CAS: 937-32-6; 4-Nitrophenyl Hypochlorothioite

上下游产品

di(p-nitrophenyl) disulfide para-nitrobenzenethiol 1-acetylsulfanyl-4-nitro-benzene 1-[(4-nitrophenyl)thio]piperidine N-[5-(4-nitro-phenylsulfanyl)-thiazol-2-yl]-acetamideN-[5-(4-nitro-phenylsulfanyl)-thiazol-2-yl]-acetamide 4-nitro-benzenesulfenic acid-[2]pyridylamide N-Acetyl-p-nitrobenzenesulfenamide

📜4-硝基苯硫醇置于氯体系中,化学反应生成 4-硝基苯亚磺酰氯
参考文献:Z-E异构化n-磺基苯亚胺
标题:Z-E异构化n-磺基苯亚胺
摘要:已通过1 H NMR程序在聚结温度下测量了各种对称n-磺基苯亚胺的z-E异构化的自由能.在两种情况下,已经测量了在一系列温度下非对称n-磺苯基亚胺的异构化速率,并确定了活化焓和熵.取代基对异构化势垒δg的影响*可以通过氮孤对与亚胺碳和氮上取代基的超共轭转化来解释,该取代以线性转变态用于转化过程.使用扩展的hückel扰动方法以轨道方式讨论了结果,该方法可用于定性地解释取代基对广泛的亚氨基化合物(包括胍和亚氨基碳酸酯)的反转势垒的影响.
DOI:10.1039/p29790000427

专利信息

专利号:US-7015176-B2
优先权日:2003-06-03
标题 :Process for the synthesis of aryl sulfurpentafluorides
发明人：BAILEY III WADE H; CASTEEL JR WILLIAM J; PESARESI RENO J; PROZONIC FRANK M
权利人:AIR PROD & CHEM
摘要:A process is described for the synthesis of an aryl sulfur pentafluoride compound. In one embodiment of the present invention, there is provided a process for preparing an aryl sulfurpentafluoride compound comprising: combining an at least one aryl sulfur compound with a fluorinating agent to at least partially react and form an intermediate aryl sulfurtrifluoride product; and exposing the intermediate aryl sulfurtrifluoride product to the fluorinating agent and optionally a fluoride source to at least partially react and form the aryl sulfurpentafluoride compound.

专利号:EP-1484318-A1
优先权日:2003-06-03
标题:Process for the synthesis of aryl sulfurpentafluorides

专利号:US-2004249209-A1
优先权日:2003-06-03
标题:Process for the synthesis of aryl sulfurpentafluorides

专利号:CN-118978463-A
优先权日:2024-08-05
标题:Synthesis method of 9-aryl-10-sulfoxide phenanthrene compound