CAS: 4313-57-9; 1-Methyl-1,4-Cyclohexadiene

上下游产品

CAS号108-88-3 甲苯 | CAS号100-51-6 苯甲醇 | CAS号84194-54-7 Bicyclo[4.1.0]h... | CAS号103-50-4 二苄醚 | CAS号100-52-7 苯甲醛 | CAS号78-79-5 异戊二烯 | CAS号88946-47-8 3-trimethylsily... | CAS号611-45-0 1-Benzylnaphthalene | CAS号67-56-1 甲醇 | CAS号7664-41-7 氨 | CAS号591-49-1 1-甲基-1-环己烯 | CAS号591-47-9 4-甲基-1-环己烯 | CAS号82166-21-0 2-methyl cyclohexane | CAS号591-48-0 3-甲基-1-环己烯 | CAS号108-88-3 甲苯 | CAS号89-71-4 邻甲基苯甲酸甲酯 | CAS号73588-12-2 methyl (E)-3-(6... | CAS号34284-44-1 1-methoxy-1-met... | CAS号138714-09-7 trans-1,4-Dimet...

📜苯甲醇置于氨,Lithium,叔丁醇体系中,用 四氢呋喃 作为反应溶剂,以54%的收率获得产物1-甲基-1,4-环己二烯
参考文献:轻度条件下苯并位的苯衍生物的还原带有氧原子
标题:轻度条件下苯并位的苯衍生物的还原带有氧原子
摘要:通过使用t-Buoh,Li和气态nh 3将苄基位置带有o原子的化合物(例如苄醇,二苄基醚,氧化苯乙烯,苯甲醛,苯乙酮和二苯甲酮)还原为相应的非共轭二烯.在室温下于thf中.在这些还原中,观测到苄基位置上的官能团首先被还原.
DOI:10.1002/hlca.200890250

专利信息

专利号:US-7691635-B2
优先权日:2004-03-26
标题 :Labeling reagents, methods for the synthesis of such reagents and methods for the detection of biological molecules
发明人：LAAYOUN ALI; BERNAL-MENDEZ ELOY
权利人:BIOMERIEUX SA
摘要:The present invention relates to a temperature-stable labeling reagent of formula (0): n nin which:n R 1 represents H or an alkyl, aryl or substituted aryl group, R 2 represents a detectable marker or at least two detectable markers interlinked by at least one multimeric structure, L is a linker arm comprising a linear chain of at least two covalent bonds and n is an integer equal to 0 or 1, R 3 and R 4 represent, independently of one another: H, NO 2 , Cl, Br, F, I, R 2 -(L) n -Y—X—, OR, SR, NR 2 , R, NHCOR, CONHR, COOR, —CO—NH—(CH 2 ) 3 —(O—CH 2 —CH 2 ) 3 —CH 2 —NH—R 2 , —CO—NH—(CH 2 ) 3 —(O—CH 2 —CH 2 ) 4 —CH 2 —NH—R 2 with R=alkyl or aryl, A is a linker arm comprising at least one covalent double bond enabling the conjugation of the diazo function with the aromatic ring and u is an integer between 0 and 2, preferably 0 or 1, —Y—X— represents —CONH—, —NHCO—, —CH 2 O—, —CH 2 S—, —Z— represents —NH—, —NHCO—, —CONH— or —O—, m is an integer between 1 and 10, preferably between 1 and 3, and p is an integer between 1 and 10, preferably between 1 and 3. n The present invention also describes a method for the synthesis of said labels and also applications for the labeling of biological molecules, in particular of nucleic acids, with a labeling reagent bearing the diazomethyl function. n The invention is particularly suitable for use in the field of diagnostics.

专利号:US-2023250053-A1
优先权日:2020-06-24
标 题:Process for synthesizing targeting molecules
发明人：SHI ZHONGPING; TAN YICHEN; LORA GONZALEZ FEDERICO; CARRASQUILLO-FLORES RONALD; SMITH MICHAEL J
权利人:BRISTOL MYERS SQUIBB CO
摘要:The present application provides processes for synthesizing targeting molecules of Formula (I) comprising a retinoid moiety useful in the synthesis of fat-soluble compounds for targeting and enhancing activity of therapeutic molecules, including siRNA.

专利号:US-2024182430-A1
优先权日:2022-11-28
标 题 :Synthesis of substituted pyrazines
发明人：ROGERS THOMAS E; BUCK ERIC
权利人:MEDIBEACON INC
摘要:Described herein are methods to form substituted pyrazines. Also described herein are methods to purify substituted pyrazines.

专利号:WO-2014064476-A1
优先权日:2012-10-24
标 题 :The synthesis of tetrahydroisoquinolines from 2-methyl-1-phenyl substituted indenes

专利号:WO-2010129520-A1
优先权日:2009-05-06
标题 :Solid support for fmoc-solid phase synthesis of peptide acids

专利号:WO-2015007693-A1
优先权日:2013-07-15
标 题:Method and apparatus for the synthesis of dihydroartemisinin and artemisinin derivatives