CAS: 1048-08-4; Tetraphenylsilane

该化合物是一个有机硅化合物,其特点是其独特的结构,其特点是将硅原子捆绑在四个苯环上.该化合物显示出硅和芳香烃的典型特性,包括稳定性和各种化学反应的潜力.硅原子的存在允许与其他化学物种进行有趣的互动,使其成为材料科学和有机化学的感兴趣对象.其芳香环有助于其电子特性,有可能允许在有机电子产品中应用,或作为前体用于合成更复杂的材料.此外,该化合物的溶性和再活性可因所使用的溶剂和条件而不同而不同,这对实际应用非常重要.

结构式图片

上下游产品

CAS号10026-04-7 四氯化硅 | CAS号591-50-4 碘苯 | CAS号775-12-2 二苯基硅烷 | CAS号7789-66-4 四溴化硅 | CAS号694-53-1 苯硅烷 | CAS号591-51-5 苯基锂 | CAS号789-25-3 三苯基硅烷 | CAS号98-13-5 苯基三氯硅烷 | CAS号76-86-8 三苯基氯硅烷 | CAS号1450-18-6 1,1,1-三甲基-2,2,2... | CAS号358-23-6 三氟甲磺酸酐 | CAS号27607-81-4 Phenylsilicium-... | CAS号27607-88-1 Tetrakis(triflu... | CAS号18826-13-6 4,4'-二(三苯基甲硅烷基)-联苯 | CAS号605-02-7 1-苯基萘 | CAS号604-53-5 1,1'-联萘 | CAS号462-06-6 氟苯 | CAS号10026-04-7 四氯化硅 | CAS号791-31-1 三苯基硅醇 | CAS号71-43-2 苯

合成工艺路线路线简述

  • 合成目标产物 Tetraphenylsilane 主要起始原料 Bromobenzene And Triphenylsilyl Chloride
  • (文献来源)合成步骤主要原料 Bromobenzene 和 Triphenylsilyl Chloride
三苯基氯硅烷置于ch3Mgi,Cl2体系中,用 乙醚 用作溶剂,化学反应生成四苯基硅烷
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.C,23,Page 72-75
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Si: Mvol.C,23,Page 72-75

专利信息


专利号:US-4348525-A
优先权日:1981-04-09
标题 :Composition and a process for the preparation of [hydroxy(organosulfonyloxy)iodo]arenes and their use in a regiospecific synthesis of diaryliodonium salts
发明人:KOSER GERALD F; WETTACH RICHARD H
权利人:UNIV AKRON
摘要:[Hydroxy(organosulfonyloxy)iodo]arenes are synthesized in neutral organic solvents by the reaction of ring-substituted [hydroxy(organosulfonyloxy)iodo]benzenes with iodoarenes via ligand transfer. The produced compounds are reacted with (triorganosilyl) arenes or (trihalosilyl)arenes in neutral organic solvents to produce diaryliodonium salts. The diaryliodonium salt synthesis proceeds in regiospecific fashion, aryliodination occurring at the point of attachment of the silicon atom in the silylarenes.

专利号:US-4826635-A
优先权日:1981-04-09
标题:Composition and a process for the preparation of (hydroxy (organosulfonyloxy)iodo)arenes and their use in a regiospecific synthesis of diaryliodonium salts
发明人:KOSER GERALD F; WETTACH RICHARD H
权利人:UNIV AKRON
摘要:[Hydroxy(organosulfonyloxy)iodo]arenes are synthesized in neutral organic solvents by the reaction of ring-subsituted [hydroxy(organosulfonyloxy)iodo]benzenes with iodoarenes via ligand transfer. The produced compounds are reacted with (triorganosilyl) arenes or (trihalosilyl)arenes in neutral organic solvents to produce diaryliodonium salts. The diaryliodonium salt synthesis proceeds in regiospecific fashion, aryliodination occurring at the point of attachment of the silicon atom in the silylarenes.

专利号:WO-2024100281-A1
优先权日:2022-11-10
标题:Solution-based synthesis of composites.
发明人:RYAN KEVIN M; COLLINS GEAROID
权利人:UNIV LIMERICK
摘要:A method for synthesizing an Si and/ or Ge NW/carbon composite in a solution-based approach is provided. The method comprises combining (i) a mixture of a lithium alloying metal and a carbon particle, (ii) an Si and/or Ge precursor and (iii) a refluxing solvent under reflux conditions and reacting to form the composites.

专利号:WO-2023217803-A1
优先权日:2022-05-09
标题 :A method for high yield nanowire synthesis
发明人:RYAN KEVIN M; KILIAN SEAMUS; KENNEDY TADHG
权利人:UNIV LIMERICK
摘要:A method for synthesizing a silicon and/or germanium nanowire(s) using a catalyst generated in situ is provided. The method provides high yield nanowire synthesis and comprises the steps of: combining a metal oxide, a reducing agent and a precursor in a reaction. The metal oxide and the reducing agent generate a metal oxide catalyst in situ in the reaction, and the catalyst reacts with the material from the precursor to synthesize nanowires.

专利号:US-6121495-A
优先权日:1995-09-12
标题:Ethynyl substituted aromatic compounds, synthesis, polymers and uses thereof
发明人:BABB DAVID A; SMITH JR DENNIS W; MARTIN STEVEN J; GODSCHALX JAMES P
权利人:DOW CHEMICAL CO
摘要:Compounds of ethynyl aromatic compounds form polymers which have high thermal stability. The monomers are useful for coating a wide variety of substances such as dielectric coatings where high thermal resistance is desirable including electronic components such as computer chips.

专利号:WO-2023277824-A2
优先权日:2021-07-01
标 题 :Diverse functionalization of hydrosilanes and programmable synthesis of multisubstituted organosilanes enabled by neutral eosin y photocatalysis
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合成参考文献


摘要:Hwu, J. R.; Ethiraj, K. S., Science of Synthesis, (2002) 4, 198.
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