer J.; White,Peter S.; Gagne,Michel R.
参考文献:Organometallics 日期:2000 卷标:19(21) 页码:4376-4384]
16291-32-0 + 1079-66-9 = 84783-64-2
反应条件:1.1 Reagents: (Sp-4-2)-[(1R,2R)-1,2-Cyclohexanediamine-Kn1,Kn2]Bis(Nitrato-Ko)Platinum
标题:A Notice: Incorrect Formulation In The Synthetic Method Of 2,2'-Bis(Diphenylphosphino)Biphenyl
作者:Miyamoto,T. Ken; Matsuura,Yumiko; Okude,Kojiro; Ichida,Hikaru; Sasaki,Yukiyoshi
参考文献:Journal Of Organometallic Chemistry 日期:1989 卷标:373(1)
📜2,2'-二羟基联苯置于palladium Diacetate 三氯硅烷,N,N-二甲基苯胺,1,4-双(二苯基膦)丁烷体系中,用 吡啶,二甲基亚砜,甲苯 作为反应溶剂,化学反应生成 2,2'-双(二苯基磷)联苯
参考文献:手性柔性联苯膦配体的一般合成路线:使用手性添加剂可以制备和观察掺入对映体纯形式的金属配合物.
标题:手性柔性联苯膦配体的一般合成路线:使用手性添加剂可以制备和观察掺入对映体纯形式的金属配合物.
摘要:[图:见正文]手性柔性biphep配体的对映体和非对映体纯金属络合物是通过将biphep-Ru络合物与对映纯3,3'-二甲基二氨基联萘,Dm-Dbn的对映异构体选择性配位,然后进行差向异构化而获得的剩余的biphep-Ru对映异构体可与dm-Dabn络合.因此,描述了从双酚到各种取代的biphep配体的有效且通用的合成途径,以及在它们的ru(II)配合物中观测到对映体纯的biphep配体.
DOI:10.1021/ol0068896
海关参考信息
- 2902200000-苯
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专利信息
专利号:US-11718584-B2
优先权日:2019-02-22
标题 :Process for the synthesis anthranilic diamide compounds and intermediates thereof
发明人：KARRI PHANEENDRASAI; PABBA JAGADISH; SHINDE BHARAT UTTAMRAO; KALWAGHE AMOL DNYANESHWAR; MADHAVRAO KAMBLE MARUTI; KLAUSENER ALEXANDER G M; PANMAND DEEPAK SHANKAR
权利人:PI INDUSTRIES LTD
摘要:The present invention disclosed a process for the synthesis of anthranilic diamide compound of formula (I), n n n n n n n n n n wherein, R 1 , R 2 , R 3a , R 3b , R 3c , R 4 , R 5 , R 6 and Z are as defined in the detailed description. The process comprising the step of obtaining a mono- or dicyano substituted aniline compound of formula (IV) which is then converted to an anthranilic acid compound of formula (V) or an anthranilic amide compound of formula (Va). Further, the compound of formula (VI) can be optionally synthesized from compound of formula (IV or V or Va)
专利号:US-2008207950-A1
优先权日:2004-12-22
标 题:Enantioselective Synthesis of a Sterically Hindered Amine
发明人：BERENS ULRICH; MALAN CHRISTOPHE; KIRNER HANS JURG
权利人:CIBA SC HOLDING AG
摘要:Compounds of the formula (I) wherein R is phenyl, or phenyl substituted by Cl, Br, C 1 -C 4 alkyl or CF 3 ; R 1 is H or methyl or ethyl; R 2 is H or methyl or acyl; R 3 is H or methyl; R′ 4 is —CH 3 or â•?CH 2 ; may be obtained in high enantiopurity by hydrogenation of a compound of the formula (II) wherein R and R 3 are as in formula (I); A is acyl; and R 4 is —CH 3 or â•?CH 2 ; in the presence of a chiral Rhodium or Ruthenium catalyst. Residues R 1 as methyl or ethyl and/or R 2 as H or methyl may subsequently be introduced without racemization by deacylation and optional alkylation.
专利号:US-2016090360-A1
优先权日:2013-04-26
标题:Synthesis of bace inhibitors
发明人：FETTES ALEC; MARTY HANS-PETER; SCALONE MICHELANGELO
权利人:HOFFMANN LA ROCHE
摘要:The present invention provides a one step carbonylation of a compound of formula II in the presence of water to afford a compound of formula (I), useful in processes to manufacture BACE inhibitors.
专利号:US-2016223559-A1
优先权日:2015-02-02
标题:Tetrazine-containing compounds and synthetic methods thereof
发明人：DEVARAJ NEAL K; WU HAOXING; YANG JUN
权利人:UNIV CALIFORNIA
摘要:Described herein are tetrazine derivatives and efficient synthetic methods of synthesis thereof using elimination-Heck cascade reaction. Provided herein is the synthesis of conjugated tetrazines from the tetrazine derivatives. Also provided herein are methods of use of the conjugated tetrazines as fluorogenic probes for live-cell imaging.
专利号:US-9914695-B2
优先权日:2015-07-10
标题:Two-step process for preparing 3-substituted phenylalkylamines
发明人：Teramura Doug; LIAO SUBO
权利人:MALLINCKRODT LLC
摘要:Processes for preparing 3-substituted phenylalkylamines comprising reacting a phenyl boronic compound with an α-β unsaturated carbonyl-containing compound via an asymmetric 1,4-addition reaction, followed by reductive alkylation. The processes may be useful in the synthesis of tapentadol.
专利号:JP-2009530403-A
优先权日:2006-03-21
标 题 :Synthesis of arylamines from reactions of aromatic compounds with ammonia or metal amides.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Burmester, C.; Haß, O.; Faust, R., Science of Synthesis, (2008) 43, 263.
摘要:Ogasawara, M., Science of Synthesis, (2008) 44, 29.
摘要:Palframan, M. J.; Parsons, A. F., Science of Synthesis, (2009) 48, 679.
摘要:Vrána, J.; Růžička, A., Science of Synthesis Knowledge Updates, (2021) 2, 38.
摘要:Davies, G. H. M.; Wisniewski, S. R., Science of Synthesis Knowledge Updates, (2021) 2, 119.
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