CAS: 28903-71-1; 5,10,15,20-Tetrakis (4-Methoxyphenyl)-21H,23H-Porphine Cobalt (Ii)

该化合物是一个金属卤素综合体,由一个钴(II)中心在以4个4-甲基苯基组取代的浮游大型循环中协调.该复合体在可见频谱中表现出很强的吸收作用,使其在光物理和催化应用中变得有用.对甲基氧电子施放组提高了其在有机溶剂中的溶解性,并影响其红氧化特性,促进了其在氧化反应和电子转移过程中的作用.其稳定的协调几何和可金枪鱼电子结构使其在材料科学(包括分子电子学和传感器开发)中具有价值.该复合体的精确结构和再活性也使它成为研究基于金属的催化机制的候选体.

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CAS号71-48-7 乙酸钴 | CAS号22112-78-3 5,10,15,20-四(4-... | CAS号123-11-5 4-甲氧基苯甲醛; 对甲氧基苯... | CAS号109-97-7 吡咯 | CAS号7646-79-9 氯化钴

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    主要参考文献

    1.) Gupta, V.K., Agarwal, S.; PVC based 5,10,15,20-tetrakis (4-methoxyphenyl)porphyrinatocobalt(II) membrane potentiometric sensor for arsenite, Talanta65, 2005, 730-734. https://doi.org/10.1016/j.talanta.2004.07.043 2.) Gupta, V.K., Chandra, S., Chauhan, D.K., Mangla, R.; Membranes of 5,10,15,20-Tetrakis(4-Methoxyphenyl) Porphyrinatocobalt(TMOPP-Co) (I) as MoO42-– Selective Sensors. Sensors 2, 2002, 164-173. https://doi.org/10.3390/s20500164 3.) Zhou, Y., Xing, Y.F., Wen, J., Ma, H.B., Wang, F.B., Xia, X.H.; Axial ligands tailoring the ORR activity of cobalt porphyrin. Science Bulletin64, 2019, 1158-1166. https://doi.org/10.1016/j.scib.2019.07.003 4.) Wang, Y.H., Schneider, P.E., Goldsmith, Z.K., Mondal, B., Hammes-Schiffer, S., Stahl, S.S. Bronsted Acid Scaling Relationships Enable Control Over Product Selectivity from O2Reduction with a Mononuclear Cobalt Porphyrin Catalyst. ACS Cent. Sci. 2019, 5, 6, 1024-1034. https://doi.org/10.1021/acscentsci.9b00194 5.) Chambers, D.R., Juneau, A., Ludwig, C.T., Frenette, M., Martin, D.B.C.; C-O Bond Cleavage of Alcohols via Visible Light Activation of Cobalt Alkoxycarbonyls. Organometallics2019, 38, 24, 4570-4577. https://doi.org/10.1021/acs.organomet.9b00552 6.) Tripathi, D., Yadav, I., Negi, H., Singh, R.K., Srivastava, V.C., Sankar, M.; Highly efficient Co(II) porphyrin catalysts for the extractive oxidative desulfurization of dibenzothiophene in fuel oils under mild conditions. Journal of porphyrins and Phthalocyanines 2021, 25, 1, 24-30. https://doi.org/10.1142/S1088424620500443 7.) Jiang, Q., Sheng, W., Tian, M., Tang, J., Guo, C.; Cobalt(II)-Porphyrin-Catalyzed Aerobic Oxidation: Oxidative Coupling of Phenols. Joc. 2013, 10, 1861-1866. https://doi.org/10.1002/ejoc.201201595 8.) Huang, L., Chen, Y., Gao, G.Y., Zhang, X.P.; Diastereoselective and Enantioselective Cyclopropanation of Alkenes Catalyzed by Cobalt Porphyrins. Org. Chem. 2003, 68, 21, 8179-8184. https://doi.org/10.1021/jo035088o

    合成参考文献


    参考文献:10.1007/s13361-017-1783-z
    摘要:Castellanos-García LJ, Agudelo BC, Rosales HF, Cely M, Ochoa-Puentes C, Blanco-Tirado C, Sierra CA, Combariza MY. Oligo p-Phenylenevinylene Derivatives as Electron Transfer Matrices for UV-MALDI. Journal of The American Society for Mass Spectrometry. 2017 Sep 06;28(12):2548–60. doi: 10.1007/s13361-017-1783-z.
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