专利号:US-5936080-A 优先权日:1996-05-24 标题 :Compositions and methods for the synthesis of organophosphorus derivatives 发明人:STEC WOJCIECH J; WOZNIAK LUCYNA 权利人:GENTA INC; POLSKA AKADEMIA NAUK INSTYTUT 摘要:New organophosphorus mononucleoside derivatives, methods of their synthesis and methods for the synthesis of organophosphorus dinucleotide derivatives utilizing the organophosphorus mononucleosides are provided. Synthesized organophosphorus mononucleoside derivatives of the present invention are characterized by the formula; ##STR1## Organophosphorus dinucleoside derivatives prepared from the synthesis methods provided in the present invention are characterized by the formula; ##STR2##
专利号:EP-0828749-B1 优先权日:1995-05-26 标题 :Methods for the synthesis of organophosphorus derivatives 发明人:STEC WOJCIECH J; WOZNIAK LUCYNA; RILEY TIMOTHY 权利人:GENTA INC; POLSKA AKADEMIA NAUK INSTYTUT 摘要:New organophosphorus mononucleoside derivatives, method of their synthesis and methods for the synthesis of organophosphorus dinucleotide derivatives utilizing the organophosphorus mononucleoside derivatives are provided. Synthesized organophosphorus mononucleoside derivatives of the present invention are characterized by formula (1).
专利号:US-4465845-A 优先权日:1982-04-26 标题:High pressure synthesis of sulfur-selenium fulvalenes 发明人:OKAMOTO YOSHIYUKI; WOJCIECHOWSKI PIOTR S 权利人:KOPPERS CO INC 摘要:A process is disclosed for one-step preparation of sulfur-selenium fulvalenes by reaction of an acetylenic compound with carbon selenide sulfide or with a mixture of carbon diselenide and carbon disulfide under pressures of at least about 1,000 atmospheres. Fulvalene compounds made by the process are characterized in having at least one sulfur atom and at least one selenium atom in the ring structure of the fulvalene compound. Substituted diselenadithiafulvalenes made by this process are precursors to very pure diselenadithiafulvalene which is useful in preparing charge-transfer salts.
专利号:US-4402875-A 优先权日:1981-09-18 标 题 :Substituted teraselenafulvalenes and high pressure synthesis thereof 发明人:OKAMOTO YOSHIYUKI; WOJCIECHOWSKI PIOTR S 权利人:KOPPERS CO INC 摘要:A process is disclosed for one-step preparation of substituted tetraselenafulvalenes by reaction of carbon diselenide with acetylenic compounds under pressures of at least about 1,000 atmospheres. Substituted tetraselenafulvalenes made by this process are useful as precursors to very pure tetraselenafulvalene and are useful in forming complexes with certain inorganic anions to provide charge-transfer salts having very high electrical conductivity.
专利号:US-4246173-A 优先权日:1978-04-24 标题 :Process for preparing tetraselenofulvalenes, and conductive salts obtained therefrom 发明人:COWAN DWAINE O; BLOCH AARON N; BECHGAARD KLAUS 权利人:UNIV JOHNS HOPKINS 摘要:A multistep process for preparing tetraselenofulvalenes involving the synthesis of 1,3-diselenole-2-selones and -2-thiones from diselenocarbamates and α-haloketones followed by coupling of the selone or thione using a dechalkogenizing reagent. New highly conductive salts obtained by coupling certain tetraselenofulvalenes with acceptor compounds are also disclosed.
专利号:EP-1323727-A2 优先权日:1995-05-26 标题 :Composition and methods for the synthesis of organophosphorus derivatives