📜酰氧基丙基双封头置于potassium Carbonate体系中,用 甲醇 用作溶剂,化学反应 2.0H,反应生成1,3-二(3-羟基丙基)-1,1,3,3-四甲基二硅氧烷 参考文献:Synthesis Of Polyesters Containing Disiloxane Subunits: Structural Characterization,Kinetics,And An Examination Of The Thermal Tolerance Of Novozym-435 标题:Synthesis Of Polyesters Containing Disiloxane Subunits: Structural Characterization,Kinetics,And An Examination Of The Thermal Tolerance Of Novozym-435 摘要:This Paper Reports The Novozym-435 Mediated Polymerization Of Disiloxane-Containing Polyester Monomers Under Solvent-Free Conditions. The Thermal Tolerance Of The Immobilized Enzyme Was Examined By Conducting Polymerization Cycles Over A Temperature Range Of 35-150 Degrees C. Increasing The Temperature Up To 100 Degrees C Afforded An Increase In The Apparent Second Order Rate Constant. Residual Activity Was Measured Using The Production Of octyl Palmitate. The Enzyme Was Shown To Retain On Average Greater Than 90% Of Its Residual Activity Regardless Of The Polymerization Temperature. This Prompted A Study Of The Long Term Thermal Tolerance Of The Biocatalyst In Which It Was Determined That Over Ten Reaction Cycles There Was A Significant Decrease In The Initial Polymerization Rate,But No Change In The Degree Of Monomer Conversion After 24 H. The Disiloxane Containing Polyesters Were Characterized Using Nuclear Magnetic Resonance Spectroscopy And Fourier-Transform Infrared Spectroscopy. Differential Scanning Calorimetry Was Used To Determine The Thermal Properties Of The Disiloxane-Containing Polyesters. (C) 2012 Elsevier B.V. All Rights Reserved. Doi:10.1016/j.Molcatb.2012.09.010
专利号:US-7871987-B2 优先权日:2004-12-16 标 题:Ester derivatives of ascorbic and 2-keto acid saccharides 发明人:MCAULIFFE JOSEPH C; SMITH WYATT CHARLES; STARCH MICHAEL S 权利人:DOW CORNING 摘要:Novel ester derivatives of ascorbic acid and 2-keto-acid saccharides are provided wherein the ester is introduced by ester bond formation between at least one hydroxy-functionality on the ascorbic acid or 2-keto-acid saccharide and a carboxy-functional organosiloxane, or between a 2-keto-gulonic acid and a hydroxy-functional organosiloxane, as well as methods for their synthesis. Treatment, cosmetic, and personal care formulations comprising the novel esters are also provided, including controlled release forms thereof.
专利号:CN-116285356-A 优先权日:2023-05-09 标 题 :Synthesis process and application of organosilicon elastomer heat-conducting wave-absorbing material