CAS: 36140-19-9; Dicyclohexylboryl Chloride Dicyclohexylchloroborane

上下游产品

CAS号110-83-8 环己烯 | CAS号1568-65-6 二环己基硼烷 | CAS号63348-81-2 单氯硼烷二甲基硫醚络合物 | CAS号1088-01-3 tricyclohexyl borate | CAS号55382-85-9 二环己基碘硼烷 | CAS号10025-91-9 三氯化锑 | CAS号4441-56-9 环己基硼酸 | CAS号101-83-7 二环己胺 | CAS号108-91-8 环己胺 | CAS号259672-48-5 4-[cyclohexyl(h... | CAS号28047-23-6 (chloro-cyclohe... | CAS号100-44-7 氯化苄 | CAS号21722-83-8 乙酸环己基乙酯 | CAS号835-68-7 Cyclohexyl(4-me...

环己烯置于chloroborane Methyl Sulfide Complex体系中,化学反应生成氯代二环己基硼烷
参考文献:Chiral Dihydroxyacetone Equivalents In Synthesis: Rapid Assembly Of Styryl 1,2-Polyols As An Entry To The Styryllactone Family Of Natural Products
标题:Chiral Dihydroxyacetone Equivalents In Synthesis: Rapid Assembly Of Styryl 1,2-Polyols As An Entry To The Styryllactone Family Of Natural Products
摘要:报告了一种迅速进入天然产物斯替利乳酸酯家族的多醇框架的方法.关键步骤是对一个手性二羟基丙酮等价物进行两次高度的非对映体选择性硼介导的醇缩反应,随后进行1,3-反式或1,3-顺式选择性还原.此外,环状醇缩产物的evans-Tishchenko还原使其与1,2-顺式醇缩产物达到平衡,之后再进行1,3-反式选择性还原.
Doi:10.1055/s-2002-31905

专利信息

专利号:US-5681978-A
优先权日:1993-07-07
标题:Method for the stereocontrolled synthesis of stegobinone and useful borane intermediates
发明人：MATTESON DONALD S; MAN HON-WAH; HO OLIVER
权利人:UNIV WASHINGTON
摘要:A method of synthesis of (2S,3R,1'R)-stegobinone(I) using borane intermediates and methods for the use of stegobinone (I) for attracting beetles of the Anobium species.

专利号:US-5463131-A
优先权日:1994-06-30
标题 :Synthesis of organohaloboranes and alkoxyorganoboranes
发明人：BURKHARDT ELIZABETH R
权利人:MINE SAFETY APPLIANCES CO
摘要:A one-step process is provided for the synthesis of organohaloboranes, including diisopinocampheylchloroborane, and alkoxyorganoboranes. The present process does not utilize a thermally unstable ether adduct or a malodorous dimethyl sulfide adduct as required in prior processes. In general, the organohaloboranes are synthesized in a single reactor by reacting olefin(s) and/or alkyne(s) with boron trihalide and diborane. Alkoxyorganoboranes are synthesized in a single reactor by reacting olefin(s) and/or alkyne(s) with alkylborate and diborane.

专利号:US-8425653-B2
优先权日:2009-03-20
标题:Plasmon mediated photoinduced synthesis of silver triangular bipyramids
发明人：MIRKIN CHAD A; ZHANG JIAN
权利人:MIRKIN CHAD A; ZHANG JIAN; UNIV NORTHWESTERN
摘要:A method of preparing silver triangular bipyramids having a high shape selectivity and low edge length variation is disclosed. Also disclosed are silver triangular bipyramids prepared by this method.

专利号:US-7884128-B2
优先权日:2005-10-13
标题:Process for total synthesis of pladienolide B and pladienolide D
发明人：KANADA REGINA MIKIE; ITO DAISUKE; SAKAI TAKASHI; ASAI NAOKI; KOTAKE YOSHIHIKO; NIIJIMA JUN
权利人:EISAI R&D MAN CO LTD
摘要:Process for producing compound of Formula: n nwherein P 2 , P 3 and R 2 are the same as defined below, characterized by comprising reacting a compound represented by Formula (7):n n nwherein P 3 means a protecting group for hydroxy group; and Het means a 1-phenyl-1H-tetrazol-5-yl group, with a compound represented by Formula (8):n n nwherein P 2 means a protecting group for hydroxy group; and R 2 means a phenyl group which may be substituted, in the presence of a base.

专利号:WO-2004009574-A1
优先权日:2002-07-22
标 题 :Synthesis of discodermolide
发明人：FLORENCE GORDON; KOCH GUIDO; LOISELEUR OLIVIER; MICKEL STUART JOHN; PATERSON IAN
权利人:NOVARTIS AG; NOVARTIS PHARMA GMBH; UNIV CAMBRIDGE TECH; FLORENCE GORDON; KOCH GUIDO; LOISELEUR OLIVIER; MICKEL STUART JOHN; PATERSON IAN
摘要:The invention relates to a process for preparing discodermolide, for preparing intermediates for the manufacture of discodermolide and discodermolide analogues and to the intermediates obtained during the process. Wherein the process proceeds via a tetraene of formula (IV).

专利号:US-9707553-B2
优先权日:2011-07-11
标题 :P-chirogenic organophosphorus compounds
发明人：JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; LAUREANO HUGO; HENRY JEAN-CHRISTOPHE; LEROUX FREDERIC; COLOBERT FRANCOISE
权利人:CENTRE NAT DE LA RECH SCIENT (CNRS); UNIV BOURGOGNE; UNIV STRASBOURG; SYNTHELOR SAS
摘要:P-chirogenic organophosphorus compounds of general formula (I), a process for the synthesis of the compounds of formula (I), and intermediate products of general formulae (II), (III) and (IV), as shown below, are involved in the synthesis of compounds (I). n n n n n n n n n n Metal complexes comprising compounds (I) as ligands are also described. The compounds and complexes are useful in asymmetric catalysis by transition metal complexes or organocatalysis, especially for asymmetric hydrogenation or allylation. Compounds of general formula (I) may be useful as agrochemical and therapeutic substances, or as reagents or intermediates for fine chemistry.