CAS: 2498-77-3; 1-Methyltetraphene

该化合物是一种多环芳烃,其特点是由多发引信芳香环组成的复杂结构,是苯的衍生物,其甲基组附于芳香系统中的碳原子之一,该化合物一般在室温时是固体的,以其疏水性闻名,使其在水中溶解不力,但在有机溶剂中可溶解. 1-Mebybenz[a]anthracene因其潜在的致癌性而得到承认,因为许多全氟芳烃与包括癌症在内的不良健康影响有关,经常在环境科学和毒理学方面加以研究,因为它存在于化石燃料和燃烧产品中,该化合物可以在各种环境基质中检测,包括空气,土壤和沉积物,并且对与污染和人类健康有关的研究很感兴趣.正确处理和处置由于其危险性质至关重要.

结构式图片

欧盟法规

ECHA物质C&L通报

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合成工艺路线路线简述

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    参考文献:K区芳烃氧化物的溶剂分解:取代基对苯并[a]蒽5,6-氧化物反应的影响
    标题:K区芳烃氧化物的溶剂分解:取代基对苯并[a]蒽5,6-氧化物反应的影响
    摘要:苯并 [a] 蒽 5,6-氧化物 (Ba-O) 在取代 1 (1-Mba-O),4 (4-Mba-O),7 ( 7-Mba-O),11 (11-Mba-O) 和 12 (12-Mba-O),7,12-二甲基取代 (7,12-Dmba-O) 和 7-溴取代1:9 二恶烷-水和甲醇在 25 O C 报告.这些取代导致其酸催化溶剂分解的速率差异 > 150 倍,并导致异构化导致的溶剂加合物和酚类的分布发生显着变化.利用光学纯的 Ba-O,7-Mba-O,12-Mba-O 和 7,12-Dmba-O 以及它们的光学纯反式二氢二醇来确定水解反应中水的攻击点
    Doi:10.1021/ja00010A036

    海关参考信息

    专利信息


    专利号:WO-02098881-A1
    优先权日:2001-06-06
    标 题 :Tetramerous derivative of indole-3-carbinol with anti-carcinogenic activity and method of synthesis of said derivative

    专利号:EP-1395595-A1
    优先权日:2001-06-06
    标 题:Tetramerous derivative of indole-3-carbinol with anti-carcinogenic activity and method of synthesis of said derivative

    专利号:US-2017355909-A1
    优先权日:2016-06-12
    标 题 :Mobile apparatus for carbon-containing materials including biohazard wastes gasification by thermal decomposition and conversion into a liquid fuels.
    发明人:DEMENTEV ALEXANDER
    权利人:DEMENTEV ALEXANDER
    摘要:The present invention relates to a method for gasification of carbon-containing materials including biohazard wastes, and more specifically, to a method for gasification of carbon-containing materials which allows an increase in carbon efficiency and a reduction in carbon dioxide emission, comprising the steps of: biohazard wastes grinding and sterilization, mix with carbon-containing materials for the gasification; and catalytic production of diesel fuel. A system having a movable platform including: material preparation block, gasification and catalytic of diesel fuel production reactors which are structurally and functionally integrated. In the practice of the process, a mixture of carbon-containing materials, a compressed air feed and process steam is fed to the gasifier to produce a synthesis gas. The synthesis gas is fed to the Fischer-Tropsch reactor where it is catalytically reacted to produce heavy hydrocarbons. The outlet from the Fischer-Tropsch reactor is separated into water, a low heating value tail gas, and the desired hydrocarbon liquid product. The water is pressurized and heated to generate process steam. The system further includes a plurality of heat exchangers that enable heat to be recovered from the outlet of the gasifier. The recovered heat is used to make the process steam as well as to preheat the hydrocarbon mix before it is fed to the gasifier and preheat the synthesis gas before it is fed to the Fischer-Tropsch reactor. The method of the present invention greatly increases carbon efficiency and reduces the generation of carbon dioxide.

    专利号:US-10350574-B2
    优先权日:2017-10-24
    标题:Method for producing a product gas having component gas ratio relationships
    发明人:CHANDRAN RAVI; NEWPORT DAVE G; BURCIAGA DANIEL A; LEO DANIEL MICHAEL; MILLER JUSTIN KEVIN; HARRINGTON KAITLIN EMILY; ATTWOOD BRIAN CHRISTOPHER
    权利人:THERMOCHEM RECOVERY INT INC
    摘要:A liquid fuel product system is configured to produce liquid fuels from carbonaceous materials. The liquid fuel product system includes a plurality of feedstock delivery systems, a plurality of first stage product gas generation systems, a plurality of second stage product gas generation systems, a plurality of third stage product gas generation systems, a primary gas clean-up system, a compression system, a secondary gas clean-up system, and a synthesis system that includes one or more from the group consisting of ethanol, mixed alcohols, methanol, dimethyl ether, and Fischer-Tropsch products.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s00216-017-0224-y
    摘要:Große Brinkhaus S, Thiäner JB, Achten C. Ultra-high sensitive PAH analysis of certified reference materials and environmental samples by GC-APLI-MS. Analytical and Bioanalytical Chemistry. 2017 Feb 15;409(11):2801–12. doi: 10.1007/s00216-017-0224-y.
    参考文献:10.1007/bf02899015
    摘要:Ingleton PM, Gaitens PV. Prolactin cells of female rats treated with the carcinogen 7,12-dimethylbenz(A) anthracene (DMBA) in vivo. An ultrastructural study. Virchows Arch B Cell Pathol Incl Mol Pathol. 1986;51(1):51–64. doi: 10.1007/bf02899015.
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