CAS: 82-44-0; 1-Chloroanthraquinone

• 英文名称1-Chloroanthraquinone
• 中文名称1-氯蒽醌
• IUPAC名称1-chloroanthracene-9,10-dione
• 其它别名1-氯代蒽醌; α氯代蒽醌; Anthraquinone, 1-Chloro-
• CAS编号82-44-0
• MFCD编号:MFCD00001189
• EINECS号:201-421-4
• 分子式:C14H7ClO2
• 分子量:242.66
• 产品CID: 1815136
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: BOCJQSFSGAZAPQ-UHFFFAOYSA-N
• InChI=1S/C14H7ClO2/c15-11-7-3-6-10-12(11)14(17)9-5-2-1-4-8(9)13(10)16/h1-7H…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数0.0

物理性质

• 熔点159-160°C
• 沸点345.65 °C at 760 mmHg
• 闪点179.7±26.2 °C
• 密度1.4±0.1 g/cm3
• PSA:34.14
• LogP:3.1154
• 折射率1.666
• 蒸汽压0.0±1.0 mmHg at 25°C
• 溶解性Soluble In Hot Toluene. (Almost Transparency)
• 敏感性有毒。原料蒽醌能引起过敏性湿疹、鼻炎、支气管哮喘，反应设备应密闭，车间保持良好通风状态。
• 外观形态淡黄色至黄色粉末或块状物
• 储存条件存储低于 +30°C.
• 产品应用用作蒽醌还原染料及其他蒽醌染料的中间体,如还原棕BR染料.质量指标:外观淡黄色结晶粉末含量≥99.0熔点≥154°C汞含量≤0.5ppm水份≤0.5
• 性质描述黄色针状结晶或结晶性粉末.升华.熔点162°C.溶于醋酸,硝基苯,戊醇和热苯,微溶于热乙醇,不溶于水.在浓硫酸中呈灰黄色.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生慢性毒性 类别3
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H412 |对水生生物有害并具有长期持续影响.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xi
• 安全声明26-37/39-24/25
• 危险类别码36/37/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 1-Chloro Anthraquinone 主要起始原料 3-Chlorophthalic Anhydride
• 84-65-1 = 82-44-0 + 82-46-2 + 727-51-5 + 131-09-9 + 1594-69-0
  反应条件:1.1 Reagents: Fuming Sulfuric Acid Catalysts: Mercury Sulfate; 3 H,120 °C1.2 Reagents: Sodium Chlorate Solvents: Water; 2 H,100 °C
  标题:Anthraquinone Derivatives
  参考文献:Federal Republic Of Germany]
  
  84-65-1 = 82-44-0 + 82-46-2 + 727-51-5 + 131-09-9 + 1594-69-0
  反应条件:1.1 Reagents: Fuming Sulfuric Acid Catalysts: Mercury Sulfate; 3 H,120 °C1.2 Reagents: Sodium Chlorate Solvents: Water; 4 H,100 °C; 2 H,100 °C
  标题:Chloroanthraquinones
  参考文献:Federal Republic Of Germany]
  
  129-39-5 + 605-28-7 + 1604-40-6 = 82-44-0 + 82-46-2 + 605-40-3 + 727-51-5 + 131-09-9 + 1594-69-0 + 605-43-6
  反应条件:1.1 Reagents: Chlorine Catalysts: Phthalic Anhydride; 6 H,195 - 200 °C
  标题:Chloroanthraquinones
  参考文献:Federal Republic Of Germany]
  
  = 82-44-0
  反应条件:1.1 Reagents: Sodium Periodate Solvents: Ethyl Acetate,Water; 2 Min,Rt1.2 20 Min,Rt
  标题:Carbon-Carbon Cleavage Of Aryl Diamines And Quinone Formation Using Sodium Periodate. A Novel Application
  作者:Telvekar,Vikas N.; Et Al
  参考文献:Tetrahedron Letters 日期:2010 卷标:51(30) 页码:3940-3943]
  
  = 82-44-0
  反应条件:1.1 Reagents: Chlorine; 90 Min,240 °C
  标题:Halogenated Anthraquinones
  参考文献:Federal Republic Of Germany]
  
  = 82-44-0
  反应条件:1.1 Reagents: Tert-Butyl Nitrite,Cupric Chloride Solvents: Acetonitrile; 1.5 H,70 °C
  标题:Synthesis Of Mesodiphenylhelianthrene From 1-Aminoanthraquinone And The Structural Elucidation Of Its Endoperoxide Species After Irradiation
  作者:Feng,Sheng-Jan; Et Al
  参考文献:Organic Letters 日期:2022 卷标:24(29) 页码:5266-5270]
  
  = 82-44-0
  反应条件:1.1 Reagents: Oxygen Catalysts: Vanadium Oxide (V2O5),Thallium(I) Nitrate; 430 °C
  标题:Halogen-Substituted Anthraquinones
  参考文献:Federal Republic Of Germany]
  
  = 82-44-0
  反应条件:1.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux
  标题:Synthesis And Characterization Of 1-Phenoxy-9,10-Anthraquinones
  作者:Hu,Shi-Rong; Et Al
  参考文献:Organic Chemistry: An Indian Journal 日期:2008 卷标:4(3) 页码:210-213]
  
  = 82-44-0
  反应条件:1.1 Catalysts: 12-Tungstosilicic Acid
  标题:Preparation Of Anthraquinones
  参考文献:Japan]
  
  = 82-44-0
  反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; Rt
  标题:Oxidations In The Light
  作者:Eckert,Alfred
  参考文献:Berichte Der Deutschen Chemischen Gesellschaft [abteilung] B: Abhandlungen 日期:1927 卷标:60 页码:1691-3]
  
  183874-11-5 = 82-44-0
  反应条件:1.1 Reagents: Sulfuric Acid Solvents: Acetic Acid,Water1.2 Reagents: Water1.3 Reagents: Sodium Bicarbonate Solvents: Water2.1 Reagents: Potassium Dichromate Solvents: Acetic Acid,Water
  标题:Application Of Organolithium And Related Reagents In Synthesis. Part Xvi. Synthetic Strategies Based On Aromatic Metalation. A Concise Regiospecific Conversion Of Chlorobenzoic Acids Into Their Benzylated Derivatives
  作者:Epsztajn,J.; Et Al
  参考文献:Monatshefte Fuer Chemie 日期:1996 卷标:127 页码:701-715]
  
  = 82-44-0
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran1.2 -1.3 Reagents: Water2.1 Reagents: Sulfuric Acid Solvents: Acetic Acid,Water2.2 Reagents: Water2.3 Reagents: Sodium Bicarbonate Solvents: Water3.1 Reagents: Potassium Dichromate Solvents: Acetic Acid,Water
  标题:Application Of Organolithium And Related Reagents In Synthesis. Part Xvi. Synthetic Strategies Based On Aromatic Metalation. A Concise Regiospecific Conversion Of Chlorobenzoic Acids Into Their Benzylated Derivatives
  作者:Epsztajn,J.; Et Al
  参考文献:Monatshefte Fuer Chemie 日期:1996 卷标:127 页码:701-715]
  
  81-64-1 = 82-44-0
  反应条件:1.1 Reagents: Zinc Solvents: Acetic Acid; 1 H,Reflux2.1 Reagents: Zinc Solvents: Acetic Acid; 24 H,Reflux2.2 Reagents: Water3.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux3.2 Reagents: Water; 0 °C
  标题:Study On Synthesis And Photochromism Of 1-Phenoxy-9,10-Anthraquinone
  作者:Jiang,Shulian
  参考文献:Yingyong Huagong 日期:2011 卷标:40(12) 页码:2059-2062]
  
  = 82-44-0
  反应条件:1.1 Reagents: Sulfur1.2 Solvents: Benzene
  标题:Reaction Of Anthrone And Its 1- And 4-Substituted Derivatives With Sulfur In The Presence Of Nucleophiles
  作者:Loskutov,V. A.
  参考文献:Russian Journal Of Organic Chemistry (Translation Of Zhurnal Organicheskoi Khimii) 日期:2000 卷标:36(10) 页码:1478-1481]
  
  82-49-5 + 14486-58-9 + 82-48-4 = 82-44-0 + 82-46-2 + 727-51-5 + 131-09-9 + 1594-69-0
  反应条件:1.1 Reagents: Sodium Chlorate Solvents: Water; 4 H,100 °C; 2 H,100 °C
  标题:Treatment Of Waste Waters
  参考文献:Federal Republic Of Germany]
  
  128-56-3 = 82-44-0
  反应条件:1.1 Reagents: Hydrochloric Acid,Sulfuric Acid,Sodium Chlorate,Ammonium Chloride Solvents: Water; 4 H,Reflux
  标题:Chlorination Of Anthraquinone Sulfonic Acids
  参考文献:United States]
  
  82-46-2 = 82-44-0
  反应条件:1.1 Reagents: Indium Solvents: 1-Butyl-3-Methylimidazolium Bromide; 5 H,95 °C
  标题:Efficient Indium-Mediated Dehalogenation Of Aromatics In Ionic Liquid Media
  作者:Canete,Alvaro F.; Et Al
  参考文献:Molecules 日期:2013 卷标:18 页码:398-407]
  
  82-46-2 = 82-44-0 [标题:Reaction Conditions
  标题:The Ullmann Reaction Of 1,5-Dichloroanthraquinone
  作者:Tokita,Sumio; Et Al
  参考文献:Nippon Kagaku Kaishi 日期:1981 卷标:(6) 页码:984-8]
  
  = 82-44-0
  反应条件:1.1 Reagents: Iodobenzene Diacetate Solvents: Acetone; 10 Min,Rt1.2 Reagents: Water; Rt
  标题:A Novel Application Of (Diacetoxyiodo)Benzene For Carbon-Carbon Cleavage Of Aryl Diamines And Synthesis Of Quinones
  作者:Telvekar,Vikas N.; Et Al
  参考文献:Synlett 日期:2010 卷标:(14) 页码:2059-2062]
  
  = 82-44-0
  反应条件:1.1 Reagents: Potassium Dichromate Solvents: Acetic Acid,Water
  标题:Application Of Organolithium And Related Reagents In Synthesis. Part Xvi. Synthetic Strategies Based On Aromatic Metalation. A Concise Regiospecific Conversion Of Chlorobenzoic Acids Into Their Benzylated Derivatives
  作者:Epsztajn,J.; Et Al
  参考文献:Monatshefte Fuer Chemie 日期:1996 卷标:127 页码:701-715]
  
  52868-88-9 = 82-44-0
  反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Chlorate Solvents: Water
  标题:α-Chloroanthraquinone
  作者:Scott,W. J.; Et Al
  参考文献:Organic Syntheses 日期:1938 卷标:18 页码:15-16]
  
  4888-02-2 = 82-44-0
  反应条件:1.1 Reagents: Hydrazine,Phenyl-,Sulfur1.2 Solvents: Water
  标题:Reaction Of Anthrone And Its 1- And 4-Substituted Derivatives With Sulfur In The Presence Of Nucleophiles
  作者:Loskutov,V. A.
  参考文献:Russian Journal Of Organic Chemistry (Translation Of Zhurnal Organicheskoi Khimii) 日期:2000 卷标:36(10) 页码:1478-1481]
  
  = 82-44-0
  反应条件:1.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux1.2 Reagents: Water; 0 °C
  标题:Study On Synthesis And Photochromism Of 1-Phenoxy-9,10-Anthraquinone
  作者:Jiang,Shulian
  参考文献:Yingyong Huagong 日期:2011 卷标:40(12) 页码:2059-2062]
  
  17648-03-2 = 82-44-0
  反应条件:1.1 Reagents: Zinc Solvents: Acetic Acid; 24 H,Reflux1.2 Reagents: Water2.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux2.2 Reagents: Water; 0 °C
  标题:Study On Synthesis And Photochromism Of 1-Phenoxy-9,10-Anthraquinone
  作者:Jiang,Shulian
  参考文献:Yingyong Huagong 日期:2011 卷标:40(12) 页码:2059-2062]
  
  17648-03-2 = 82-44-0
  反应条件:1.1 Reagents: Zinc Solvents: Acetic Acid; 24 H,Reflux2.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux
  标题:Synthesis And Characterization Of 1-Phenoxy-9,10-Anthraquinones
  作者:Hu,Shi-Rong; Et Al
  参考文献:Organic Chemistry: An Indian Journal 日期:2008 卷标:4(3) 页码:210-213]
  
  81-64-1 = 82-44-0
  反应条件:1.1 Reagents: Zinc Solvents: Acetic Acid; 60 Min,Reflux2.1 Reagents: Zinc Solvents: Acetic Acid; 24 H,Reflux3.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux
  标题:Synthesis And Characterization Of 1-Phenoxy-9,10-Anthraquinones
  作者:Hu,Shi-Rong; Et Al
  参考文献:Organic Chemistry: An Indian Journal 日期:2008 卷标:4(3) 页码:210-213]
  
  = 82-44-0
  反应条件:1.1 Reagents: Sulfuric Acid,Boric Acid (H3Bo3); 1 H,165 °C; 0.5 H,165 °C -> 190 °C1.2 Reagents: Water2.1 Reagents: Zinc Solvents: Acetic Acid; 1 H,Reflux3.1 Reagents: Zinc Solvents: Acetic Acid; 24 H,Reflux3.2 Reagents: Water4.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux4.2 Reagents: Water; 0 °C
  标题:Study On Synthesis And Photochromism Of 1-Phenoxy-9,10-Anthraquinone
  作者:Jiang,Shulian
  参考文献:Yingyong Huagong 日期:2011 卷标:40(12) 页码:2059-2062]
  
  = 82-44-0
  反应条件:1.1 Reagents: Sulfuric Acid,Boric Acid (H3Bo3) Solvents: Water; 60 Min,165 °C; 30 Min,165 °C -> 190 °C2.1 Reagents: Zinc Solvents: Acetic Acid; 60 Min,Reflux3.1 Reagents: Zinc Solvents: Acetic Acid; 24 H,Reflux4.1 Reagents: Phosphorus Oxychloride,Phosphorus Pentachloride; 24 H,Reflux
  标题:Synthesis And Characterization Of 1-Phenoxy-9,10-Anthraquinones
  作者:Hu,Shi-Rong; Et Al
  参考文献:Organic Chemistry: An Indian Journal 日期:2008 卷标:4(3) 页码:210-213

海关参考信息

• 2903919090-氯苯
  2912110000-甲醛
  2912210000-苯甲醛
  2914610000-蒽醌
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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