CAS: 17599-61-0; (E)-1-Phenyl-N-(Trimethylsilyl)Methanimine
该化合物是一种有机硅化合物,其特点是反应性金属组,结为三甲基硅酸基,这种结构具有独特的反应性,在有机合成中具有价值,特别是作为含有硅的中间体或保护组的前体.三甲基硅基混合物可增强稳定性并影响消毒和电子特性,而苯甲基乙烯细胞则在进一步发挥功能方面具有多功能性.其应用包括在交叉反应,水合和作为先进材料的建筑块中使用.该化合物的平衡反应性和稳定性使其适合于在温和空气条件下进行受控制的合成变异.建议通过对湿气和空气的潜在敏感性在惰性大气中进行适当处理.
- 英文名称(E)-1-Phenyl-N-(Trimethylsilyl)Methanimine
- 中文名称N-三甲基硅基苯甲醛亚胺
- IUPAC名称(E)-1-phenyl-N-(trimethylsilyl)methanimine
- 其它别名[1-Phenyl-Methylidene]-Trimethylsilanyl-Amine; (Benzylidene)(Trimethylsilyl)Amine; N-Trimethylsilylbenzaldimine; N-Trimethylsilylbenzaldimine ; (E)-1-Phenyl-N-Trimethylsilylmethanimine; Silanamine, 1,1,1-Trimethyl-N-(Phenylmethylene)-; N-Trimethylsilylbenzaldimine
- CAS编号17599-61-0
- MFCD编号:MFCD00463605
- EINECS号:627-863-1
- 分子式:C10H15NSi分子量:177.32
- 产品CID: 897986
- 产品分类化学试剂 → 有机试剂 → 亚氨、脒
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
CAS号999-97-3 六甲基二硅氮烷 | CAS号100-52-7 苯甲醛 | CAS号4039-32-1 六甲基二硅基胺基锂 | CAS号75-77-4 三甲基氯硅烷 | CAS号100-47-0 苯甲腈 | CAS号16118-22-2 N-Benzylideneamine | CAS号13892-06-3 1,1,1-三甲基-N-(三苯... | CAS号3475-21-6 4-甲基-2-苯基吡啶 | CAS号61501-04-0 2,2-二甲基-1-苯基丙烷-1-胺 | CAS号100-46-9 苄胺 | CAS号91-00-9 二苯甲胺 | CAS号207615-45-0 benzyl N-benzyl... | CAS号201856-48-6 (3R,4S)-3-(1-乙氧... | CAS号538-51-2 N-苄叉苯胺 | CAS号27593-61-9 methyl N-benzyl... | CAS号27068-65-1 2,4-二甲基-6-苯基吡啶 | CAS号32981-85-4 (2R,3S)-3-苯甲酰氨基...合成工艺路线路线简述
海关参考信息
- 2902300000-甲苯
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:EP-0442576-A1
优先权日:1990-02-13
标 题:Synthesis of cis-beta-lactams with the aid of an alkali metal compound
发明人：VAN KOTEN GERARD; VAN DER STEEN FREDERIK HENDRIK; JASTRZEBSKI JOHANN TONNS BARTH; KLEIJN HENK
权利人:UNIV UTRECHT
摘要:A synthesis of cis -β-lactams in a nearly quantitative yield by a condensation reaction of an alkali metal enolate, a substituted glycine ester and an alkali metal base, with an activated imine, is provided.
专利号:US-8207358-B2
优先权日:2005-11-04
标 题:Methods for the preparation of taxanes using chiral auxiliaries
发明人：LOURDUSAMY METTILDA; CARON GAETAN
权利人:LOURDUSAMY METTILDA; CARON GAETAN; ACCORD HEALTHCARE LTD
摘要:The present invention relates to a stereoselective synthesis of novel β-lactam dimers as useful precursors for the preparation of paclitaxel, docetaxel, and analogues thereof. More particularly, the new β-lactams are prepared from readily available and enantiomerically pure chiral auxiliaries. The β-lactams are then reacted with a suitably protected taxane to produce diastereomerically enriched side chain-bearing taxanes. Finally, the chiral auxiliary is cleaved and protecting groups are removed to provide the desired taxane.
专利号:US-7541458-B2
优先权日:2005-06-10
标题:β-lactam synthesis
发明人：VU PHONG; HOLTON ROBERT A
权利人:UNIV FLORIDA STATE RES FOUND
摘要:The present invention is directed to a process for the preparation of β-lactams. Generally, an imine is cyclocondensed with a ketene acetal or enolate to form the β-lactam product in a “one potâ€? synthesis, this process is generally performed at a higher temperature than conventional processes.
专利号:JP-H04211092-A
优先权日:1990-02-13
标题 :Synthesis of cis-β-lactams with the aid of alkali metal compounds
专利号:CA-2036152-A1
优先权日:1990-02-13
标 题 :Synthesis of cis-beta-lactams with the aid of an alkali metal compound
专利号:MX-2007015593-A
优先权日:2005-06-10
标题:SYNTHESIS OF BETA-LACTAMA.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Jackowski, O.; Perez-Luna, A., Science of Synthesis Knowledge Updates, (2022) 3, 80.
摘要:Chemla, F.; Ferreira, F.; Pérez-Luna, A., Science of Synthesis Knowledge Updates, (2012) 1, 475.
摘要:Tius, M. A., Science of Synthesis Knowledge Updates, (2022) 1, 453.
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