CAS: 7789-40-4; Thallium(I) Bromide

该化合物是一种无机化合物,其特点是晶体结构和高熔点,通常看起来像一种白色或无色固体,以其在水中的高溶性而著称; 哈龙溴具有半导体特性,在各种电子应用中,特别是在红外探测器和光导装置中,它具有实用性; 其毒性也值得注意,因为是一种重金属,在接触时会造成严重的健康风险; 就化学行为而言,TlBr可参与各种反应,包括涉及卤素交换和复杂形成的反应; 必须谨慎地处理溴,利用适当的安全措施减少与接触有关的风险; 此外,三丁基溴可通过(I)与氢氧化物或涉及盐的其他方法的反作用合成.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    📜溴化铵 反应生成 溴化铊
    参考文献:Smirnov,V. A.;Kopetskij,Ch. V.;Redkin,A. N.,Vysokochist. Veshchestva,(1988) N 1,48-54
    标题:Smirnov,V. A.;Kopetskij,Ch. V.;Redkin,A. N.,Vysokochist. Veshchestva,(1988) N 1,48-54

    专利信息


    专利号:US-2011229397-A1
    优先权日:2008-10-03
    标 题:Process and apparatus for continuous flow synthesis of nanocrystals
    发明人:BARTEL JOSEPH; MCKENZIE LALLIE
    权利人:LIFE TECHNOLOGIES CORP
    摘要:Novel reactor, systems and methods of preparing nanocrystals in a continuous flow-through process are provided. The novel reactor is highly configurable and can be modified to achieve desired reaction times of a flow through mixture. The reactor is designed to provide uniform, efficient heating of the reaction mixture.

    专利号:US-7485741-B2
    优先权日:2002-12-02
    标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds
    发明人:BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE
    权利人:RHODIA POLYAMIDE INTERMEDIATES
    摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.

    专利号:US-9759727-B2
    优先权日:2010-03-23
    标 题:Ligands for semiconductor nanocrystals
    发明人:HAN HEE-SUN; LIU WENHAO; BAWENDI MOUNGI G
    权利人:HAN HEE-SUN; LIU WENHAO; BAWENDI MOUNGI G; MASSACHUSETTS INST TECHNOLOGY
    摘要:In this invention, polyimidazole ligands (PILs) incorporating pendant imidazole moieties for nanocrystal binding and either sulfonatebetaine, carboxybetaine, or phosphocholinebetaine moieties for water-solubilization have been developed. Greatly enhanced stability of nanocrystals (both over time and in wide pH range) was achieved by incorporating multi-dentate imidazole moieties which provide strong coordination of the ligand to the nanocrystal surface and prevent aggregation of nanocrystals. Synthesis of betaine PILs was developed by modifying the synthesis of recently developed PEG containing poly imidazole ligands (PEG PILs). These nanocrystals are compact, water soluble, and biocompatible.

    专利号:US-10202546-B2
    优先权日:2010-03-23
    标 题:Ligands for semiconductor nanocrystals
    发明人:HAN HEE-SUN; LIU WENHAO; BAWENDI MOUNGI G
    权利人:MASSACHUSETTS INST TECHNOLOGY
    摘要:In this invention, polyimidazole ligands (PILs) incorporating pendant imidazole moieties for nanocrystal binding and either sulfonatebetaine, carboxybetaine, or phosphocholinebetaine moieties for water-solubilization have been developed. Greatly enhanced stability of nanocrystals (both over time and in wide pH range) was achieved by incorporating multi-dentate imidazole moieties which provide strong coordination of the ligand to the nanocrystal surface and prevent aggregation of nanocrystals. Synthesis of betaine PILs was developed by modifying the synthesis of recently developed PEG containing poly imidazole ligands (PEG PILs). These nanocrystals are compact, water soluble, and biocompatible.

    专利号:US-2017198217-A1
    优先权日:2015-09-04
    标题 :Synthesis of nanocrystals

    专利号:WO-2006067800-A1
    优先权日:2004-12-24
    标 题:Triorganoantimony compounds for pesticidal use
    发明人:CHANDRASHEKAR KRISHNAPPA; BEHL HARI MOHAN; KUMAR VISHAL; SIDHU OM PRAKASH; PUSHPANGADAN PALPU; RAO CHANDANA VENKATESWARA; SHUKLA SANJEEV KUMAR; RANJAN ASHOK; SAXENA ARVIND KUMAR; KANT RAVI; SINGHAL KIRAN; RAJ PREM
    权利人:COUNCIL SCIENT IND RES; CHANDRASHEKAR KRISHNAPPA; BEHL HARI MOHAN; KUMAR VISHAL; SIDHU OM PRAKASH; PUSHPANGADAN PALPU; RAO CHANDANA VENKATESWARA; SHUKLA SANJEEV KUMAR; RANJAN ASHOK; SAXENA ARVIND KUMAR; KANT RAVI; SINGHAL KIRAN; RAJ PREM
    摘要:The invention concerns with synthesis of mixed triorganoantimony (III) compounds bearing halophenyl groups ('R2SbR1') , using metal turnings viz Lithium, Magnesium or Zinc in donor solvents with plurality of uses as microbiocides and insecticides for controlling undesirable micro organisms and pests in crop protection, protection of materials; household and veterinary pests apart from being cytotoxic.

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    合成参考文献


    摘要:Chand, K.; Umesh; Dorairaj, D. P.; Hsu, S. C. N., Science of Synthesis Knowledge Updates, (2021) 2, 294.
    摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(110), 1982
    摘要:Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*., 2(94), 1961
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