📜以 Neat (No Solvent) 用作溶剂,化学反应生成溴化镥 参考文献:The Ammonium-Bromide Route To Anhydrous Rare Earth Bromides Mbr3 标题:The Ammonium-Bromide Route To Anhydrous Rare Earth Bromides Mbr3 摘要: Doi:10.1016/0022-5088(87)90372-9
专利信息
专利号:US-7485741-B2 优先权日:2002-12-02 标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds 发明人:BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE 权利人:RHODIA POLYAMIDE INTERMEDIATES 摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.
专利号:US-12209104-B1 优先权日:2018-07-11 标 题:Metal complexes and methods of making the same 发明人:KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA 权利人:TRIAD NAT SECURITY LLC 摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.
参考文献:10.1007/978-3-030-29430-4_2 摘要:Vogt N, Vogt J. Inorganic Molecules without Carbon Atoms. 2019. In: Structure Data of Free Polyatomic Molecules. 参考文献:10.1134/s0036023625600571 摘要:Akulinin PV, Savinkina EV, Grigoriev MS. Features of Changes in Composition and Structures of Rare-Earth Halide Complexes with Acethylurea. Russ. J. Inorg. Chem. 2025 Apr;70(4):521–9. doi: 10.1134/s0036023625600571.