CAS: 934545-83-2; 3-Bromo-9-(Naphthalen-1-yl)-9H-Carbazole

该化合物是一种有机化合物,其结构复杂,包括一个碳氮核心,以溴原子和环烷基组取代,该化合物通常具有与芳香化合物和热循环化合物相关的特性,包括因其广泛的同化系统而具有稳定性和潜在欧元叠叠相互作用;溴原子的存在会引入卤化,从而影响其再活性和溶解于各种溶剂;此外,环烷基子组成可增强该化合物的光物理特性,使其对有机电子学,发光二极体等应用感兴趣,并成为有机合成中的潜在构件;该化合物的分子结构还可能具有特定的电子特性,可在各种化学和材料科学应用中加以利用.

英文名称3-Bromo-9-(Naphthalen-1-yl)-9H-Carbazole
中文名称3-溴-N-(1-萘基)咔唑
IUPAC名称3-bromo-9-(naphthalen-1-yl)-9H-carbazole
其它别名3-溴-9-(萘-1-基)-9H-咔唑; 9H-Carbazole, 3-Bromo-9-(1-Naphthalenyl)-
CAS编号934545-83-2
MFCD编号:MFCD26127423
EINECS号:834-907-5
分子式:C22H14BrN
分子量:372.26
产品CID: 1974018
产品分类有机原料→分子砌块→芳杂环类化合物→咔唑类化合物

相似结构搜索
InChIKey: QTWVKYHIDBPQIL-UHFFFAOYSA-N
InChI=1S/C22H14BrN/c23-16-12-13-22-19(14-16)18-9-3-4-10-21(18)24(22)20-11-5-7-15-6-1-2-8-17(15)20/h1-14H…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

相似化合物

22034-43-1 929103-28-6 257288-83-8

物理性质

沸点545.2±32.0 °C at 760 mmHg
闪点283.5±25.1 °C
密度1.4±0.1 g/cm3
PSA:4.93
LogP:6.6994
折射率1.694
蒸汽压0.0±1.5 mmHg at 25°C
外观形态白色至几乎白色粉末至晶体
储存条件密封, 常温干燥保存
产品应用该化合物用作有机发光二极管(OLEDS)传导层的散射材料,提供符合OLED设备制造商要求的有利光电子特性,特别是生产OLD显示板和OLEM照明产品的制造商.

欧盟法规

C&L通报

上下游产品

9-(1-萘基)-咔唑 9-(Naphthalen-1-yl)-9H-Carbazole 22034-43-1
3-溴咔唑 3-Bromo-9H-Carbazole 1592-95-6

合成工艺路线路线简述

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Copper Solvents: Toluene; Rt -> 150 °C; 24 H,150 °C
标题:Preparation Of Anthracene-Based Compounds Useful As Electroluminescent Material In Oled
参考文献:China]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Triphenylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 100 °C
标题:Preparation Of Carbazole Compounds As Organic Electronic Device Materials
参考文献:World Intellectual Property Organization]

22034-43-1 = 934545-83-2
反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dichloromethane; 12 H,Rt1.2 Reagents: Water; Rt
标题:Triazine-Based Compounds And Organic Light-Emitting Devices Including Triazine-Based Compounds
参考文献:United States]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Triphenylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 100 °C
标题:Carbazole Compounds As Organic Electronic Device Materials
参考文献:Korea]

22034-43-1 = 934545-83-2
反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dichloromethane; Rt; 24 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Rt
标题:Organic Light-Emitting Device
参考文献:United States]

= 934545-83-2 [标题:Reaction Conditions
标题:Preparation Of Carbazole Compounds For Electronic Device
参考文献:Korea]

22034-43-1 = 934545-83-2
反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Toluene,Ethyl Acetate; 36 H,Rt
标题:Organic Compounds,Light-Emitting Components,Light-Emitting Devices,Electronic Devices,And Lighting Devices
参考文献:European Patent Organization]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Catalysts: Tributylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene,Water; 12 H,Rt
标题:Organic Light-Emitting Devices And Displays With Emitting Layers Employing Multiple Hosts
参考文献:United States]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Copper,18-Crown-6 Solvents: Dimethylformamide; 24 H,140 °C
标题:Preparation Of Carbazole Compounds For Electronic Device
参考文献:World Intellectual Property Organization]

22034-43-1 = 934545-83-2
反应条件:1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl Peroxide Solvents: Dichloromethane; Rt
标题:Organic Electronic Element Containing Light Efficiency Improving Layer And Electronic Device Containing The Same
参考文献:Korea]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
标题:Heteroaryl Compounds As Organic Electronic Device Materials
参考文献:World Intellectual Property Organization]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
标题:Carbazole Compounds For Organic Electronic Device
参考文献:Korea]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Triphenylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 100 °C
标题:Preparation Of Heteroaromatic Compound For Organic Electronic Element And Electronic Device Thereof
参考文献:World Intellectual Property Organization]

1592-95-6 + 90-14-2 = 934545-83-2
反应条件:1.1 Reagents: Potassium Carbonate,Sodium Sulfate Catalysts: Copper Solvents: Nitrobenzene; 200 °C
标题:Carbazole Compounds As Capping Layer Materials And Electronic Device Thereby
参考文献:Korea]

= 934545-83-2 [标题:Reaction Conditions
标题:Preparation Of Arylamine Compounds For Organic Electroluminescent Devices And Display Devices
参考文献:Korea

9-(1-萘基)-咔唑置于n-溴代丁二酰亚胺(Nbs)体系中,用乙酸乙酯,甲苯作为反应溶剂,化学反应 36.0H,以99%的收率获得产物3-溴-N-(1-萘基)咔唑
参考文献:Organic Compound,Light-Emitting Element,Light-Emitting Device,Electronic Device,And Lighting Device
标题:Organic Compound,Light-Emitting Element,Light-Emitting Device,Electronic Device,And Lighting Device
摘要:提供一种新型物质,可以实现发光元件寿命和发射效率的提高.提供一种具有通用式(g1)表示的结构的咔唑化合物.请注意,在通用式(g1)中,使取代基的homo能级和lumo能级分别变深和变浅的取代基被用作每个取代基(r1,R2,Ar3和α3).此外,在通用式(g1)中,使取代基的带隙(bg)和t1能级分别变宽和变高的取代基被用作每个取代基(r1,R2,Ar3和α3).