CAS: 12372-57-5; Zirconium(4+) Tetranitrate

该化合物是一种无机化合物,其特性是:在+4氧化状态下,其成分为,在+4氧化状态下,与硝酸盐离子结合;它一般是白色晶状固体,在水中可溶解,因而在各种应用中有用,包括作为氧化的前体和合成其他化合物;该化合物在正常条件下具有稳定性,但能对加热分解,释放氮氧化物;在材料科学领域,特别是在陶瓷和催化剂的生产中,经常使用硝酸铵;必须谨慎地处理该化合物,因为它可能会对皮肤,眼睛和呼吸系统产生刺激作用;在实验室环境中与该物质打交道时,应当注意适当的安全措施,包括使用个人防护设备.

结构式图片

欧盟法规

C&L通报

合成工艺路线路线简述

    📜以 Neat (No Solvent) 用作溶剂,化学反应生成硝酸锆
    参考文献:Natsina,A. A.; Ukraintseva,E. A.; Yakovlev,I. I.,Russian Journal Of Inorganic Chemistry,1989,Vol. 34,P. 1373-1375
    标题:Natsina,A. A.; Ukraintseva,E. A.; Yakovlev,I. I.,Russian Journal Of Inorganic Chemistry,1989,Vol. 34,P. 1373-1375

    专利信息


    专利号:US-10010875-B2
    优先权日:2014-10-30
    标题 :Method for preparing copper-zinc-based catalyst used in synthesis of methanol through CO2 hydrogenation
    发明人:YU YANG; HAO AIXIANG; CHEN HAIBO; WEI SHIXIN; YIN YUSHENG; XIE TIANMING; HE JIAN; MAO CHUNPENG; TAN JIEDONG
    权利人:CHINA PETROLEUM & CHEM CORP; RES INSTITUTE OF NANJING CHEMICAL INDUSTRY GR; RES INST NANJING CHEMICAL IND GROUP
    摘要:Disclosed is a method for preparing a copper-zinc-based catalyst used in synthesis of methanol through CO 2 hydrogenation, and ultrasonic waves are used for control over crystalline phase's composition of a catalyst precursor. Further related to is a catalyst prepared by such a method. An amount of aurichalcite in an active catalyst precursor can be improved through the method, and the specific surface area of the metal copper in a reduced state catalyst is high. The catalyst presents high activity and hydrothermal stability, and promotes high space time yield of methanol in the synthesis of methanol through CO 2 hydrogenation.

    专利号:US-2024075466-A1
    优先权日:2021-04-09
    标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
    发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
    权利人:UMICORE AG & CO KG
    摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

    专利号:US-12312290-B2
    优先权日:2019-05-31
    标 题 :Isobutyl benzene and a process for synthesis of isobutyl benzene by using a catalyst
    发明人:KAMBLE SANJAY PANDURAG; RODE CHANDRASHEKHAR VASANT; PILLAI NANDAKUMAR VELAYUDHAN; RAMALINGAM KARTHICK; SHETTY ROHIT RAVI
    权利人:MANGALORE REFINERY & PETROCHEMICALS LTD
    摘要:The present disclosure provides a process for the synthesis of isobutyl benzene by side chain alkylation of toluene in the presence of a catalyst. The catalyst used in the process of present disclosure provides maximum conversion of toluene with high selectivity towards isobutyl benzene.

    专利号:EP-4008687-A1
    优先权日:2020-12-02
    标 题:A method for the large scale synthesis of metal oxide nanosheets, and their uses
    发明人:VINCENT MEWIN; ETACHERI VINODKUMAR
    权利人:FUNDACION IMDEA MAT
    摘要:The present invention relates to a rapid, scalable and inexpensive method for the synthesis of metal oxide nanosheets; the uses of the metal oxide nanosheets as electrode active materials and as catalyst; an electrode comprising the metal oxide nanosheets, a process for producing the electrode, a cell comprising the electrode and an energy storage and/or delivery system.

    专利号:US-2025192223-A1
    优先权日:2022-03-07
    标 题:Synthesis of al-doped llzo thin-tape electrolytes for solid-state batteries using flame-assisted spray pyrolysis
    发明人:DENG SILI; MULDOON VALERIE L; ZHANG JIANAN
    权利人:MASSACHUSETTS INST TECHNOLOGY
    摘要:A method of synthesis of aluminum-doped Li 6.25 Al 0.25 La 3 Zr 2 O 12 (Al-LLZO) can include preparing a precursor solution by dissolving lithium nitrate, aluminum nitrate, zirconium (IV) oxynitrate, and lanthanum nitrate in stoichiometric amounts according to the composition Li 6.25 Al 0.25 La 3 Zr 2 O 12 in water, and decomposing droplets by passing through a co-flow burner. Also disclosed is a method of produce producing a thin-tape comprising Al-LLZO.

    专利号:US-6899858-B2
    优先权日:2003-01-23
    标题:Method of synthesis of hafnium nitrate for HfO2 thin film deposition via ALCVD process
    发明人:ZHUANG WEI-WEI; EVANS DAVID R; HSU SHENG TENG
    权利人:SHARP LAB OF AMERICA INC
    摘要:A method of preparing a hafnium nitrate thin film includes placing phosphorus pentoxide in a first vessel; connecting the first vessel to a second vessel containing hafnium tetrachloride; cooling the second vessel with liquid nitrogen; dropping fuming nitric acid into the first vessel producing N 2 O 5 gas; allowing the N 2 O 5 gas to enter the second vessel; heating the first vessel until the reaction is substantially complete; disconnecting the two vessels; removing the second vessel from the liquid nitrogen bath; heating the second vessel; refluxing the contents of the second vessel; drying the compound in the second vessel by dynamic pumping; purifying the compound in the second vessel by sublimation to form Hf(NO 3 ) 4 , and heating the Hf(NO 3 ) 4 to produce HfO 2 for use in an ALCVD process.

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    合成参考文献


    摘要:American Conference of Governmental Industrial Hygienists TLVs and BEIs. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. Cincinnati, OH 2015, p. 61
    摘要:Association of American Railroads; Bureau of Explosives. Emergency Handling of Hazardous Materials in Surface Transportation. Association of American Railroads, Pueblo, CO. 2005, p. 956
    摘要:Lewis, R.J. Sr.; Hawley's Condensed Chemical Dictionary 15th Edition. John Wiley & Sons, Inc. New York, NY 2007., p. 1352
    摘要:International Maritime Organization. International Maritime Dangerous Goods Code. London, UK. 2004., p. 130
    摘要:49 CFR 171.2 (USDOT); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of April 10, 2015: https://www.ecfr.gov
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