专利号:US-7399857-B2 优先权日:2005-03-31 标题 :Synthesis of organometallic cyclometallated transition metal complexes 发明人:LUSSIER BARBARA B; DEATON JOSEPH C 权利人:EASTMAN KODAK CO 摘要:A process for forming a tris-cyclometallated complex comprises the step of reacting;n a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.
专利号:US-2006224007-A1 优先权日:2005-03-31 标题 :Synthesis of organometallic cyclometallated transition metal complexes 发明人:LUSSIER BARBARA B; DEATON JOSEPH C 权利人:EASTMAN KODAK CO 摘要:A process for forming a tris-cyclometallated complex comprises the step of reacting; a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.
专利号:WO-2024126692-A1 优先权日:2022-12-15 标题 :Peracid promoters in the iridium-catalyzed hydrosilylation synthesis of haloalkylorganosilanes 发明人:SCHOLZ HENRIK; KROKE EDWIN; KRAUSHAAR KONSTANTIN; GLATZER HOLGER JÜRGEN; LEWIS KENRICK MARTIN; WAGNER ROLAND 权利人:MOMENTIVE PERFORMANCE MAT GMBH 摘要:The present invention is directed at a process for producing a compound of Formula (I): (R1)y(R2O)3-ySiCH2CHR3CR4R5X comprising reacting (a) an olefinic halide; (b) an alkoxysilane; (c) a catalytically effective amount of iridium-containing catalyst; and (d) a reaction-promoting effective amount of a peroxycarboxylic acid to produce the product of Formula (I).
专利号:US-2021363167-A1 优先权日:2018-07-27 标题:Method for the synthesis of iridium organometallic material 发明人:SANNER ROBERT DEAN 权利人:L LIVERMORE NAT SECURITY LLC 摘要:According to one embodiment, a method of synthesizing an organometallic iridium monomer compound includes obtaining a dimeric iridium compound having a halogenated bridge, refluxing a mixture comprising the dimeric iridium compound, a base, an ancillary ligand, and 1,2-dimethoxyethane for forming a precipitate of an organometallic iridium monomer, and filtering the refluxed mixture to collect the organometallic iridium monomer precipitate.
专利号:US-7005522-B2 优先权日:2004-06-29 标 题 :Synthesis of organometallic cyclometallated transition metal complexes 发明人:DEATON JOSEPH C 权利人:EASTMAN KODAK CO 摘要:A process for forming a tris-cyclometallated iridium or rhodium complex comprises reacting in the presence of a solvent:n a) a bis-cyclometallated complex comprising an Ir (III) or Rh (III) metal, two bidentate ligands, two monodentate ligands and a counterion, and b) a heterocyclic compound capable of forming an organometallic cyclometallated complex.
专利号:US-7015344-B2 优先权日:2004-06-29 标题 :Synthesis of organometallic cyclometallated group viiib metal complexes 发明人:DEATON JOSEPH C 权利人:EASTMAN KODAK CO 摘要:A process for forming an organometallic cyclometallated Group viiib metal complex comprises reacting a Group viiib metal compound with a heterocyclic compound capable of forming an organometallic cyclometallated complex in the presence of a solvent comprising an aromatic oxygen containing compound.
参考文献:10.1007/978-981-15-8625-5_5 摘要:Kumar A, Kumar A, Verma A, Singh DP, Mudila H, Kumar D, Srivastava R. Preparation and Optoelectronic Properties of Iridium (III) Complexes Based on 1,3,4-Oxadiazole and β-diketones. 2020. In: Springer Proceedings in Physics. 参考文献:10.1007/s10118-023-2922-6 摘要:Ji S, Lan H, Zhou S, Zhang X, Chen W, Jiang X. Ir(III)-based Ratiometric Hypoxic Probe for Cell Imaging. Chin J Polym Sci. 2023 Jan 16;41(5):794–801. doi: 10.1007/s10118-023-2922-6. 参考文献:10.1007/s11581-023-04946-8 摘要:Chu J, Gong J, Cheng Y, Xiong S. Effect of calcination temperatures on the electrocatalytic performance of IrO2@RGO for oxygen evolution reaction. Ionics. 2023 Apr 14;29(6):2417–25. doi: 10.1007/s11581-023-04946-8. 参考文献:10.1038/s41929-023-00937-0 摘要:Lee MG, Li X, Ozden A, Wicks J, Ou P, Li Y, Dorakhan R, Lee J, Park HK, Yang JW, Chen B, Abed J, dos Reis R, Lee G, Huang JE, Peng T, Chin Y, Sinton D, Sargent EH. Selective synthesis of butane from carbon monoxide using cascade electrolysis and thermocatalysis at ambient conditions. Nat Catal. 2023 Apr 03;6(4):310–8. doi: 10.1038/s41929-023-00937-0. 参考文献:10.1038/s41929-023-01017-z 摘要:Wang Q, Wang H, Cao H, Tung C, Liu W, Hung S, Wang W, Zhu C, Zhang Z, Cai W, Cheng Y, Tao HB, Chen HM, Wang Y, Li Y, Yang HB, Huang Y, Li J, Liu B. Atomic metal–non-metal catalytic pair drives efficient hydrogen oxidation catalysis in fuel cells. Nat Catal. 2023 Aug 31;6(10):916–26. doi: 10.1038/s41929-023-01017-z.