CAS: 7650-89-7; Tribenzylphosphine

该化合物是一种有机磷的化合物,其特点是磷原子与三个苯基组有结合,其化学配方为C21H21P,通常在室温下是白色至黄色的固体.该化合物因其在协调化学中的作用而闻名为离心机,由于它能够通过磷原子捐献电子密度,从而可以稳定金属复合体.丁基苯丙基苯在二氯甲烷和甲苯等有机溶剂中表现出中等溶性,使其在各种合成应用中有用.此外,它可以参与氧化等反应,并在某些条件下可以起到减少剂的作用.大体苯基组的存在有助于其发育特性,影响其再活性和与其他化学物种的相互作用.在处理丁基苯丙基苯时,应当注意安全防范,因为如果摄入或吸入,它可能会对健康造成危害.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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CAS号100-44-7 氯化苄 | CAS号2767-80-8 三(羟甲基)膦 | CAS号6921-34-2 苄基氯化镁 | CAS号14990-01-3 benzylphosphane | CAS号620-05-3 苄基碘 | CAS号56522-04-4 DIBENZYLPHOSPHINE | CAS号23743-25-1 1,2-BIS(DIBENZY... | CAS号17586-68-4 tribenzyl(methy... | CAS号4538-55-0 dibenzylphospho...

合成工艺路线路线简述

    📜苄基双(羟甲基)膦置于三乙胺体系中,化学反应生成 三苄基膦
    参考文献:Petrov,K.A. Et Al.,Journal Of General Chemistry Of The Ussr,1962,Vol. 32,# 2,P. 542-545
    标题:Petrov,K.A. Et Al.,Journal Of General Chemistry Of The Ussr,1962,Vol. 32,# 2,P. 542-545

    海关参考信息

    专利信息


    专利号:US-10889599-B2
    优先权日:2018-02-27
    标 题:1,1-diborylalkyl-1-metal compounds, preparation method thereof, and their applications toward synthesis of 1,1-diboronate ester compounds
    发明人:CHO SEUNG HWAN; LEE YEOSAN
    权利人:POSTECH ACAD IND FOUND
    摘要:The present invention relates to a 1,1-diborylalkyl-1-metal compound including one metal group together with two identical boron groups at the sp3 carbon center, and its use. Specifically, the present invention relates to development of novel organic reactions, synthesis of functional molecules, and synthesis of new drugs by applying the novel 1,1-diboryl-1-metal substituted alkyl compounds to various molecular libraries which could not be synthesized by conventional methodologies.

    专利号:US-4794199-A
    优先权日:1984-07-05
    标题:Process for synthesis of primary amines from olefins, syngas and ammonia
    发明人:LIN JIANG-JEN; KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention concerns the synthesis of primary amines from olefins, synthesis gas and ammonia via an amination process in the presence of a cobalt catalyst, an ether solvent and a tertiary group VB donor ligand.

    专利号:US-4891442-A
    优先权日:1987-03-09
    标 题 :Process for synthesis of β-phenylalanine
    发明人:LIN JIANG-JEN; KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:N-acetyl-β-phenylalanine is synthesized by reacting phenylacetaldehyde, acetamide and synthesis gas with a catalyst comprising a cobalt-containing compound in conjunction with a cocatalyst that may be either a Group VB or VIB containing ligand, or a rhodium compound optionally bonded to one or more Group VB or VIB donor ligands, at a temperature of at least 50° C. and a pressure of at least 500 psi.

    专利号:US-6051711-A
    优先权日:1997-10-24
    标 题 :Synthesis of swainsonine salts
    发明人:TROPPER FRANCOIS; SHAH RAJAN N; SHARMA PRADEEP
    权利人:GLYCODESIGN INC
    摘要:A method for synthesizing swainsonine salts and intermediates thereof comprising subjecting a compound of the formula I wherein R2 and R2' are the same or different and represent alkyl, halogen, alkenyl, alkoxy, cycloalkyl or aryl which may be substituted, to acid hydrolysis in the presence of a C1-4 alkanol to obtain a crystalline salt of swainsonine; and optionally, recrystallizing the swainsonine salt from a C1-4 alkanol. The reaction may be used in combination with one or more additional reaction steps.

    专利号:US-4303593-A
    优先权日:1979-06-16
    标 题 :Process for the dimerization of hexafluoropropene oxide
    发明人:KUEHNE GERHARD
    权利人:HOECHST AG
    摘要:In the dimerization of hexafluoropropene oxide to give oligomeric acid fluorides of the formula the ratio of the oligomeric constituents formed is directed, in an improved manner, towards the formation of the dimer (n=0) if the reaction is carried out in the presence of a catalyst system which consists of a mixture of a copper (I) compound and a copper (II) compound mixed with a complex-forming agent from the group of the nitriles, isocyanides, tertiary phosphines and cyclic hydrocarbons with 6 to 12 ring atoms and 2 to 3 double bonds in the ring, and an aprotic organic solvent. The dimer is an intermediate product in the synthesis of perfluoropropyl perfluorovinyl ether, the latter being employed as a comonomer in fluorine-containing copolymers.

    专利号:EP-2647639-A1
    优先权日:2012-04-06
    标题:ß-boration of alkene and alkyne intermediates
    权利人:LEK PHARMACEUTICALS
    摘要:The present invention relates to the field of organic chemistry, and in particular to the preparation of β-borated compounds. These β-borated compounds can be used as intermediates in the synthesis of pharmaceutically active agents such as Sitagliptin.

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    合成参考文献


    摘要:Gudat, D., Science of Synthesis Knowledge Updates, (2021) 1, 270.
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