CAS: 464-48-2; (1S,4S)-1,7,7-Trimethylbicyclo[2.2.1]Heptan-2-One

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CAS号791787-82-1 Borneol | CAS号464-43-7 右莰醇 | CAS号464-45-9 左旋龙脑 | CAS号36065-15-3 (1S)-1,7,7-trim... | CAS号76-29-9 D-溴樟脑 | CAS号756834-48-7 tert-butyldimet... | CAS号33171-48-1 (-)-endo-6-brom... | CAS号64474-54-0 S-(-)-3-溴樟脑 | CAS号560-09-8 (1S,3R)-(-)-樟脑酸 | CAS号464-45-9 左旋龙脑 | CAS号464-43-7 右莰醇 | CAS号79-92-5 莰烯 | CAS号2767-84-2 1,7,7-三甲基螺[2.2.1]庚二酮 | CAS号64474-54-0 S-(-)-3-溴樟脑 | CAS号508-32-7 cyclene | CAS号5794-04-7 (-)-莰烯

📜Borneol置于cultured Cells Of Nicotiana Tabacum体系中,化学反应 240.0H,反应生成 左旋樟脑
参考文献:用烟草培养细胞对单环和双环单萜类化合物进行生物转化的对映选择性
标题:用烟草培养细胞对单环和双环单萜类化合物进行生物转化的对映选择性
摘要:研究了对薄荷烷和双环 [2.2.1] 和 [3.1.1] 庚烷衍生物的对映体对与烟草培养细胞的生物转化.发现(I)培养的细胞区分对-薄荷醇-2-醇和双环[2.2.1]庚烷-2-醇和双环[3.1.1]庚烷-3-醇衍生物的对映异构体,并对映选择性转化将这些醇转化为相应的酮,(II) 细胞高度还原 P-Menthan-2-One 衍生物的羰基,但不还原 P-Menthan-3-Ones 的羰基,以及 (Iii) 细胞区分双环[3.1.1]Hept-2-En-4-One(verbenone)的对映异构体,并对映选择性还原(1S,5S)-对映异构体的c-C双键.
DOI:10.1246/bcsj.61.869

专利信息

专利号:US-6933385-B2
优先权日:2001-08-03
标题 :Protected 3,5-dihydroxy-2,2-dimethyl-valeroamides for the synthesis of epothilones and derivatives and process for the production and the use
发明人：WESTERMANN JURGEN; PLATZEK JOHANNES; PETROV ORLIN
权利人:SCHERING AG
摘要:The invention relates to new protected 3,5-dihydroxy-2,2-dimethyl-valeroamides for the synthesis of epothilones and derivatives and process for the production and the use of the new compounds for the production of epothilones or epothilone derivatives.

专利号:US-2010204463-A1
优先权日:2007-08-07
标题 :Preparation Of Synthetic Nucleosides via Pi-Allyl Transition Metal Complex Formation
发明人：LIOTTA DENNIS C; LI YONGFENG
权利人:LIOTTA DENNIS C; LI YONGFENG
摘要:This invention provides highly regioselective and stereoselective processes for preparing synthetic nucleosides. A process for the preparation of synthetic nucleosides is provided that comprises a) preparing a bicycloamide derivative, b) reacting the bicycloamide derivative with a nucleic acid base or heterocyclic base or salt thereof in the presence of a transition metal catalyst to form a cyclopentenecarboxamide, and c) cleaving a carboxamide group from the cyclopentenecarboxamide to form the synthetic nucleoside. The processes according to the invention can be used for the synthesis of a variety of anti-viral agents, including Abacavir, Carbovir, and Entecavir, as well as derivatives thereof.

专利号:JP-2004537589-A
优先权日:2001-08-03
标 题 :Protected 3,5-dihydroxy-2,2-dimethyl-valeronitrile, synthesis method and use thereof for the synthesis of epothilone and epothilone derivatives

专利号:JP-2004537591-A
优先权日:2001-08-03
标题:Protected 3,5-dihydroxy-2,2-dimethyl-valeronitrile, synthesis method and use thereof for the synthesis of epothilone and epothilone derivatives

专利号:JP-4620346-B2
优先权日:2001-08-03
标题 :Protected 3,5-dihydroxy-2,2-dimethyl-valeronitrile, synthesis method and use thereof for the synthesis of epothilone and epothilone derivatives

专利号:US-6451340-B1
优先权日:1997-07-25
标题:Nucleotide analog compositions
发明人：ARIMILLI MURTY N; KELLY DAPHNE E; LEE THOMAS T K; MANES LAWRENCE V; MUNGER JR JOHN D; PRISBE ERNEST J; SCHULTZE LISA M
权利人:GILEAD SCIENCES INC
摘要:The invention provides crystalline forms of adefovir dipivoxil and methods to prepare the crystals. The compositions and methods of the present invention have desirable properties for large scale synthesis of crystalline adefovir dipivoxil or for its formulation into therapeutic dosages. Invention compositions include an anhydrous crystal form of adefovir dipivoxil.