CAS: 510-75-8; Gibberellin A7

该化合物是属于胡贝林家族的植物激素,在调节植物的各种生理过程,包括生长,种子发芽和花朵方面发挥着关键作用;是四环二化合物,其特点是能够促进干叶延长和增强水果开发; GA7因其在打破种子的耐久性并在发芽期间刺激酶生产方面的有效性而特别引人注目;该化合物在植物中合成,也可以通过发酵过程利用特定的微生物产生;它在农业中的应用包括通过操纵生长模式提高作物产量和质量;GA7一般认为在农业实践中使用是安全的,但其影响可因植物物种和环境条件而异;它的活动受到其他激素和环境因素的影响,使它成为植物生长管制中的一个关键组成部分.

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CAS号77-06-5 赤霉素

合成工艺路线路线简述

    📜赤霉素置于吡啶,四氯化碳,2-(2-Cyanopropan-2-Yldiazenyl)-2-Methylpropanenitrile,三正丁基氢锡,三苯基膦体系中,化学反应生成 赤霉素 A7
    参考文献:Voigt,B.; Adam,G.,Zeitschrift Fur Chemie,1988,Vol. 28,# 7,P. 263
    标题:Voigt,B.; Adam,G.,Zeitschrift Fur Chemie,1988,Vol. 28,# 7,P. 263

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    专利信息


    专利号:EP-3650430-A1
    优先权日:2015-05-12
    标题 :Intermediates and processes for the synthesis of herbicides

    专利号:US-5294593-A
    优先权日:1992-05-14
    标 题 :Inducing dormancy in non dormant seeds
    发明人:KHAN ANWAR A
    权利人:CORNELL RES FOUNDATION INC
    摘要:Dormant seeds , e.g., of lettuce, tomatoes, peppers, carrots, onions, impatiens and primrose, are produced by soaking non-dormant seeds in a solution of gibberellin synthesis inhibitor, preferably tetcyclacis, preferably in the dark at 25 degrees C. to 350 degrees C. for at least 24 hours, washing to remove the inhibitor and drying to original seed weight. The dormancy can be released by application of a gibberellin, and in some cases by moist chilling, or exposure to light at 25 degrees C. to 35 degrees C.

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    合成参考文献


    参考文献:10.2503/jjshs.68.1158
    摘要:Koshioka M, Roh M, Nakayama M, Hisamatsu T, Mander LN. Identification of Endogenous Gibberellins in Inflorescence of Ornithogalum thyrsoides. Engei Gakkai zasshi. 1999;68(6):1158–60. doi: 10.2503/jjshs.68.1158.
    参考文献:10.1111/j.1399-3054.1987.tb04342.x
    摘要:Jensen E, Junttila O. Endogenous gibberellins in young seedlings of wheat (Triticum aestivum) cultivars. Physiologia Plantarum. 1987 Nov;71(3):277–80. doi: 10.1111/j.1399-3054.1987.tb04342.x.
    参考文献:10.1016/s0040-4020(01)92692-4
    摘要:Cross BE, Galt RHB, Hanson JR. New metabolites of Gibberella fujikuroi—I. Tetrahedron. 1962 Jan;18(4):451–9. doi: 10.1016/s0040-4020(01)92692-4.
    参考文献:10.1124/mol.119.115964
    摘要:Lee TD, Lee OW, Brimacombe KR, Chen L, Guha R, Lusvarghi S, Tebase BG, Klumpp-Thomas C, Robey RW, Ambudkar SV, Shen M, Gottesman MM, Hall MD. A High-Throughput Screen of a Library of Therapeutics Identifies Cytotoxic Substrates of P-glycoprotein. Molecular Pharmacology. 2019 Nov;96(5):629–40. doi: 10.1124/mol.119.115964.
    参考文献:10.3389/fcimb.2021.743454
    摘要:Hu W, Huang L, Zhou Z, Yin L, Tang J. Diallyl Disulfide (DADS) Ameliorates Intestinal Candida albicans Infection by Modulating the Gut microbiota and Metabolites and Providing Intestinal Protection in Mice. Front. Cell. Infect. Microbiol. 2022 Jan 07;11(). doi: 10.3389/fcimb.2021.743454.
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