CAS: 1121-49-9; (Bromomethylene)Cyclohexane

该化合物是高纯度的化学化合物, 具有特殊的稳定性和反应性. 它精确的96%的纯度能确保各种应用的可靠性能, 包括有机合成和研究. 它因其独特的化学特性而得到青睐, 成为化学研究与开发的宝贵工具.

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上下游产品

CAS号1034-49-7 (溴甲基)三苯基溴化鏻 | CAS号108-94-1 环己酮 | CAS号60014-80-4 1-dibromomethyl... | CAS号52183-68-3 1-(dibromomethy... | CAS号849728-00-3 ethyl hydrogen ... | CAS号53282-32-9 trifluoromethyl... | CAS号75-63-8 三氟溴甲烷 | CAS号931-51-1 环己基氯化镁 | CAS号60014-85-9 dibromomethylid... | CAS号591-49-1 1-甲基-1-环己烯 | CAS号184-26-9 1,4-dioxaspiro[... | CAS号1192-37-6 亚甲基环己烷 | CAS号1552-91-6 2-环己基亚基乙酸 | CAS号1608-31-7 Cyclohexylidene... | CAS号53723-48-1 2-cyclohexylide... | CAS号88924-29-2 tributyl(cycloh... | CAS号88931-02-6 3-(2-cyclohexyl...

合成工艺路线路线简述

  • 合成目标产物 Bromomethylenecyclohexane 96 主要起始原料 Cyclohexane, (Dibromomethylene)-
  • (文献来源)合成步骤主要原料 Cyclohexane, (Dibromomethylene)-
📜1-溴-1-溴甲基环己烷置于potassium Tert-Butylate体系中,用 叔丁醇 用作溶剂,化学反应生成溴亚甲基环己烷
参考文献:Bromomethylenecycloalkanes
标题:Bromomethylenecycloalkanes
摘要:
Doi:10.1021/jo01018A021

海关参考信息

专利信息


专利号:US-4964846-A
优先权日:1986-05-16
标 题 :Process for the E/Z stereoselective synthesis of homochiral five and six ring intermediate products
发明人：GAIS HANS-JOACHIM; ERDELMEIER IRENE; BIRK ROLF
权利人:SCHERING AG
摘要:This invention comprises a process for the production of unsymmetrical olefins from prochiral symmetrical ketones by addition of lithiosulfoximine from n-butyllithium and N-substituted S-methyl-S-phenyl-sulfoximine derivatives and then reaction with n-butyllithium/trimethychlorosilane.

专利号:US-8952207-B2
优先权日:2007-09-11
标题:Copper-catalyzed C—H bond arylation
发明人：DAUGULIS OLAFS; DO HIEN-QUANG
权利人:DAUGULIS OLAFS; DO HIEN-QUANG; UNIV HOUSTON SYSTEM
摘要:The present invention is a one-step method for efficiently converting carbon-hydrogen bonds into carbon-carbon bonds using a combination of aryl halides, a substrate, and a copper salt as catalyst. This method allows faster introduction of complex molecular entities, a process that would otherwise require many more steps. This invention is particularly relevant for the organic synthesis of complex molecules such as, but not limited to, pharmacophores and explosives.

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主要参考文献

参考标题:Synthesis Of Alkenyl Sulfides Through The Iron-Catalyzed Cross-Coupling Reaction Of Vinyl Halides With Thiols
作者:Yun-Yung Lin,Yu-Jen Wang,Che-Hung Lin,Jun-Hao Cheng,Chin-Fa Lee |发布日期:2012.7.20
摘要:Here The Iron-Catalyzed Cross-Coupling Reaction Of Alkyl Vinyl Halides With Thiols. While Many Works Are Devoted To The Coupling Of Thiols With Alkyl Vinyl Iodides, Interestingly, The Known S-Vinylation Of Vinyl Bromides And Chlorides Is Limited To 1-(2-Bromovinyl)Benzene And 1-(2-Chlorovinyl)Benzene. Investigation On The Coupling Reaction Of Challenging Alkyl Vinyl Bromides And Chlorides With Thiols

合成参考文献


摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 47, 443.
摘要:Sandrock, D. L., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 333.
摘要:Corcé, V.; Lévêque, C.; Ollivier, C.; Fensterbank, L., Science of Synthesis: Photocatalysis in Organic Synthesis, (2018) 1, 452.
摘要:Primer, D. N.; Molander, G. A., Science of Synthesis, (2019) , 261.
摘要:Ho, C.-Y.; Raja, D., Science of Synthesis: Knowledge Updates, (2023) 1, 91.
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