CAS: 36802-41-2; Bis(2-Methoxyphenyl)(Phenyl)Phosphine

该化合物是有机磷的化合物,其独特结构特征是磷原子与两个2-甲基苯基组和一个苯基组结合,这种化合物一般在室温时是一种固体,在有机溶剂中可以溶解,在各种化学应用中有用;其分子结构具有特定的电子和...

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methoxybenzene Dichlorophenylphosphine 2-bromoanisole chloro-diphenylphosphinerac-(2-methoxyphenyl)(phenyl)phosphine bis(2-methoxyphenyl)(phenyl) phosphine oxide P)-[2-(S)-(2-methoxymethylpyrrolidino)phenyl](2-methoxy-phenyl)(phenyl) phosphine oxide(RP)-[2-(S)-(2-methoxymethylpyrrolidino)phenyl](2-methoxy-phenyl)(phenyl) phosphine oxide P)-[2-(S)-(2-methoxymethylpyrrolidino)phenyl](2-methoxy-phenyl)(phenyl) phosphine oxide(SP)-[2-(S)-(2-methoxymethylpyrrolidino)phenyl](2-methoxy-phenyl)(phenyl) phosphine oxide

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    专利号:US-9834536-B2
    优先权日:2013-04-23
    标题:Method for producing catalyst for cyclic carbonate synthesis
    发明人:TAKAHASHI TOSHIKAZU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU; YAMAMOTO SHOUJI; NANIKI TAKASHI; FURUKAWA TAKURO
    权利人:AIST; MARUZEN PETROCHEM CO LTD
    摘要:A method for producing a heterogeneous catalyst for use of synthesizing cyclic carbonates by reacting an epoxide and carbon dioxide in the presence of the catalyst. A method for making a catalyst that includes forming a catalyst precursor then reacting the catalyst precursor with a tertiary phosphine.

    专利号:US-10029241-B2
    优先权日:2013-04-23
    标题:Method for producing catalyst for cyclic carbonate synthesis
    发明人:NANIKI TAKASHI; TAKAHASHI TOSHIKAZU; YASUDA HIROYUKI; YAMAMOTO SHOUJI
    权利人:MARUZEN PETROCHEM CO LTD; AIST
    摘要:A method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost is provided. The heterogeneous catalyst is used for the purpose of synthesizing a cyclic carbonate by reacting an epoxide and carbon dioxide. A catalyst obtained by this production method and a method for synthesizing a cyclic carbonate with use of this catalyst are also provided.

    专利号:US-5739373-A
    优先权日:1992-11-20
    标 题:Optically active phosphono analogs of succinates and synthesis thereof
    发明人:TALLEY JOHN J
    权利人:MONSANTO CO
    摘要:The present invention relates to catalytic asymmetric hydrogenation of phosphorus analogs of itaconic acid to synthesize novel optically active phosphono succinates.

    专利号:US-5159093-A
    优先权日:1990-10-01
    标题 :Iridium-optically active phosphine complex and process for producing optically active alcohols using the same
    发明人:TAKETOMI TAKANAO; AKUTAGAWA SUSUMU; KUMOBAYASHI HIDENORI; TAKAYA HIDEMASA; MASHIMA KAZUSHI
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:An iridium-optically active phosphine complex represented by formula (I): n n [H.sub.2 Ir(L.sup.1)(L.sup.2)]Y (I) n n wherein L 1 represents an optically active phosphine compound represented by formula (II): ##STR1## wherein Ar represents a phenyl group or a p- and/or m-lower alkyl-substituted phenyl group, or formula (III): ##STR2## L 2 represents a tertiary phosphine compound represented by formula (IV): ##STR3## wherein Z represents a lower alkoxy group or a di-lower alkylamino group; and A represents an integer of from 1 to 3; Y represents BF 4 , PF 6 , ClO 4 , or BPh 4 , wherein Ph represents a phenyl group, and a process for producing an optically active alcohol using the above complex as an enantioselective catalyst are disclosed. The complex exhibits excellent catalytic activity to give high enantioselective yields in enantioselective synthesis, particularly enantioselective hydrogenation.

    专利号:US-5210332-A
    优先权日:1990-10-01
    标题:Iridium-optically active phosphine complex and process for producing optically active alcohols using the same
    发明人:TAKETOMI TAKANAO; AKUTAGAWA SUSUMU; KUMOBAYASHI HIDENORI; TAKAYA HIDEMASA; MASHIMA KAZUSHI
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:An iridium-optically active phosphine complex represented by formula (I): n n [H.sub.2 Ir(L.sup.1)(L.sup.2)]Y (I) n n wherein L 1 represents an optically active phosphine compound represented by formula (II): ##STR1## wherein Ar represents a phenyl group or a p- and/or m-lower alkyl-substituted phenyl group, or formula (III): ##STR2## L 2 represents a tertiary phosphine compound represented by formula (IV): ##STR3## wherein Z represents a lower alkoxy group or a di-lower alkylamino group; and A represents an integer of from 1 to 3; Y represents BF 4 , PF 6 , ClO 4 , or BPh 4 , wherein Ph represents a phenyl group, n and a process for producing an optically active alcohol using the above complex as an enantioselective catalyst are disclosed. The complex exhibits excellent catalytic activity to give high enantioselective yields in enantioselective synthesis, particularly enantioselective hydrogenation.
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    双(邻甲氧基苯基)苯膦
    36802-41-2
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    合成参考文献


    摘要:Ramsden, C. A., Science of Synthesis, (2007) 31, 2047.
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