📜癸二酸置于氯化亚砜体系中,化学反应 1.0H,反应生成癸二酰氯 参考文献:Behavior Of Ruthenium Trisbipyridine-anthraquinone Conjugates Connected With Alkyl Spacers In Homogeneous And Microheterogeneous Media 标题:Behavior Of Ruthenium Trisbipyridine-anthraquinone Conjugates Connected With Alkyl Spacers In Homogeneous And Microheterogeneous Media 摘要:合成了一系列单核钌三吡啶复合物,这些复合物通过不同长度的灵活烷基链与蒽醌单元连接,还有一个具有中央蒽醌单元的双核表面活性剂钌复合物,其烷基链间隔是通过灵活的链连接的.通过利用附加的醌基对钌中心金属-配体电荷转移激发态的分子内电子转移猝灭,探究了它们在ch3Cn和二十六烷基磷酸盐小泡中的构象偏好.烷基链间隔的长度对两种介质中的猝灭效率影响微小.只有在小泡中,双核钌复合物的猝灭行为才表现出显著差异.这些结果表明,双亲结构对于一组固定分子采取跨越双层膜的拉伸构象是必要且有效的. Doi:10.1246/bcsj.70.2077
专利号:US-7956011-B2 优先权日:2005-05-04 标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays 发明人:SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN 权利人:CANCER RES INST ROYAL 摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.
专利号:US-3891594-A 优先权日:1972-04-07 标题:Direct synthesis of composite materials 发明人:TAYLOR LYNN J 权利人:TAYLOR LYNN J 摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.
专利号:US-3817911-A 优先权日:1972-04-07 标 题 :Direct synthesis of composite materials 发明人:TAYLOR L 权利人:TAYLOR L 摘要:THERE IS DISCLOSED AN IN SITU PROCESS FOR THE PREPARATION OF A COMPOSITE MATERIAL CONSISTING ESSENTIALLY OF AN ORGANIC POLYMER OR COPOLYMER HAVING DISPERSED THEREI AN INORGANIC OXIDE OR MIXTURE OF OXIDES, SAID PROCESS COMPRISING THE SIMULTANEOUS OR SEQUENTIAL SYNTHESIS OF THE ORGANIC POLYMER FROM AT LEAST ONE NON-POLYMERIC ORGANIC PRECUROR AND OF THE INORGANIC OXIDE OR OXIDE MIXTURE DERIVED FROM AT LEAST ONE INORGANIC-OXIDE PRECURSOR.
专利号:US-3960805-A 优先权日:1974-04-19 标 题:Direct synthesis of organic polymer-inorganic oxide composites 发明人:TAYLOR LYNN JOHNSTON 权利人:TAYLOR LYNN JOHNSTON 摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.
专利号:US-7147800-B2 优先权日:2001-01-23 标题 :Selective ether cleavage synthesis of liquid crystals 发明人:WELLINGHOFF STEPHEN T; HANSON DOUGLAS P 权利人:SOUTHWEST RES INST 摘要:A method for making platform molecules comprising: reacting 4-alkoxy benzoyl chloride with R2-hydroquinone under first conditions effective to produce bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene comprising bis terminal alkoxy groups wherein R2 is a bulky organic group; and, subjecting the bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene to second conditions effective to selectively cleave the bis terminal alkoxy groups to produce a solution comprising complexes comprising diphenolic platform molecules comprising bis terminal hydroxyl groups, the second conditions also being effective to precipitate the complexes out of the solution.
专利号:US-6538094-B2 优先权日:1998-12-21 标题:Process for synthesis of allophanate compounds and compositions including the product thereof 发明人:TAZZIA CHARLES L 权利人:BASF CORP 摘要:The invention provides a process for preparing an allophanate-containing compound in the presence of a metal catalyst and a tertiary amine. In a preferred process, the tertiary amine compound also has a hydroxyl group. The hydroxyl group can react with the isocyanate functionality. Also disclosed is a process in which an allophanate-containing compound is prepared with copper acetate monohydrate as a catalyst. The allophanate-containing compound is used as a curing agent in coating compositions, particularly electrocoat coating compositions. The coating compositions are used to coat articles.
摘要:Higashihara, T.; Ueda, M., Science of Synthesis Knowledge Updates, (2010) 4, 301. 摘要:National Technical Information Service., OTS0544140 参考文献:10.1007/s11095-014-1423-2 摘要:Said SS, Pickering JG, Mequanint K. Controlled Delivery of Fibroblast Growth Factor-9 from Biodegradable Poly(ester amide) Fibers for Building Functional Neovasculature. Pharmaceutical Research. 2014 May 24;31(12):3335–47. doi: 10.1007/s11095-014-1423-2. 参考文献:10.1038/s41557-018-0027-6 摘要:Molla MR, Rangadurai P, Antony L, Swaminathan S, de Pablo JJ, Thayumanavan S. Dynamic actuation of glassy polymersomes through isomerization of a single azobenzene unit at the block copolymer interface. Nat Chem. 2018 Jun;10(6):659–66. doi: 10.1038/s41557-018-0027-6.