CAS: 877-09-8; 1,2,3,5-Tetrachloro-4,6-Dimethylbenzene

该化合物是一种芳香化合物,其特点是存在一个用多种氯原子替代的苯环,其典型的外观无色,不光彩,不光彩黄色,其密度相对较高,易变性较低;该化合物主要用作工业溶剂,并用于合成各种化学产品;该化合物的化学结构有助于其稳定性和抗降解性,使其在环境中具有持久性;四氯-m-xyle被认为具有危险性,可能对健康造成影响,包括皮肤和眼部刺激,并可能对水生生命造成风险;适当处理和处置对于减轻环境影响和健康风险至关重要;与许多氯化化合物一样,重要的是监测接触水平,并在工业应用中使用期间遵守安全条例.

结构式图片

相似化合物

7359-72-0 875-40-1 1006-32-2

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2,4-dimethylbenzenesulfonic acid m-xylene iodine chlorine 1,2,3,5-tetrachloro-4,6-bis-dichloromethyl-benzene α,α'-dibromo-2,4,5,6-tetrachloro-m-xylene 2,3,5-Trichloro-4-hydroxy-4,6-dimethyl-cyclohexa-2,5-dienone 2,3,5-Trichloro-4,6-dimethyl-4-nitrooxy-cyclohexa-2,5-dienone

合成工艺路线路线简述

    📜间二甲苯置于碘体系中,化学反应生成 四氯间二甲基苯酚
    参考文献:Koch,Chemische Berichte,1890,Vol. 23,P. 2321
    标题:Koch,Chemische Berichte,1890,Vol. 23,P. 2321

    海关参考信息

    专利信息


    专利号:US-7294732-B2
    优先权日:2002-08-07
    标 题:Silicon compound
    发明人：OHNO KOHJI; TSUJII YOSHINOBU; FUKUDA TAKESHI
    权利人:CHISSO CORP
    摘要:A silicon compound represented by Formula (1). In Formula (1), R 1 is a group independently selected respectively from the group consisting of a hydrogen atom, alkyl, substituted or non-substituted aryl and substituted or non-substituted arylalkyl, and A 1 is an organic group substituted with a halogenated sulfonyl group and is preferably a group represented by Formula (2). In Formula (2), X is halogen; R 2 is alkyl; a is an integer of 0 to 2; and Z 1 is a single bond or alkylene having a carbon number of 1 to 10. n n n n n n n n n n The silicon compound provided by the present invention is a silsesquioxane derivative having an excellent living polymerizable radical polymerization initiating function. For example, it is possible to commence polymerization by allowing an acryl base monomer to coexist to form an acryl base polymer making use of one point of the structure of the silsesquioxane in the present invention as a starting point. Because a halogenated sulfonyl group has a strong electrophilicity, it is possible to synthesize various silsesquioxane derivatives by reacting the silicon compound provided by the present invention with various nucleophilic reagents, and it can actively be used as an intermediate useful for organic synthesis.

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    主要参考文献

    [参考文献]: Shanshan Di, Et Al. Effects Of Benthic Organism Tubifex Tubifex On Hexachlorocyclohexane Isomers Transfer And Distribution Into Freshwater Sediment. Ecotoxicol Environ Saf. 2016 Apr:126:163-169.

    合成参考文献


    参考文献:10.1007/s10661-011-2104-9
    摘要:Steinberg SM, Emerson DW. On-line dechlorination–hydrogenation of chlorinated paraffin mixtures using GC and GC/MS. Environmental Monitoring and Assessment. 2011 May 21;184(4):2119–31. doi: 10.1007/s10661-011-2104-9.
    参考文献:10.1007/s00128-011-0309-9
    摘要:Cheng H, Li X, Wang Y, Zhao C, Liu Y, Chen H, Xu X. Profile of Organochlorine Pesticides in Soil Cores from Some Hotspot Areas of Beijing, China. Bulletin of Environmental Contamination and Toxicology. 2011 May 26;87(2):175–9. doi: 10.1007/s00128-011-0309-9.
    参考文献:10.1007/s11356-014-3031-4
    摘要:Sun H, An T, Li G, Qiao M, Wei D. Distribution, possible sources, and health risk assessment of SVOC pollution in small streams in Pearl River Delta, China. Environmental Science and Pollution Research. 2014 May 28;21(17):10083–95. doi: 10.1007/s11356-014-3031-4.
    参考文献:10.1007/s11356-018-2044-9
    摘要:Di S, Liu R, Chen L, Diao J, Zhou Z. Selective bioaccumulation, biomagnification, and dissipation of hexachlorocyclohexane isomers in a freshwater food chain. Environmental Science and Pollution Research. 2018 Apr 30;25(19):18752–61. doi: 10.1007/s11356-018-2044-9.
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