CAS: 87147-90-8; (S)-2-Amino-3-(Pyren-1-yl)Propanoic Acid

上下游产品

Dl-1-Pyrenylalanine 91879-08-2
N-Acetyl-Dl-3-(1-Pyrenyl)Alanine 91859-60-8

📜1-芘甲醇置于氢氧化钾,Sodium Hydroxide,Aminoacylase,三溴化磷,Sodium Hydride,Cobalt(II) Chloride体系中,用 四氢呋喃,乙醇,水,苯 作为反应溶剂,化学反应 88.0H,反应生成 (2S)-2-氨基-3-(1-芘基)丙酸
参考文献:A Non-Covalent Strategy For The Assembly Of Supramolecular Photocurrent-Generating Systems
标题:A Non-Covalent Strategy For The Assembly Of Supramolecular Photocurrent-Generating Systems
摘要:Three Photocurrent-Generating Thin Films Were Assembled On Gold Surfaces. Sam I Was Constructed From Molecules Consisting Of An Alkyl Disulfide Group Linked Covalently To A 12-Residue Helical Peptide And Terminated With An Alanine Residue Containing A Pyrene Chromophore. Sam I Served As A Benchmark For Multilayered Films Ii And Iii In Photocurrent Generation Experiments. Films Ii And Iii Were Assembled From Several Components That Were Linked Noncovalently By Metal-Ligand Complexation. Cyclic Voltammetry And Contact Angle Measurements Suggest That The Films Consist Of Ordered Layers With Relatively Few Defects. Photoexcitation Of Sam I By The Output Of A 350 Nm Lamp (Approximately 0.2 Mw Power Incident On The Sample) Results In Current Generation In The Range 5-10 Na/cm2. Photoexcitation Of Ii And Iii Yields Higher Current In The Range 10-30 Na/cm2,Representing A Quantum Efficiency Of Approximately 1%. The Observation Of Comparable Or Higher Current From Noncovalently Assembled Multicomponent Films Indicates That This Method Of Assembly May Obviate The Problems Associated With The Covalent Assembly Of Devices From Large Molecules.
DOI:10.1021/ja0289548

专利信息

专利号:US-2007161807-A1
优先权日:2004-01-28
标 题:Method for manufacturing optically pure coumaryl amino acids and the novel coumaryl aminoacids thus obtained
发明人：GARBAY CHRISTIANE; BISCHOFF LAURENT; BRUN MARIE-PRISCILLE
权利人:INSERM INST NAT DE LA SANT E E
摘要:The present invention relates to the field of the synthesis of optically pure amino acid derivatives, mainly for the purpose of manufacturing optically active polypeptides that are useful as labelled detection tools.

专利号:US-7385038-B2
优先权日:2002-07-18
标 题:Non-natural labeled amino acid and method of constructing amino acid/tRNA complex
发明人：HOHSAKA TAKAHIRO; SISIDO MASAHIKO
权利人:PROTEIN EXPRESS CO LTD
摘要:This invention relates to: a labeled amino acid that can be introduced into a protein with the aid of a protein synthesis system; a functional protein having functions derived from a label compound; a labeled amino acid comprising an aromatic ring bound to an amino acid side chain and a label compound bound thereto via the aromatic ring; a functional protein to which the labeled amino acid has been introduced; and a novel method for effectively obtaining a labeled amino acid-tRNA complex.