N-[nα-(Tert-Butoxycarbonyl)-L-Asparaginyl]-1,5-Diaminopentane置于palladium Dihydroxide 氢气,Caesium Carbonate,溶剂黄146,1,8-二氮杂双环[5.4.0]十一碳-7-烯,三乙胺,三氟乙酸,2-巯基乙醇体系中,用 氯仿,N,N-二甲基甲酰胺 用作溶剂,化学反应 8.0H,反应生成乳铁蛋白
参考文献:An Efficient And Versatile Synthesis Of Acylpolyamine Spider Toxins
标题:An Efficient And Versatile Synthesis Of Acylpolyamine Spider Toxins
摘要:An Efficient And Versatile Synthesis Of Acylpolyamine Spider Toxins Was Developed Based On The Structural Classification Of The Nephila And Nephilengys Spider Toxins Using The 2-Nitrobenzenesulfonamide Protecting Group. The Naturally occurring Toxins 1-5 Representing Each Structural Type Have Been Efficiently Synthesized By This Method In A High Overall Yield With Few Steps. (C) 2002 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0960-894X(01)00733-8