CAS: 97886-45-8; S,S-Dimethyl 2-(Difluoromethyl)-4-Isobutyl-6-(Trifluoromethyl)Pyridine-3,5-Bis(Carbothioate)

该化合物是一种化学化合物,主要用于农业和园艺应用中的一种发芽前除草剂,属于二硫甲酸酯类,以其能够阻止某些年生草和大叶杂草生长为名,干扰种子发芽和根茎发育,其特点是水溶性相对较低,允许其在土壤中长期存在,并提供扩大的杂草控制.该化合物具有中等毒性,需要谨慎处理和应用,以尽量减少环境影响,确保非目标生物的安全.其作用方式包括抑制细胞分解,特别是在植物的分子组织中.Dithiopyr经常以多种方式进行配制,包括颗粒和乳化精,以提高其功效和应用的便利性.与许多除草剂一样,抗药管理战略对于保持其有效性十分重要.

结构式图片

物理性质

欧盟法规

C&L通报REACH预注册

合成工艺路线路线简述

  • 97898-34-5 = 97886-45-8
    反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Trioctylmethylammonium Chloride Solvents: Dichloromethane,Water
    标题:A Process For Preparation Of Aromatic Thiol Esters
    参考文献:United States]

    137419-53-5 = 97886-45-8
    反应条件:1.1 Reagents: Dabco
    标题:Process For Preparation Of Fluoromethylated Piperidinedicarbothioates
    参考文献:European Patent Organization]

    = 97886-45-8 [标题:Reaction Conditions
    标题:Pyridinedicarbothioate And Pyrimidinylureidosulfonylpyrazolecarboxylate Herbicide Mixture
    参考文献:Japan]

    97898-34-5 + 5188-07-8 = 97886-45-8
    反应条件:1.1 Catalysts: Tetrabutylammonium Chloride Solvents: Toluene,Water; 25 °C; 4 H,25 °C
    标题:Synthesis Of Dithiopyr
    作者:Zhou,Kunying; Shen,Jianshi; Han,Ping; Wei,Xinghui
    参考文献:Nongyao 日期:2012 卷标:51(4) 页码:251-253]

    118528-85-1 = 97886-45-8
    反应条件:1.1 Reagents: Ammonia Solvents: Acetonitrile1.2 Reagents: Phosphorus Oxychloride Solvents: Toluene1.3 Reagents: Dabco Solvents: Water
    标题:Process For Preparation Of Fluoromethylated Pyridinedicarbothioates
    参考文献:European Patent Organization]

    118528-85-1 = 97886-45-8
    反应条件:1.1 Solvents: Acetonitrile1.2 Reagents: Hydrochloric Acid,Ammonia Solvents: Water1.3 Reagents: Dabco,Potassium Carbonate Solvents: Toluene
    标题:Process For Preparation Of Fluoromethylated Dihydropyridinedicarbothioates
    参考文献:European Patent Organization]

    97898-34-5 + 5188-07-8 = 97886-45-8
    反应条件:1.1 Solvents: Dichloromethane; 3.5 H,0 °C
    标题:Processes For Preparation Of Haloalkyl Pyridinyl Compounds And Intermediates Thereof,As Agrochemicals And Pharmaceuticals
    参考文献:European Patent Organization]

    = 97886-45-8 [标题:Reaction Conditions
    标题:Process For Preparation Of Fluoromethylated Piperidinedicarbothioates
    参考文献:European Patent Organization]

    = 97886-45-8 [标题:Reaction Conditions
    标题:Substituted 2,6-Substituted Pyridine Compounds
    参考文献:European Patent Organization

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:ES-2717283-T3
优先权日:2012-07-24
标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
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合成参考文献


摘要:Ecobichon DJ, ed; Occupational Hazards of Pesticide Exposure, Sampling, Monitoring, Measuring. Philadelphia, PA: Taylor & Francis, p.56, ISBN 1-56032-706-3 (1999)
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
参考文献:10.1002/ps.786
摘要:Kuk YI, Kim KH, Kwon OD, Lee DJ, Burgos NR, Jung S, Guh JO. Cross‐resistance pattern and alternative herbicides for Cyperus difformis resistant to sulfonylurea herbicides in Korea. Pest Management Science. 2003 Nov 03;60(1):85–94. doi: 10.1002/ps.786.
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