CAS: 403842-84-2; 1-Methyl-3-N-Octylimidazolium Trifluoromethanesulfonate

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412009-62-2 460345-16-8 174899-66-2

上下游产品

CAS号616-47-7 N-甲基咪唑 | CAS号111-83-1 1-溴代正辛烷 | CAS号2926-27-4 三氟甲磺酸钾 | CAS号21252-69-7 1-辛基咪唑 | CAS号333-27-7 三氟甲烷磺酸甲酯 | CAS号64697-40-1 1-甲基-3-辛基氯化咪唑鎓 | CAS号111-85-3 氯辛烷 | CAS号1493-13-6 三氟甲烷磺酸

📜1-溴辛烷 以 水,乙腈 作为反应溶剂,化学反应生成 1-甲基-3-辛基咪唑三氟甲烷磺酸
参考文献:离子液体中铜催化点击反应的动力学研究
标题:离子液体中铜催化点击反应的动力学研究
摘要:铜(I)催化的叠氮化物-炔烃环加成(Cuaac)反应在化学合成中受到广泛关注.虽然近年来人们广泛探索使用离子液体(il)作为合成溶剂,但对其对 Cuaac 反应机理和反应性的影响仍知之甚少.在这里,我们研究了苯乙炔-苄基叠氮化物和乙炔-苄基叠氮化物 Cuaac 反应的动力学,以探讨 Il 结构的影响,包括用于促进反应的碱的作用和水含量的重要性."湿"离子液体的使用消除了初始诱导期,导致反应动力学曲线发生显着变化.发现反应速率取决于铜(I)源.还研究了添加碱的影响,使用带有叔胺的 Il 可以在环境温度下 5 分钟内实现高转化.这项研究的结果强调了离子液体中 Cuaac 反应的性质和复杂性.随着越来越多的离子液体参与工业过程,从这项研究中获得的数据对于更好地了解影响离子液体介质中 Cuaac 反应的过程以及创建有机合成定制系统非常有价值,从而提高此类过程的效率和可持续性.
DOI:10.1039/d3Ob00237C

专利信息

专利号:US-9267213-B1
优先权日:2005-03-25
标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
发明人：MAURER KARL; COOPER JOHN J
权利人:CUSTOMARRAY INC
摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

专利号:US-9126848-B2
优先权日:2009-12-29
标题:Synthesis of nanoparticles by means of ionic liquids
发明人：DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL
权利人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL; LEIBNIZ INSITUT FUER NEUE MATERIALIEN GEMEINNUETZIGE GMBH
摘要:A method for producing nanoscale particles by means of ionic liquids produces highly crystalline particles. The ionic liquids can be easily regenerated.

专利号:WO-2023113033-A1
优先权日:2021-12-16
标题 :Gas diffusion electrode
发明人：KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
权利人:NISSAN CHEMICAL CORP
摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.

专利号:US-2012275991-A1
优先权日:2009-12-29
标 题:Synthesis of Nanoparticles by Means of Ionic Liquids

专利号:EP-2519471-B1
优先权日:2009-12-29
标题 :Synthesis of nanoparticles by means of ionic liquids

专利号:DE-102009060835-A1
优先权日:2009-12-29
标题:Synthesis of nanoparticles using ionic liquids