CAS: 97931-41-4; Methyl 3-Carbazolecarboxylate

该化合物是一种有机化合物,其特征是其卡通醇结构,即含有二苯并呋喃杂物的引信环系统;该化合物的特点是一个箱式叶酸盐功能组,该组有助于其反应性和溶解性.一般而言,甲基卡通醇-3-卡方正叶是一种固体或液体,视具体情况而定,并经常用于有机合成和生产各种药品和农用化学品.其分子结构允许材料科学的潜在应用,特别是有机半导体和染料的开发.甲基酯组的存在增强了其有机溶剂中的溶性,使之适合各种化学反应.此外,该化合物可能具有有趣的光物理特性,可以在可视电子应用中加以利用.与许多有机化合物一样,在处理甲基卡通醇-3-卡方糖时,应当采取安全措施,包括使用适当的个人防护设备和遵守安全准则.

结构式图片

相似化合物

51035-17-7 51761-07-0 22404-78-0

物理性质

MSDS等安全信息

    上下游产品

    propynoic acid methyl ester N-(carbobenzyloxy)-2-[(E)-2-(phenylthio)ethenyl]indole N,N-dimethyl-formamide dimethyl acetalN,N-dimethyl-formamide dimethyl acetal ethyl 3-(2-(methyl)-1-(phenylsulfonyl)-1H-indol-3-yl)acrylate9H-carbazole-3-carboxylic acid 9-Ethyl-9H-carbazole-3-carboxylic acid

    合成工艺路线路线简述

    • 1638131-81-3 = 97931-41-4
      反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium Diacetate Solvents: Dimethyl Sulfoxide; 3 H,130 °C
      标题:C-N Bond Formation Via Cu-Catalyzed Cross-Coupling With Boronic Acids Leading To Methyl Carbazole-3-Carboxylate: Synthesis Of Carbazole Alkaloids
      作者:Rasheed,Sk.; Rao,D. Nageswar; Reddy,K. Ranjith; Aravinda,S.; Vishwakarma,Ram A.; Et Al
      参考文献:Rsc Advances 日期:2014 卷标:4(10) 页码:4960-4969]

      522614-63-7 = 97931-41-4
      反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol,Dichloromethane; 2 D,1 Atm,Rt
      标题:Regiochemical Switching In Diels-Alder Cycloadditions By Change In Oxidation State Of Removable Diene Sulfur Substituents. Synthesis Of Carbazoles By Sequential Heteroannulation And Diels-Alder Cycloaddition
      作者:Back,Thomas G.; Pandyra,Aleksandra; Wulff,Jeremy E.
      参考文献:Journal Of Organic Chemistry 日期:2003 卷标:68(8) 页码:3299-3302]

      1638131-81-3 = 97931-41-4
      反应条件:1.1 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Catalysts: Palladium Diacetate Solvents: Toluene; 12 - 24 H,100 °C
      标题:Mild And Efficient Synthesis Of Functionalized Carbazoles Via A Dbu-Assisted Sequence Involving Cu- And Pd-Catalyzed Coupling Reactions
      作者:Khan,Aminur; Karim,Rejaul; Dhimane,Hamid; Alam,Safiul
      参考文献:Chemistryselect 日期:2019 卷标:4(21) 页码:6598-6605]

      4058-18-8 = 97931-41-4
      反应条件:1.1 Reagents: Oxygen Solvents: Acetic Acid; 20 H,120 °C
      标题:Palladium-Catalyzed Direct Synthesis Of Carbazoles Via One-Pot N-Arylation And Oxidative Biaryl Coupling: Synthesis And Mechanistic Study
      作者:Watanabe,Toshiaki; Oishi,Shinya; Fujii,Nobutaka; Ohno,Hiroaki
      参考文献:Journal Of Organic Chemistry 日期:2009 卷标:74(13) 页码:4720-4726]

      19718-49-1 + 88284-48-4 = 97931-41-4
      反应条件:1.1 Reagents: Cesium Fluoride Solvents: Acetonitrile; 10 H,Rt1.2 Catalysts: Tricyclohexylphosphine,Palladium Diacetate; Rt -> 100 °C; 1 D,100 °C
      标题:Synthesis Of Carbazoles And Dibenzofurans Via Cross-Coupling Of O-Iodoanilines And O-Iodophenols With Silylaryl Triflates And Subsequent Pd-Catalyzed Cyclization
      作者:Liu,Zhijian; Larock,Richard C.
      参考文献:Tetrahedron 日期:2007 卷标:63(2) 页码:347-355]

      619-45-4 = 97931-41-4
      反应条件:1.1 Reagents: Cupric Acetate Catalysts: Palladium Diacetate Solvents: Pivalic Acid,Toluene; 24 H,140 °C
      标题:Ligand-Free Pd-Catalyzed Domino Synthesis Of Carbazoles Via Dehydrogenative Aromatization/c(Sp2)-C(Sp2) Coupling Sequence
      作者:Wen,Lixian; Tang,Lin; Yang,Yu; Zha,Zhenggen; Wang,Zhiyong
      参考文献:Organic Letters 日期:2016 卷标:18(6) 页码:1278-1281]

      4058-18-8 = 97931-41-4
      反应条件:1.1 Catalysts: Palladium Diacetate Solvents: Acetic Acid; 1 H,Reflux
      标题:Mastering Tricyclic Ring Systems For Desirable Functional Cannabinoid Activity
      作者:Petrov,Ravil R.; Knight,Lindsay; Chen,Shao-Rui; Wager-Miller,Jim; Mcdaniel,Steven W.; Et Al
      参考文献:European Journal Of Medicinal Chemistry 日期:2013 卷标:69 页码:881-907]

      2089460-17-1 = 97931-41-4
      反应条件:1.1 Reagents: Tert-Butyl Nitrite Solvents: 1,2-Dichloroethane; 10 Min,Rt1.2 Reagents: Oxygen; 10 Min,Rt; 24 H,Rt
      标题:Visible-Light-Induced Synthesis Of Carbazoles By In Situ Formation Of Photosensitizing Intermediate
      作者:Chatterjee,Tanmay; Roh,Geum-Bee; Shoaib,Mahbubul Alam; Suhl,Chang-Heon; Kim,Jun Soo; Et Al
      参考文献:Organic Letters 日期:2017 卷标:19(7) 页码:1906-1909]

      117738-74-6 = 97931-41-4
      反应条件:1.1 Reagents: Potassium Acetate Catalysts: Palladium Solvents: Dimethyl Sulfoxide; 25 Min,180 °C
      标题:Direct Arylation-Based Synthesis Of Carbazoles Using An Efficient Palladium Nanocatalyst Under Microwave Irradiation
      作者:Steingruber,H. Sebastian; Mendioroz,Pamela; Volpe,Maria A.; Gerbino,Dario C.
      参考文献:International Electronic Conference On Synthetic Organic Chemistry 日期:2020 卷标:(2020) 页码:1-11]

      615-42-9 + 619-45-4 = 97931-41-4
      反应条件:1.1 Catalysts: [2-[bis(Tricyclo[3.3.1.13,7]Dec-1-Yl)Phosphino-Kp]-N,N-Dimethylbenzenamine]Chlor... Solvents: Methanol; Rt -> 0 °C1.2 Reagents: Silver Hexafluoroantimonate; 24 H,80 °C
      标题:Ligand-Enabled Gold-Catalyzed C(Sp2)-N Cross-Coupling Reactions Of Aryl Iodides With Amines
      作者:Akram,Manjur O.; Das,Avishek; Chakrabarty,Indradweep; Patil,Nitin T.
      参考文献:Organic Letters 日期:2019 卷标:21(19) 页码:8101-8105]

      4058-18-8 = 97931-41-4
      反应条件:1.1 Reagents: Pivalic Acid,Potassium Carbonate Catalysts: Palladium Diacetate; 17 H,110 °C1.2 Reagents: Water
      标题:Method For Preparing Carbazole Derivative With Phenolic Compound
      参考文献:China]

      1638131-81-3 = 97931-41-4
      反应条件:1.1 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Catalysts: Palladium Diacetate Solvents: Dimethylformamide; 5 Min,Rt; 60 Min,100 °C
      标题:Microwave-Assisted Synthesis Of Functionalized Carbazoles Via Palladium-Catalyzed Aryl C-H Activation And Study Of Their Interactions With Calf-Thymus Dna
      作者:Alam,Safiul; Karim,Rejaul; Khan,Aminur; Mallick,Asifur Rahaman; Sepay,Nayim; Et Al
      参考文献:Synthetic Communications 日期:2022 卷标:52(18) 页码:1834-1855]

      1073968-33-8 = 97931-41-4
      反应条件:1.1 Reagents: Aluminum Chloride Solvents: Toluene; 23 °C; 24 H,23 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water
      标题:First Inverse Electron-Demand Diels-Alder Methodology Of 3-Chloroindoles And Methyl Coumalate To Carbazoles
      作者:Guney,Tezcan; Lee,Jennifer J.; Kraus,George A.
      参考文献:Organic Letters 日期:2014 卷标:16(4) 页码:1124-1127]

      = 97931-41-4
      反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Acetonitrile; 1 H,Reflux
      标题:Synthesis Of Carbazoles By A Diverted Bischler-Napieralski Cascade Reaction
      作者:Faltracco,Matteo; Ortega-Rosales,Said; Janssen,Elwin; Cioc,Razvan C.; Vande Velde,Christophe M. L.; Et Al
      参考文献:Organic Letters 日期:2021 卷标:23(8) 页码:3100-3104]

      117738-74-6 = 97931-41-4
      反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Palladium Solvents: Dimethyl Sulfoxide; 25 Min,180 °C1.2 Reagents: Ethyl Acetate
      标题:Convenient One-Pot Synthesis Of 9H-Carbazoles By Microwave Irradiation Employing A Green Palladium-Based Nanocatalyst
      作者:Steingruber,H. Sebastian; Mendioroz,Pamela; Volpe,Maria A.; Gerbino,Dario C.
      参考文献:Synthesis 日期:2021 卷标:53(21) 页码:4048-4058]

      4058-18-8 = 97931-41-4
      反应条件:1.1 Reagents: Palladium Diacetate Solvents: Acetic Acid; 1 H,120 °C
      标题:Preparation Of Carbazolamide Derivative Or Salts As Imhibitor Of Rorγt
      参考文献:World Intellectual Property Organization]

      4058-18-8 = 97931-41-4
      反应条件:1.1 Reagents: Palladium Diacetate Solvents: Acetic Acid; 1 H,Reflux
      标题:Carbazoles And Azacarbazoles As Cannabinoid Receptor Modulators And Their Preparation And Use For The Treatment Of Diseases
      参考文献:United States]

      1882902-31-9 = 97931-41-4
      反应条件:1.1 Solvents: Toluene; Rt -> 110 °C
      标题:The Synthetic Studies Of Carbazole Alkaloids
      作者:Yokoyama,Hajime; Shoji,Yuzen; Kubo,Takayoshi; Miyazawa,Masahiro; Hirai,Yoshiro
      参考文献:Heterocycles 日期:2015 卷标:91(9) 页码:1752-1762]

      17763-71-2 = 97931-41-4
      反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Palladium Diacetate,X-Phos Solvents: Toluene; 1 H,100 °C; 100 °C -> Rt1.2 Reagents: Oxygen Solvents: Acetic Acid; 10 H,100 °C
      标题:Preparation Of 9H-Carbazole And 9H-Pyrido[3,4-B]Indole Derivatives As Eg5 Inhibitors
      参考文献:Japan]

      4637-24-5 + 856251-57-5 = 97931-41-4
      反应条件:1.1 Catalysts: Dabco Solvents: Dimethylformamide; 4 H,110 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 0 °C
      标题:An Improved Synthesis Of Carbazoles Via Domino Reaction Of N-Protected-2-Methylindoles With Dmf-Dma/dma-Dma
      作者:Sureshbabu,Radhakrishnan; Mohanakrishnan,Arasambattu K.
      参考文献:Journal Of Heterocyclic Chemistry 日期:2012 卷标:49(4) 页码:913-918
    📜Methyl 2,3,4,9-Tetrahydro-1H-Carbazole-6-Carboxylate置于palladium On Activated Charcoal体系中,化学反应生成 3-咔唑羧酸甲酯
    参考文献:Carter Et Al.,Journal Of The Chemical Society,1957,P. 2210,2212
    标题:Carter Et Al.,Journal Of The Chemical Society,1957,P. 2210,2212

    海关参考信息

    专利信息


    专利号:US-12319661-B2
    优先权日:2018-12-10
    标题 :Polycyclic compound
    发明人：ZENG YUFENG
    权利人:EUTEC NEW MATERIALS TECH SUZHOU CO LTD
    摘要:Novel polycyclic compounds, synthesis methods and applications thereof are provided. The compound comprise a plurality of carbocyclic and/or heterocyclic structures having at least one group that emits visible light or fluorescence and at least one ultraviolet and/or visible (blue) light absorbing group covalently bonded to provide stability. The compounds can be used as a light conversion agent, dye, pigment, fluorescence agent, ultraviolet light or blue light absorber, and is applied to optical film, agricultural film, optical disk (disc), optical lens, goggles, skin care, makeup, lighting, coatings, adhesives, light stabilizers, or panels.

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    主要参考文献

    [参考文献]: Deng Hd, Et Al. Carbazole Alkaloids From The Peels Of Clausena Lansium. J Asian Nat Prod Res. 2014 Oct;16(10):1024-8.
    [参考文献]: Deng Hd, Mei Wl, Wang H, Guo Zk, Dong Wh, Wang H, Li Sp, Dai Hf. Carbazole Alkaloids From The Peels Of Clausena Lansium. J Asian Nat Prod Res. 2014 Oct;16(10):1024-8.

    合成参考文献


    参考文献:10.1016/0031-9422(91)84151-h
    摘要:Wen-Shyong L, McChesney JD, El-Feraly FS. Carbazole alkaloids from Clausena lansium. Phytochemistry. 1991 Jan;30(1):343–6. doi: 10.1016/0031-9422(91)84151-h.
    参考文献:10.1248/cpb.46.344
    摘要:ITO C, KATSUNO S, RUANGRUNGSI N, FURUKAWA H. Structures of Clausamine-A, -B, -C, Three Novel Carbazole Alkaloids from Clausena anisata. Chem. Pharm. Bull. 1998;46(2):344–6. doi: 10.1248/cpb.46.344.
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