CAS: 110-42-9; Methyl Decanoate

该化合物是一种清晰的无色液体,具有轻度,类似酯的气味,通常用作有机合成和工业应用的中间体,其主要优点包括高纯度,稳定性和与一系列化学工艺的兼容性.甲基二甲酸酯是生产口味,香味和生物燃料的宝贵前体.它也因其有利的物理化学特性,例如低挥发性和良好的溶液,而被用作溶剂或塑胶.该化合物的特点是其可靠的性能和实验室及工业环境的一贯质量.

结构式图片

相似化合物

112-30-1 334-48-5 112-31-2

欧盟法规

REACH注册ECHA物质ECHA物质欧盟农药活性物质C&L通报REACH预注册

上下游产品

CAS号67-56-1 甲醇 | CAS号110-38-3 癸酸乙酯 | CAS号334-48-5 正癸酸 | CAS号1342298-82-1 hydrazidomycin B | CAS号4637-24-5 N,N-二甲基甲酰胺二甲基缩醛 | CAS号1634-04-4 甲基叔丁基醚 | CAS号7289-52-3 甲癸醚 | CAS号112-30-1 正癸醇 | CAS号108965-84-0 methyl (2Z,4E)-... | CAS号104383-13-3 1-(tert-butylpe... | CAS号100-41-4 乙苯 | CAS号36283-44-0 (R)-N-(1-苯乙基)乙酰胺 | CAS号5851-50-3 2-壬基苯并咪唑 | CAS号42175-41-7 benzyl decanoate | CAS号22890-11-5 N-[3-(dimethyla... | CAS号112-31-2 癸醛 | CAS号112-30-1 正癸醇 | CAS号111-84-2 正壬烷 | CAS号124-18-5 正癸烷

合成工艺路线路线简述

  • 合成目标产物 Methyl Decanoate 主要起始原料 Methanol And Decanoic Acid
  • (文献来源)合成步骤主要原料 Methanol 和 Decanoic Acid
癸醇置于palladium Diacetate,[ruh2(Pph3)4] 吡啶体系中,用 乙醚,甲苯,乙腈 用作溶剂,化学反应 6.0H,反应生成癸酸甲酯
参考文献:钯或钌配合物催化的醇与碳酸烯丙酯的脱氢
标题:钯或钌配合物催化的醇与碳酸烯丙酯的脱氢
摘要:用无膦的钯催化剂在乙腈中处理碳酸烷基烯丙酯可高产率得到酮或醛.这种经由碳酸烯丙酯氧化醇的新方法可应用于除简单伯醇之外的各种醇.反应在中性条件下进行,因此在反应过程中不影响各种对酸或碱敏感的官能团.氢化钌配合物也是一种有效的催化剂.仲或烯丙基醇的直接脱氢反应通过钌络合物的催化作用与碳酸烯丙酯反应进行的.1,4-二醇和1,5-二醇与过量的碳酸烯丙酯转化为内酯.
Doi:10.1016/s0040-4020(01)81672-0

海关参考信息

专利信息


专利号:US-5872245-A
优先权日:1992-09-30
标题 :Continuous process for the synthesis of sucrose fatty acid esters
发明人:WILSON DONALD C
权利人:OPTIMA TECHNOLOGIES GROUP
摘要:This present invention pertains to a process for the synthesis of sucrose fatty acid esters by reacting sucrose and a purified specific fatty acid ester under substantially solvent free conditions in the presence of a transesterification stationary catalyst and mechanical emulsification. The process is continuous, yielding selected individual products of separated simple sucrose fatty acid esters of mono-, di-, tri- and polyesters while recycling the unwanted ester fractions, the unreacted sucrose and fatty acid ester.

专利号:US-9382189-B2
优先权日:2013-02-08
标题:Synthesis of a branched unsaturated compound by means of cross metathesis
发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
权利人:ARKEMA FRANCE
摘要:The invention relates to a method for the synthesis of a branched unsaturated fatty compound, said method comprising the metathesis, in the presence of a metathesis catalyst, of a linear unsaturated fatty compound and a branched olefin. The branched unsaturated fatty compound is used in particular for the production of at least one of the following products: dielectric fluids, specialty surfactants, emulsifiers, frictions agents, antistatic additives, antifogging additives, mould release agents, pigment dispersants, high-performance lubricants, waxes and wax emulsifiers, polymer conversion additives, PVC stabilizing agents, inks, resins, paints, varnishes, solvents, lipsticks, creams for the skin, deodorants, particularly stick deodorants, hair dyes, shampoos and other liquid soaps, shaving foam, laundry detergents, cleaning agents, fabric softeners, and mixtures of same.

专利号:US-8729283-B2
优先权日:2009-01-29
标 题 :Chain-selective synthesis of fuel components and chemical feedstocks
发明人:OLSON EDWIN S
权利人:ENERGY & ENVIRON RES CT FOUND
摘要:A method comprising providing a starting composition comprising a polyunsaturated fatty acid, a polyunsaturated fatty ester, a carboxylate salt of a polyunsaturated fatty acid, a polyunsaturated triglyceride, or a mixture thereof; self-metathesizing the starting composition or cross-metathesizing the starting composition with at least one short-chain olefin in the presence of a metathesis catalyst to form self-/cross-metathesis products comprising: cyclohexadiene; at least one olefin; and one or more acid-, ester-, or salt-functionalized alkene; and reacting cyclohexadiene to produce at least one cycloalkane or cycloalkane derivatives. A method for producing cycloalkanes for jet fuel by providing a starting composition comprising at least one selected from the group consisting of algal and polyunsaturated vegetable oils, subjecting the starting composition to metathesis to produce metathesis product comprising at least one olefin, cyclohexadiene, and at least one acid-, ester-, or salt-functionalized alkene, and reacting the at least one olefin and cyclohexadiene to form cycloalkane(s).

专利号:WO-2017105352-A1
优先权日:2015-12-18
标 题 :Synthesis of inorganic sio2 microcapsules containing phase change materials and applications therein
发明人:YANG JINGLEI; AN JINLIANG; YANG EN-HUA
权利人:UNIV NANYANG TECH
摘要:Disclosed herein are microcapsules that encapsulate a phase change material, where the microcapsules have a dual-core structure with a first shell being made of an organic polymeric material, in particular polyurea surrounded by a second inorganic material shell, in particular silica. Also disclosed herein is a process to manufacture said microcapsules and applications thereof.

专利号:US-10787688-B2
优先权日:2012-05-11
标 题:Multi-stage synthesis method with synthesis gas
发明人:HAAS THOMAS; WITTMANN EVA MARIA
权利人:EVONIK OPERATIONS GMBH
摘要:The invention provides a process for the preparation of hydrocarbons substituted with at least one group containing at least one oxygen atom, comprising the process stepsn A) reaction of a carbon source comprising at least one selected from CO 2 and CO to give acetate and/or ethanol with a first microorganism, B) separating off of the acetate from the first microorganism, C) reaction of the acetate to give a hydrocarbon substituted with at least one group containing at least one oxygen atom with a second microorganism and optionally D) purification of the hydrocarbon substituted with at least one group containing at least one oxygen atom.

专利号:WO-2025018894-A1
优先权日:2023-07-19
标 题:Bio-renewable surfactants based on fructose and fatty acid esters.
发明人:MINNAARD ADRIAAN JACOBUS; LIN HUNG-CHIEN; FRIDRICH BÃ?LINT
权利人:UNIV GRONINGEN
摘要:The invention relates to the fields of surfactants and green chemistry, more in particular to means and methods for the synthesis of novel surfactants based on readily available and biorenewable building blocks. Provided is a method for the synthesis of a carbohydrate surfactant molecule, comprising the steps of: (i) reacting a fructose-containing saccharide with 3-hydroxy propionitrile under acid conditions to obtain the cyano-intermediate compound cyanoethyl β-fructopyranoside; (ii) hydrogenating the cyano-intermediate compound in the presence of a catalyst to obtain an amine-intermediate compound; and (iii) amidating said amine moiety by contacting the amine-intermediate compound with at least one alkyl ester or glycerol ester of a saturated or unsaturated, optionally substituted, aliphatic C4-C22 carboxylic acid in the presence of a base to obtain a fructose-based surfactant molecule.
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癸酸甲酯
Methyl decanoate
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主要参考文献

[参考文献]: Brian D Fitz, Et Al. Evaluation Of Injection Methods For Fast, High Peak Capacity Separations With Low Thermal Mass Gas Chromatography. J Chromatogr A. 2015 May 1:1392:82-90.
[参考文献]: Hanneke Brust, Et Al. Impurity Profiling Of Trinitrotoluene Using Vacuum-Outlet Gas Chromatography-Mass Spectrometry. J Chromatogr A. 2014 Dec 29:1374:224-230.
[参考文献]: Oier Aizpurua-Olaizola, Et Al. Optimization Of Supercritical Fluid Consecutive Extractions Of Fatty Acids And Polyphenols From Vitis Vinifera Grape Wastes. J Food Sci. 2015 Jan;80(1):E101-7.

合成参考文献


摘要:Baird, M. S., Science of Synthesis, (2010) 47, 1124.
摘要:Chciuk, T. V.; Flowers, R. A.; Flowers, R. A., Science of Synthesis Knowledge Updates, (2016) 2, 233.
摘要:Li, G.; Szostak, M., Science of Synthesis Knowledge Updates, (2020) 2, 231.
摘要:Harris, R.L., L.J. Cralley, L.V. Cralley (eds.) Patty's Industrial Hygiene and Toxicology. Volume 3 Part A: Theory and Rationale of Industrial Hygiene Practice: The Work Environment. 3rd ed. New York, NY: John Wiley & Sons Inc., 1994., p. 2997
摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
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