CAS: 6002-31-9; Tert-Butyl(Phenyl)Phosphane

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CAS号62839-84-3 chloro-phenyl-s... | CAS号108-86-1 溴苯 | CAS号67033-70-9 tert-butyl(trim... | CAS号172487-18-2 phenylphosphini... | CAS号32673-25-9 二叔丁基苯基膦 | CAS号29949-69-7 氯(叔丁基)苯基膦 | CAS号507-20-0 氯代叔丁烷 | CAS号644-97-3 苯基二氯膦

📜二叔丁基苯基膦置于lithium体系中,用 四氢呋喃 作为反应溶剂,化学反应生成 叔丁基苯基膦
参考文献:碳磷键与碱金属的还原裂解.三,芳基烷基膦的反应
标题:碳磷键与碱金属的还原裂解.三,芳基烷基膦的反应
摘要:苯烷基膦ph 2 Pr,Phpr 2(r = Bu,Ipr)与na / Nh 3的还原裂解是非选择性的:苯基和烷基都可以裂解,并且可能发生桦木还原.ph 2 Tbup的反应产生了高产率的二苯基磷化物.伯烷基的ω位置的极性基团(co 2 Na,So 3,Na)可能导致选择性增加;桦木还原得到抑制,并获得官能化的仲磷化物.
DOI:10.1002/recl.19921110402

专利信息

专利号:US-2012309997-A1
优先权日:2010-02-12
标 题:Enantiomerically Enriched Aminodiphosphines as Ligands for the Preparation of Catalysts for Asymmetric Synthesis
发明人：ALONSO XALMA MONICA; VERDAGUER ESPAULELLA XAVIER; REVES VILAPLANA MARC; RIERA ESCALE ANTONI
权利人:ALONSO XALMA MONICA; VERDAGUER ESPAULELLA XAVIER; REVES VILAPLANA MARC; RIERA ESCALE ANTONI; ENANTIA S L
摘要:The present invention relates to enantiomerically enriched aminodiphosphine ligands where the chirality is located in the phosphorus atom and their preparation process, to catalysts containing them and their preparation process, as well as their use in asymmetric synthesis.

专利号:EP-4359374-B1
优先权日:2021-06-21
标 题 :Process for the synthesis of propargylic alcohol by reacting formaldehyde with acetylene in the presence of a homogeneous copper catalyst
发明人：SCHAUB THOMAS; SHEVCHENKO GRIGORY ANDRE; HASHMI A STEPHEN K; SITTE NIKOLAI AMADEUS
权利人:BASF SE

专利号:US-2020407381-A1
优先权日:2018-03-20
标题:C-bulky p-chirogenic organophosphorus compounds
发明人：BAYARDON JÉRÔME; JAILLET ANTONIN; JUGÉ SYLVAIN
权利人:UNIV BOURGOGNE
摘要:In the field of organic phosphorus chemistry, especially the chemistry of bulky organophosphorus compounds, a process for the synthesis of compound of formula (I). This process is especially useful to obtain chiral bulky phosphorus compounds. The present invention also relates to compounds of formula (VII), (VIII), (IX) and (X) and their processes of manufacturing starting from a compound of formula (I).

专利号:US-2024294449-A1
优先权日:2021-06-21
标题 :Process for the synthesis of propargylic alcohol by reacting formaldehyde with acetylene in the presence of a homogeneous copper catalyst

专利号:EP-4121416-A1
优先权日:2020-03-18
标 题 :Improved synthesis of 6-aryl-4-aminopicolinates

专利号:RU-2620265-C1
优先权日:2015-11-30
标题:Di(3-sulphophenylphosphinyl) derivatives of 2,2'-bipyridyl, 1,10-phenanthroline and pyridine derivatives and synthesis method thereof