CAS: 4098-98-0; Tetrakis(Trimethylsilyl)Silane

该化合物是一种硅化合物,其独特结构包括三硅基骨和多三甲基硅基组;该化合物因其高水平的硅替代作用而显著,有助于其稳定性和再活性;其典型表现为无色或苍白黄色液体,以其低挥发性和高热稳定性而著称;多种甲基和三甲基硅基组的存在增强了其疏水特性,使其在各种应用中有用,包括作为表面修饰剂和硅素材料合成.此外,该化合物的结构允许在有机硅化学和先进材料生产中用作前体的潜在用途;安全考虑包括在通风良好的地区处理该化合物,并使用适当的个人防护设备,因为硅可以是易燃的,而且可能与湿度发生反应.

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合成工艺路线路线简述

    📜Tetrakis(Dimethylsilyl)Silane置于溴,Lithium体系中,用 四氢呋喃,四氯化碳 作为反应溶剂,化学反应生成 四(三甲基硅基)硅烷
    参考文献:合成首个螺旋戊硅烷,八甲基硅戊五硅烷
    标题:合成首个螺旋戊硅烷,八甲基硅戊五硅烷
    摘要:锂金属对四氢呋喃中的四(二甲基溴甲硅烷基)硅烷或四(二甲基氯甲硅烷基)硅烷的作用产生了首个螺旋戊硅烷,一种高应变应变的聚硅烷,它与氢化铝锂,甲基溴化镁和五氯化磷进行了有效的裂解反应.
    DOI:10.1039/c39840000777

    专利信息


    专利号:US-6187283-B1
    优先权日:1995-11-15
    标 题 :Hydrothermal conversion of Y-zeolite using alkaline earth cations
    发明人:CHIYODA OSAMU; DAVIS MARK E
    权利人:CALIFORNIA INST OF TECHN
    摘要:Hydrothermal synthesis of the natural, alkaline earth zeolites via the alteration of Y-zeolite is presented. Synthetic versions of the zeolites harmotome, heulandite, brewsterite and gmelinite are synthesized from Y-zeolite using alkaline earth cations containing solutions. The effect of the composition of the starting zeolite, the composition of the solution phase, the presence or absence of seeds and the experimental conditions are discussed.

    专利号:US-6436364-B1
    优先权日:1995-11-15
    标 题:Hydrothermal conversion of Y-zeolite using alkaline earth cations
    发明人:CHIYODA OSAMU; DAVIS MARK E
    权利人:CALIFORNIA INST OF TECHN
    摘要:Hydrothermal synthesis of the natural, alkaline earth zeolites via the alteration of Y-zeolite is presented. Synthetic versions of the zeolites harmotome, heulandite, brewsterite and gmelinite are synthesized from Y-zeolite using alkaline earth cations containing solutions. The effect of the composition of the starting zeolite, the composition of the solution phase, the presence or absence of seeds and the experimental conditions are discussed.

    专利号:US-2011111962-A1
    优先权日:2007-07-23
    标 题 :Improvements in magnesium diboride superconductors and methods of synthesis
    发明人:WANG XIAOLIN; DOU SHI XUE; HOSSAIN MD SHAHRIAR AL; CHENG ZHENXIANG
    权利人:UNIV WOLLONGONG
    摘要:Improved magnesium diboride superconducting materials and methods of synthesis are disclosed. Embodiments of the superconducting material comprise at least two starting materials capable of forming MgB 2 and at least one dopant compound comprising silicon, carbon, hydrogen and oxygen. The starting materials and the at least one dopant compound are heated and mixed at an atomic level to produce a silicon-doped MgB 2 superconducting material. Examples of the dopant compound include silicone oil, Triacetoxy(methyl)silane ( 2 ), 1,7-Dichloro-octamethyltetrasiloxane ( 2 ) and Tetramethyl orthosilicate ( 6 ).

    专利号:US-8758653-B2
    优先权日:2009-06-02
    标 题 :Molecular optimization of multiply-functionalized mesostructured materials
    发明人:CHMELKA BRADLEY F; ATHENS GEORGE L; MESSINGER ROBERT
    权利人:CHMELKA BRADLEY F; ATHENS GEORGE L; MESSINGER ROBERT; UNIV CALIFORNIA
    摘要:A material and method for producing mesostructured materials with multiple functionalities that are independently adjustable and collectively optimizable is provided. The method uses a series of discrete synthesis steps under otherwise mutually incompatible conditions, e.g., from acidic, alkaline, and/or non-aqueous solutions, allows different functionalities to be introduced to the materials and optimized. To illustrate the method, cubic mesoporous silica films were prepared from strongly acidic solutions that were separately functionalized under highly alkaline conditions to incorporate hydrophilic aluminosilica moieties and under non-aqueous conditions to introduce perfluorosulfonic-acid surface groups.

    专利号:US-10343926-B1
    优先权日:2016-08-22
    标题 :Synthesis of hierarchical zeolites by solid state crystallization of aluminosilicate nanogels
    发明人:WANG SHENGNIAN; WANG YUXIN
    权利人:LOUISIANA TECH RES CORPORATION
    摘要:Hierarchically porous ZSM-5 zeolites, having macropores, mesopores, and micropores are formed using a solid-state crystallization process. An aluminosilicate nanogel prepared with precursors, solvent, and a structure-directing agent is provided. The solvent is evaporated from the aluminosilicate nanogel at room temperature. The dried aluminosilicate nanogel is then heated to promote crystallization. The crystallized zeolites are calcined to remove the structure-directing agent.

    专利号:US-10669156-B1
    优先权日:2016-08-22
    标 题:Synthesis of hierarchical zeolites by solid state crystallization of aluminosilicate nanogels
    发明人:WANG SHENGNIAN; WANG YUXIN
    权利人:LOUISIANA TECH RES CORPORATION
    摘要:Hierarchically porous ZSM-5 zeolites, having macropores, mesopores, and micropores are formed using a solid-state crystallization process. An aluminosilicate nanogel prepared with precursors, solvent, and a structure-directing agent is provided. The solvent is evaporated from the aluminosilicate nanogel at room temperature. The dried aluminosilicate nanogel is then heated to promote crystallization. The crystallized zeolites are calcined to remove the structure-directing agent.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Marschner, C.; Baumgartner, J., Science of Synthesis Knowledge Updates, (2013) 2, 122.
    摘要:Kleeberg, C., Science of Synthesis Knowledge Updates, (2017) 1, 181.
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