📜Ethyl Benzoyl Carbonate置于phosphorus Pentoxide,三氯氧磷体系中,用 N,N-二甲基甲酰胺,Xylene 作为反应溶剂,化学反应生成 1-苯基-3,4-二氢异喹啉 参考文献:Synthesis Of A High-Efficiency Red Phosphorescent Emitter For Organic Light-Emitting Diodes 标题:Synthesis Of A High-Efficiency Red Phosphorescent Emitter For Organic Light-Emitting Diodes 摘要:合成了四种新型红色磷光发射体化合物:双(1-苯基异喹啉-N,C2')铱(乙酰丙酮),(Piq)2Ir(Acac),双(1-(1'-萘基)异喹啉-N,C2')铱(乙酰丙酮),(1-Niq)2Ir(Acac),双(1-(2'-萘基)异喹啉-N,C2')铱(乙酰丙酮),(2-Niq)2Ir(Acac)和双(1-苯基-5-甲基异喹啉-N,C2')铱(乙酰丙酮),(M-Piq)2Ir(Acac),并对其进行了全面表征.制备了结构为ito/npb/cbp:掺杂剂/bcp/alq3/al的电致发光器件.所有器件在红色区域发射,发射范围从624到680 Nm.(M-Piq)2Ir(Acac)在电流密度j=300 Ma Cm−2时显示出最大亮度17164 Cd M−2,在电流密度j=20 Ma Cm−2时显示出最佳亮度效率8.91 Cd A−1.(1-Niq)2Ir(Acac)表现出纯红色发射,1931Cie(国际照明委员会)色度坐标x=0.701,Y=0.273. DOI:10.1039/b313843G
专利号:CN-107384885-A 优先权日:2017-09-05 标题:Application of imine reductase and its mutants in the synthesis of (S)-1-aryl-1,2,3,4-tetrahydroisoquinolines
专利号:CN-107384885-B 优先权日:2017-09-05 标 题:Application of imine reductase and mutant thereof in synthesis of (S) -1-aryl-1, 2, 3, 4-tetrahydroisoquinoline
专利号:CN-109355266-B 优先权日:2018-11-06 标题 :Imine reductase mutant and application thereof in synthesis of optically active 1-substituted-tetrahydroisoquinoline derivative
专利号:CN-110041255-A 优先权日:2019-04-28 标 题 :Asymmetric Synthesis of Solifenacin Intermediates
专利号:CN-108329309-A 优先权日:2018-04-17 标 题 :A kind of synthesis process of solifenacin succinate bulk drug
专利号:US-7642357-B2 优先权日:2004-08-27 标 题 :Iridium complexes 发明人:MASHIMA KAZUSHI; YAMAGATA TSUNEAKI 权利人:TAKASAGO PERFUMERY CO LTD 摘要:The present invention has as its object to provide an iridium complex represented by the general formula:n n[(I r H L 1 L 2 ) 2 (μ−X 1 )(μ−X 2 )(μ−X 3 )]X 4   (1)n n(wherein L 1 and L 2 may be the same or different and each represent a monodendate neutral ligand, or each cooperate with the other to form a bidendate neutral ligand; X 1 , X 2 and X 3 may be the same or different, and each represent a halogen atom; and X 4 is a counter-anion). Also, the present invention provides a novel catalyst which can achieve excellent performance as a catalyst for asymmetric synthesis, especially asymmetric hydrogenation, in terms of chemical selectivity, enantioselectivity and catalytic activity, and the like.
参考标题:A Versatile Cyclodehydration Reaction For The Synthesis Of Isoquinoline And β-Carboline Derivatives 作者:Mohammad Movassaghi,Matthew D. Hill |发布日期:2008.8.21 摘要:Beta-Carboline Derivatives Via Mild Electrophilic Amide Activation, With Trifluoromethanesulfonic Anhydride In The Presence Of 2-Chloropyridine, Is Described. Low-Temperature Amide Activation Followed By Cyclodehydration Upon Warming Provides The Desired Products With Short Overall Reaction Times. The Successful Use Of Nonactivated And Halogenated Phenethylene Derived Amides, N-Vinyl Amides, And Optically Active
合成参考文献
摘要:Leipold, F.; Hussain, S.; France, S. P.; Turner, N. J., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 2, 359. 摘要:Li, D.-D.; Wang, G.-W., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 316. 摘要:Li, D.-D.; Wang, G.-W., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 344. 摘要:Xing, Y.-K.; Fang, P.; Wang, Z.-H.; Mei, T.-S., Science of Synthesis: Special Topics, (2021) 1, 146.