CAS: 872-17-3; 11-Chloro-1-Undecene
该化合物是一种线性脂类化合物,在C1 位置上有一个末端氯组和不饱和的双倍联结.这种双功能分子是有机合成的多功能中间体,特别是在生产精细化学品,聚合物和特殊材料方面.它的被动反应点可以进一步实现功能化,例如氯组的核循环替代或双重联结的附加反应.该化合物的界定明确的结构和高纯度使它适合在制药,农用化学品和材料科学领域进行精确应用.在受控制的条件下,其稳定性确保了合成工作流程的可靠性能.产品通常得到严格的质量控制,以满足研究和工业要求.
相似化合物
871-90-9 1002-70-6 928-50-7物理性质
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号112-43-6 10-十一烯醇 | CAS号111-81-9 10-十一烯酸甲酯 | CAS号112-46-9 undec-9-enol | CAS号1653-30-1 2-十一醇 | CAS号29043-93-4 11-Chloro-1-undecyne | CAS号2424-90-0 十七烷二酸 | CAS号871-70-5 十八烷二酸 | CAS号62871-09-4 10-溴-1-癸烯 | CAS号130727-46-7 2-[2-[2-(2-unde... | CAS号4860-03-1 氯代十六烷 | CAS号130727-42-3 Thiol-C9-PEG5 | CAS号130727-51-4 [11-(甲基羰基硫基)十一烷... | CAS号120876-31-5 11-CHLOROUNDECY... | CAS号7735-38-8 13-羟基十三烷酸合成工艺路线路线简述
- 112-38-9 = 872-17-3
反应条件:1.1 Reagents: 1,1,3,3-Tetramethyldisiloxane,Cupric Chloride Catalysts: Gallium Chloride Solvents: 1,2-Dichloroethane; 3 H,80 °C
标题:Gallium-Catalyzed Reductive Chlorination Of Carboxylic Acids With Copper(Ii) Chloride
作者:Sakai,Norio; Et Al
参考文献:Journal Of Organic Chemistry 日期:2014 卷标:79(21) 页码:10619-10623]
111-81-9 = 872-17-3
反应条件:1.1 Reagents: Lithium Aluminum Hydride2.1 Reagents: Thionyl Chloride
标题:Synthesis Of ω-Functional Organosilicon Compounds Based On Undecylenic Acid
作者:Staroverov,S. M.; Et Al
参考文献:Zhurnal Obshchei Khimii 日期:1979 卷标:49(11) 页码:2487-90]
557-08-4 = 872-17-3
反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 30 Min,0 °C; 1 H,0 °C -> Rt1.2 Reagents: Water; 15 Min,Rt1.3 Reagents: Sodium Hydroxide Solvents: Water; 15 Min,Rt1.4 Reagents: Water; Rt2.1 Reagents: Thionyl Chloride Solvents: Pyridine; Rt; 2 H,50 °C2.2 Reagents: Water Solvents: Diethyl Ether; 1 H
标题:The Facile Preparation Of Alkenyl Metathesis Synthons
作者:Baughman,Travis W.; Et Al
参考文献:Tetrahedron 日期:2004 卷标:60(48) 页码:10943-10948]
1584705-82-7 = 872-17-3 + 7766-49-6
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 2,2′-Bipyridine,Cupric Chloride Solvents: 1,2-Dichloroethane; 12 H,120 °C
标题:Copper-Catalyzed Trifluoromethylthiolation Of Primary And Secondary Alkylboronic Acids
作者:Shao,Xinxin; Et Al
参考文献:Organic Letters 日期:2014 卷标:16(18) 页码:4738-4741]
112-43-6 = 872-17-3
反应条件:1.1 Reagents: Pyridine,Thionyl Chloride
标题:Synthesis Of ω-Unsaturated Acids
作者:Mirviss,Stanley B.
参考文献:Journal Of Organic Chemistry 日期:1989 卷标:54(8) 页码:1948-51]
112-43-6 = 872-17-3
反应条件:1.1 Reagents: Carbon Tetrachloride,Triphenylphosphine; 3 H,Reflux
标题:Reactivity And Kinetics Of Vinyl Sulfone-Functionalized Self-Assembled Monolayers For Bioactive Ligand Immobilization
作者:Wang,Hanqi; Et Al
参考文献:Langmuir 日期:2015 卷标:31(11) 页码:3413-3421]
= 872-17-3 + 7766-49-6
反应条件:1.1 Reagents: Sodium Periodate Solvents: Tetrahydrofuran,Water; 5 Min,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; 1 - 4 H,Rt2.1 Reagents: Potassium Carbonate Catalysts: 2,2′-Bipyridine,Cupric Chloride Solvents: 1,2-Dichloroethane; 12 H,120 °C
标题:Copper-Catalyzed Trifluoromethylthiolation Of Primary And Secondary Alkylboronic Acids
作者:Shao,Xinxin; Et Al
参考文献:Organic Letters 日期:2014 卷标:16(18) 页码:4738-4741]
7766-50-9 = 872-17-3 + 7766-49-6
反应条件:1.1 Reagents: Lithium Methoxide,Bis(Pinacolato)Diborane Catalysts: Triphenylphosphine,Cuprous Iodide Solvents: Dimethylformamide; 18 H,35 °C1.2 Reagents: Sodium Periodate Solvents: Tetrahydrofuran,Water; 5 Min,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; 1 - 4 H,Rt2.1 Reagents: Potassium Carbonate Catalysts: 2,2′-Bipyridine,Cupric Chloride Solvents: 1,2-Dichloroethane; 12 H,120 °C
标题:Copper-Catalyzed Trifluoromethylthiolation Of Primary And Secondary Alkylboronic Acids
作者:Shao,Xinxin; Et Al
参考文献:Organic Letters 日期:2014 卷标:16(18) 页码:4738-4741]
7766-50-9 + 73183-34-3 = 872-17-3 + 7766-49-6
反应条件:1.1 Reagents: Lithium Methoxide Catalysts: Triphenylphosphine,Cuprous Iodide Solvents: Dimethylformamide; 18 H,35 °C2.1 Reagents: Sodium Periodate Solvents: Tetrahydrofuran,Water; 5 Min,Rt2.2 Reagents: Hydrochloric Acid Solvents: Water; 1 - 4 H,Rt3.1 Reagents: Potassium Carbonate Catalysts: 2,2′-Bipyridine,Cupric Chloride Solvents: 1,2-Dichloroethane; 12 H,120 °C
标题:Copper-Catalyzed Trifluoromethylthiolation Of Primary And Secondary Alkylboronic Acids
作者:Shao,Xinxin; Et Al
参考文献:Organic Letters 日期:2014 卷标:16(18) 页码:4738-4741
10-十一烯-1-醇置于吡啶,氯化亚砜体系中,化学反应 2.0H,以90%的收率获得产物11-氯-1-十一碳烯
参考文献:利用appel反应通过生物合成方法获得取代呋喃的途径:呋喃脂肪酸f 5的全合成
标题:利用appel反应通过生物合成方法获得取代呋喃的途径:呋喃脂肪酸f 5的全合成
摘要:利用了appel反应条件来影响内合成过氧化物的温和生物合成激发的脱水作用,以递送多取代的富电子呋喃.与传统的脱水程序不同,此方法不含金属和酸,可以在氧化还原中性条件下实现.通常适用于一定范围的芳基和烷基取代的内过氧化物,并且对官能团具有耐受性.此外,该程序已用于提供呋喃脂肪酸(ffa)f 5的有效全合成.
DOI:10.1039/c7Cc03229C
海关参考信息
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2901220000-丙烯
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专利信息
专利号:US-8569560-B2
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis
发明人：SCHRODI YANN; PEDERSON RICHARD L; KAIDO HIROKI; TUPY MICHAEL J
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35° C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.
专利号:US-4845271-A
优先权日:1987-01-27
标 题:Process for the preparation of omega-unsaturated carboxylic acids
发明人：MIRVISS STANLEY B
权利人:AKZO AMERICA INC
摘要:An improved method for the synthesis of omega-unsaturated carboxylic acids is disclosed which precludes double bond migration or hydrogenation in order to prepare a high purity product necessary for high resolution in forming a resist by electron beam microlithography. This result can be obtained by a coupling reaction between a Grignard reagent of an unsaturated organochloride compound as defined in the application with a halo magnesium salt of a long chain organic acid.
专利号:US-8263774-B2
优先权日:2009-09-03
标题:Quinoline-oxazoline compounds and their use in oxidation synthesis
发明人：SIGMAN MATTHEW SCOTT; MICHEL BRIAN WILLIAM
权利人:SIGMAN MATTHEW SCOTT; MICHEL BRIAN WILLIAM; UNIV UTAH RES FOUND
摘要:A quinoline-oxazoline compound having the formula: n n n n n n n n n n n n where one of X 1 and X 2 is N and the other is C and one of R1, R2 and R3 is Z wherein Z is an oxazoline radical having the formula n n n n n nsuch that when X 1 is N R2 is Z and R1 is absent, and when X 2 is N either R1 or R3 is Z and R2 is absent. R1 and R3 through R12 are independently H or a pendant moiety which does not interfere with coordination of either N in the quinoline compound with a coordination center. These compounds can be complexed with a suitable coordination center such as catalytically active palladium and can be highly useful in catalytically oxidizing alkenes with high regioselectivity.
专利号:US-2013035532-A1
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis
专利号:US-2010145086-A1
优先权日:2006-10-13
标 题:Synthesis of Terminal Alkenes From Internal Alkenes Via Olefin Metathesis
专利号:US-2021130270-A1
优先权日:2018-07-16
标 题 :Synthesis of straight-chain lepidopteran pheromones through one- or two- carbon homologation of fatty alkenes
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合成参考文献
摘要:Okamoto, K.; Ohe, K., Science of Synthesis Knowledge Updates, (2020) 1, 40.
摘要:Wang, X.-Y.; Sun, X.-L., Science of Synthesis Knowledge Updates, (2020) 2, 460.
摘要:Ho, C.-Y.; Raja, D., Science of Synthesis: Knowledge Updates, (2023) 1, 50.
摘要:Ho, C.-Y.; Raja, D., Science of Synthesis: Knowledge Updates, (2023) 1, 47.
摘要:Adak, L.; Sahoo, S.; Aoki, S.; Kawanaka, Y.; Nakamura, M., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 418.
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