参考标题:Cobalt‐catalyzed Deoxygenative Hydroboration Of Nitro Compounds And Applications To One‐pot Synthesis Of Aldimines And Amides 作者:Kristina A. Gudun,Raikhan Zakarina,Medet Segizbayev,Davit Hayrapetyan,Ainur Slamova,Andrey Y. Khalimon |发布日期:2022.2 摘要:The Commercially Available And Bench-Stable Co(Acac)2 Ligated With Bis[(2-Diphenylphosphino)Phenyl] Ether (Dpephos) Was Employed For Selective Room Temperature Hydroboration Of Nitro Compounds With Hbpin (Tof Up To 4615 H−1), Tolerating Halide, Hydroxy, Amino, Ether, Ester, Lactone, Amide And Heteroaromatic Functionalities. These Reactions Offered A Direct Access To A Variety Of N-Borylamines Rn(H)Bpin
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