CAS: 97614-42-1; (2R,5R)-3-(((1H-Imidazol-1-yl)Sulfonyl)Oxy)-5-((Benzoyloxy)Methyl)Tetrahydrofuran-2,4-Diyl Dibenzoate
该化合物是一种复杂的有机化合物,其结构成分特征包括:由三种苯甲酸酯组和来自二硝酸二甲酸酯的磺酸盐组组成的乳糖酸糖混合物.该化合物具有五人组成的环状糖糖结构,有助于其生物关联性,特别是在核酸化学中.多苯甲酸组的存在表明存在一定程度的缺水性,可影响其溶性以及与生物膜的相互作用. 酸盐混合物可能具有独特的特性,例如潜在的缓冲能力或与金属离子的相互作用,增强其在生物化学应用中的效用.
- 英文名称(2R,5R)-3-(((1H-Imidazol-1-yl)Sulfonyl)Oxy)-5-((Benzoyloxy)Methyl)Tetrahydrofuran-2,4-Diyl Dibenzoate
- 中文名称(2R,5R)-3-(((1H-咪唑-1-基)磺酰基)氧基)-5-((苯甲酰氧基)甲基)四氢呋喃-2,4-二苯甲酸二酯
- IUPAC名称(2R,3R,4R,5R)-3-(((1H-imidazol-1-yl)sulfonyl)oxy)-5-((benzoyloxy)methyl)tetrahydrofuran-2,4-diyl dibenzoate
- 其它别名2-(1'-Imidazoylsulfonyl)-1,2,5-Tri-O-Benzoyl-α-D-Ribofuranose; 1,2,5-Tri-O-Benzoyl-2-(1'-Imidazoylsulfonyl)-A-D-Ribofuranose; 1,3,5-Tri-O-Benzoyl-2-O-(1'-Imidazoylsulfonyl)-A-D-Ribofuranose; 2-O-(Imidazolylsulfonyl)-1,3,5-Tri-O-Benzoyl-α-D-Ribofuranose; A-D-Ribofuranose, 1,3,5-Tribenzoate 2-(1H-Imidazole-1-Sulfonate); α-D-Ribofuranose, 1,3,5-Tribenzoate 2-(1H-Imidazole-1-Sulfonate); 1,3,5-Tri-O-Benzoyl-2-O-(1H-Imidazol-1-Ylsulfonyl)-α-D-Ribofuranose; 2-(1'-Imidazoylsulfonyl)-1,3,5-Tri-O-Benzoyl-α-D-Ribofuranose
- CAS编号97614-42-1
- MFCD编号:MFCD07367507
- 分子式:C29H24N2O10S
- 分子量:592.58
- 产品CID: 2022280
- 产品分类有机原料→分子砌块→手性化合物→手性砌块
相似化合物
122111-11-9 97614-41-0 102029-58-3MSDS等安全信息
上下游产品
1H-imidazole 1,3,5-tri-O-benzoyl-α-D-ribofuranoside β-phenyl hydroxypropionate 1,3,5-tri-O-benzoyl-2-deoxy-2-fluoro-α-D-arabinofuranose 2-O-(fluorosulfonyl)-1,3,5-tri-O-benzoyl-α-D-ribofuranose合成工艺路线路线简述
- 合成目标产物 2-(1'-Imidazoylsulfonyl)-1,3,5-Tri-O-Benzoyl-Alpha-D-Ribofuranose 主要起始原料 Imidazole And 1,3,5-Tri-O-Benzoyl-D-Ribofuranose
- 288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Thionyl Chloride Catalysts: Dimethylformamide Solvents: Dichloromethane; -15 °C; 30 Min,-15 °C; -15 °C -> Rt; 3 H,Rt1.2 0 °C; 15 H,Rt
标题:Pharmaceutical Application Of 2'-Fluoro-4'-Azido-Nucleoside Analog Or Its Salt
参考文献:China]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Sulfuryl Chloride Solvents: Dimethylformamide,Dichloromethane; 30 Min,-40 °C; 3 H,Rt1.2 0 °C; 15 H,Rt
标题:Synthesis Of 1,3,5-Tri-O-Benzoyl-2-Deoxy-2-Fluoro-α-D-Arabinofuranose
作者:Zhu,Lihua; Chen,Qian; Xu,Yunfeng; Fan,Juzheng
参考文献:Huaxi Yaoxue Zazhi 日期:2005 卷标:20(3) 页码:207-210]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Thionyl Chloride Solvents: Dimethylformamide,Dichloromethane; 30 Min,-20 °C; 2.5 H,0 °C1.2 0 °C; 15 H,0 °C
标题:Synthesis Of Clofarabine
作者:Chen,Lili; Cen,Junda
参考文献:Zhongguo Yiyao Gongye Zazhi 日期:2006 卷标:37(8) 页码:508-510]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Thionyl Chloride Solvents: Dimethylformamide,Dichloromethane; Cooled; Cooled1.2 Cooled; Cooled1.3 Reagents: Water; Cooled
标题:Process For Preparation Of Clofarabine Intermediate 2-Deoxy-2-Fluoro-3,5-Di-O-Benzoyl-α-D-Arabinofuranosyl Bromide
参考文献:China]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Sulfuryl Chloride Solvents: Dimethylformamide,Dichloromethane; Rt -> -10 °C; -15 - -10 °C; 2 H,-15 - -10 °C1.2 -15 - -10 °C; 1.5 H,-15 - -10 °C; Overnight,Rt
标题:Method For Preparing Clofarabine With High Yield
参考文献:China]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Sulfuryl Chloride Solvents: Dimethylformamide,Dichloromethane; -15 °C; 30 Min,-15 °C; -15 °C -> Rt; 3 H,Rt1.2 0 °C; 15 H,Rt
标题:Preparation Of 2'-Fluoro-4'-Substituted Nucleoside Analogs As Antiviral Agents
参考文献:China]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Sulfuryl Chloride Solvents: Dimethylformamide,Dichloromethane; -20 °C; 2 H,-5 - 0 °C1.2 Overnight
标题:Improved Synthesis Of Clofarabine
作者:Guo,Shunmin; Deng,Sishan; Qi,Yiping; Lin,Sui
参考文献:Zhongguo Xiandai Yingyong Yaoxue 日期:2009 卷标:26(2) 页码:123-125]
288-32-4 + 22224-41-5 = 97614-42-1
反应条件:1.1 Reagents: Thionyl Chloride Solvents: Dichloromethane; Rt -> -10 °C; -10 °C; 50 Min,-10 °C1.2 2 H,Rt1.3 Reagents: Water; 0.5 H
标题:Method For Preparing Clofarabine
参考文献:China]
= 97614-42-1 [标题:Reaction Conditions
标题:1-Halo-2-Deoxy-2-Fluoroarabinofuranoside Derivatives From 1,3,5-Tri-O-Acylribofuranose
参考文献:European Patent Organization]
= 97614-42-1 [标题:Reaction Conditions
标题:Fluorocarbohydrates In Synthesis. An Efficient Synthesis Of 1-(2-Deoxy-2-Fluoro-β-D-Arabinofuranosyl)-5-Iodouracil (β-Fiau) And 1-(2-Deoxy-2-Fluoro-β-D-Arabinofuranosyl)Thymine (β-Fmau)
作者:Tann,Chou H.; Brodfuehrer,Paul R.; Brundidge,Steven P.; Sapino,Chester Jr.; Howell,Henry G.
参考文献:Journal Of Organic Chemistry 日期:1985 卷标:50(19) 页码:3644-7
咪唑,1,3,5-三苯甲酰基-D-呋喃核糖置于n,N-二甲基甲酰胺 氯化亚砜体系中,用 二氯甲烷 作为反应溶剂,以76%的收率获得产物2-(1'-咪唑磺酰氧基)-1,3,5-三苯甲酰氧基-Alpha-D-呋喃核糖
参考文献:2'-Fluoro-4'-Substituted Nucleosides,The Preparation And Use
标题:2'-Fluoro-4'-Substituted Nucleosides,The Preparation And Use
海关参考信息
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专利信息
专利号:CN-106536410-B
优先权日:2014-07-23
标 题:Synthesis of high-silica zeolites by inter-zeolite conversion without the use of organic structure directing agents
专利号:CN-106536410-A
优先权日:2014-07-23
标题:Synthesis of Silica Zeolites by Inter-Zeolite Transformation Without Organic Structure Directing Agents
专利号:CN-119504405-A
优先权日:2024-11-20
标 题 :Synthesis method of glutaric acid
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参考标题:Triethylamine Poly(Hydrogen Fluorides) In The Synthesis Of A Fluorinated Nucleoside Glycon作者:T.S. Chou,Lisa M. Becke,John C. O'Toole,M.Austin Carr,Bruce E. Parker |发布日期:1996.1
摘要:The Stereospecific Synthesis Of 6 Via A Highly Selective, Noncorrosive Fluorination Of 4 With Et3N.3Hf Was Discovered. The Intermediate Fluorosulfonate 5 Was Isolated, Purified And Its Structure Verified.
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