CAS: 1767-46-0; (S)-4-Methylhexan-1-Ol
该化合物是一种具有分子式C7H16O的手性二次酒精.这种对应纯度化合物的特征是其四级立体中心,它对于不对称合成和人工解析研究很有价值.它定义的立体化学确保了反应的高度选择性,特别是在合成药品,香味和特殊化学品方面.该化合物在普通有机溶剂中表现出中等的挥发性和溶性,便于其用于催化和口腔测量应用.其光学纯度和一贯性能使它成为需要精确立体化学控制的研究的首选.建议在惰性条件下进行适当的处理以保持稳定性.
- 英文名称(S)-4-Methylhexan-1-Ol
- 中文名称(S)-(+)-4-甲基-1-己醇
- IUPAC名称(S)-4-methylhexan-1-ol
- 其它别名1-Hexanol,4-methyl-, (+)- (8CI); 1-Hexanol, 4-methyl-, (S)-; (+)-(4S)-Methylhexan-1-ol; (S)-(+)-4-Methyl-1-hexanol; (S)-4-Methyl-1-hexanol; (S)-4-Methylhexyl alcohol
- CAS编号1767-46-0
- MFCD编号:MFCD00221492
- 分子式:C7H16O分子量:116.2
- 产品CID: 900664
- 产品分类有机原料 → 醇,酚,酚醇类化合物及衍生物
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: YNPVNLWKVZZBTM-ZETCQYMHSA-N
- InChI=1S/C7H16O/c1-3-7(2)5-4-6-8/h7-8H,3-6H2,1-2H3/t7-/m0/s1
- 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数4.0
物理性质
上下游产品
CAS号1730-89-8 (S)-(+)-4-METHY... | CAS号32751-95-4 (4S)-4-methylhexanal | CAS号873798-62-0 isopropyl (R)-4... | CAS号6210-80-6 ethyl (S)-4-met... | CAS号534-00-9 (S)-1-溴-2-甲基丁烷 | CAS号6210-82-8 diethyl S-(+)-2... | CAS号1565-80-6 S(-)-2-甲基-1-丁醇 | CAS号7492-90-2 (S)-(+)-1-BROMO... | CAS号60711-13-9 (S)-(+)-2,6-dim... | CAS号2385-77-5 (R)-(+)-香茅 | CAS号34263-68-8 4-methylhexan-1... | CAS号16197-41-4 (4S)-4-methylhe... | CAS号1561-11-1 4-甲基乙酸 | CAS号1730-89-8 (S)-(+)-4-METHY... | CAS号7492-90-2 (S)-(+)-1-BROMO...合成工艺路线路线简述
📜(+)-香茅醛置于硼酸三钠,臭氧,一水合肼,溶剂黄146,二乙二醇体系中,化学反应生成(S)-(+)-4-甲基-1-己醇
参考文献:Optical Rotatory Dispersion Studies. Xxiv.1 Effect Of Distance Of A Single Asymmetric Center From An Aliphatic Carbonyl Function2
标题:Optical Rotatory Dispersion Studies. Xxiv.1 Effect Of Distance Of A Single Asymmetric Center From An Aliphatic Carbonyl Function2
摘要:
Doi:10.1021/ja01520A045
海关参考信息
- 2905121000-正丙醇
2905130000-正丁醇
2901100000-饱和无环烃 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
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主要参考文献
参考标题:Biosynthesis Of Mycotoxin Fusaric Acid And Application Of A Plp-Dependent Enzyme For Chemoenzymatic Synthesis Of Substituted作者:Yang Hai,Mengbin Chen,Arthur Huang,Yi Tang |发布日期:2020.11.18
摘要:Synthesizing The Picolinic Acid Scaffold. Fa Biosynthesis Also Involves An Off-Line Collaboration Between A Highly Reducing Polyketide Synthase (Hrpks, Fub1) And A Nonribosomal Peptide Synthetase (Nrps)-Like Carboxylic Acid Reductase (Fub8) In Making An Aliphatic α,β-Unsaturated Aldehyde. By Harnessing The Stereoselective C-C Bond-Forming Activity Of Fub7, We Established A Chemoenzymatic Route For Stereoconvergent
合成参考文献
参考文献:10.1007/s00253-010-2446-1
摘要:Clomburg JM, Gonzalez R. Biofuel production in Escherichia coli: the role of metabolic engineering and synthetic biology. Applied Microbiology and Biotechnology. 2010 Feb 09;86(2):419–34. doi: 10.1007/s00253-010-2446-1.
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