专利号:US-2007249874-A1 优先权日:2004-06-23 标题 :Synthesis of the Micro-Porous Silica Gel and Its Application to the Preparation of Catalysts for C2 Oxygenates Synthesis from Syngas 发明人:LUO HONGYUAN; DING YUNJIE; YIN HONGMEI 权利人:BP PLC 摘要:A synthesis of the micro-porous silica gel and its application to preparation of catalysts for C 2 oxygenates synthesis from syngas is invented. The small particles of silica gel which are, produced by sol gel process are heated in a basic solution, followed by drying and/or calcinations, and thus form micro-porous silica as catalyst support. The basic solution can be one or a mixed solution of hydroxides, carbonates, bicarbonates, formates and acetates of alkali metal and ammonium. The obtained micro-porous silica can be impregnated with the solutions of rhodium salt and other transition element salts (as promoter precursors), followed by drying and/or calcinations, thus forming a micro-porous silica supported rhodium based catalyst. The rhodium salt can be RhCl 3 or Rh(NO 3 ) 3 . The promoter precursors can be water-dissolvable transition metal salts, rare earth metals salts, alkali metal salts and alkali earth metal salts. The obtained catalysts show high activity and selectivity in the synthesis of C 2 -oxygenates by the hydrogenation of CO under mild process conditions.
专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-6410814-B2 优先权日:2000-04-04 标题 :Process for synthesis of lower isoparaffins from synthesis gas 发明人:FUJIMOTO KAORU; TSUBAKI NORITATSU 权利人:TOYOTA MOTOR CO LTD; GENESIS RES INST INC 摘要:A process for synthesis of lower isoparaffins from synthesis gas that is a mixture of hydrogen and carbon monoxide, wherein straight chain hydrocarbons are synthesized while isoparaffins and isoolefins are also produced through decomposition of hydrocarbons having a higher carbon number by use of a solid acid catalyst in the first stage, and isoparaffins are synthesized in the second stage. The straight chain hydrocarbons are produced by contacting the synthesis gas with a Fischer-Tropsch synthesis catalyst that is mixed with a solid acid catalyst for mainly hydrocracking long chain hydrocarbons. The isoparaffins are produced by contacting the straight chain hydrocarbons synthesized in the first stage, with a mixture of a hydrogenation catalyst for hydrogenating olefins and a solid acid catalyst for hydrocracking and isomerizing the straight chain hydrocarbons.
专利号:WO-2020248278-A1 优先权日:2019-06-14 标题:Method for continuous synthesis of substituted benzoic-acid organic substance 发明人:HONG HAO; ZHANG ENXUAN; LU JIANGPING; LIU ZHIQING; LI CHAO; TANG YANG 权利人:JINLIN ASYMCHEM LABORATORIES CO LTD 摘要:The present invention provides a method for the continuous synthesis of a substituted benzoic-acid organic substance. The continuous synthesis method comprises: in the presence of catalyst and organic solvent, the organic matter represented by formula (I) and oxygen are continuously inputted to a continuous reaction apparatus for continuous oxidation reaction to obtain a substituted benzoic-acid organic substance, which is discharged continuously, the substituted benzoic-acid organic substance having the structure represented by formula (II). Oxygen is a green reagent and is inexpensive and readily available; a large amount of wastewater, waste gas, and solid waste is not generated after the reaction, and the system is easy to handle. The use of a continuous reaction operation can reduce the risk of flash distillation and explosion of solvent due to a high concentration of oxygen in a batch reaction. Under the same oxidation conditions, the continuous preparation process can reduce the escape of oxygen, greatly increasing the oxygen utilization rate and also simplifying the operation, improving the safety of the reaction and the yield of the substituted benzoic-acid organic substance.
专利号:US-9011694-B2 优先权日:2010-09-28 标 题 :Method for the synthesis of tetravalent manganese feroxyhite for arsenic removal from water 发明人:MITRAKAS MANASSIS; SYMEONIDIS KONSTANTINOS; TRESINTSI SOFIA 权利人:MITRAKAS MANASSIS; SYMEONIDIS KONSTANTINOS; TRESINTSI SOFIA; LOUFAKIS CHEMICALS S A 摘要:The present invention refers to a method for the synthesis of an adsorbing material consisting of a single-phase tetravalent manganese feroxyhite (Å?-Fe (1-x) Mn x OOH), in which a percentage of 0.05 to 25% of iron atoms has been isomorphically substituted by Mn(IV) atoms. Its production takes place in a continuous two-stage flow reactor at weakly acidic conditions (pH 4-7) and high redox (300-800 mV). The material can be used for the removal of both pentavalent and trivalent arsenic as well as other heavy metals form water. More specifically, its adsorption capacity and selectivity depending on the trivalent and pentavalent arsenic water content, are determined by the manganese percentage and the compact or hollow morphology of its structural unit which can be both controlled by the parameters of the synthesis procedure.
专利号:US-2023278888-A1 优先权日:2022-03-07 标题 :Accelerated Synthesis of Nickle-Rich Cathode Materials Using Flame-Assisted Spray Pyrolysis 发明人:DENG SILI; ZHANG JIANAN; MULDOON VALERIE L 权利人:MASSACHUSETTS INST TECHNOLOGY 摘要:Methods of synthesis of nickel-rich cathode materials can include preheating droplets, decomposing the droplets in a burner, collecting solid particles, and calcinating the solid particles.
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