CAS: 355-68-0; 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorocyclohexane

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CAS号71-43-2 苯 | CAS号392-56-3 六氟苯 | CAS号2367-86-4 1H,2H-decafluor... | CAS号110-82-7 环己烷 | CAS号775-40-6 3,3,4,4,5,5,6,6... | CAS号653-37-2 五氟苯甲醛 | CAS号91-15-6 邻苯二甲腈 | CAS号626-17-5 间苯二甲腈 | CAS号91-22-5 喹啉 | CAS号327-54-8 1,2,4,5-四氟苯 | CAS号769-39-1 2,3,5,6-四氟苯酚 | CAS号652-18-6 2,3,5,6-四氟苯甲酸 | CAS号602-94-8 五氟苯甲酸

📜环己烷置于cobalt (Iii) Fluoride体系中,化学反应 3.0H,以100%的收率获得产物全氟环己胺
参考文献:在三氟化钴(iii)上氟化c 6烃时的骨架重排
标题:在三氟化钴(iii)上氟化c 6烃时的骨架重排
摘要:己烷,2-甲基戊烷,3-甲基戊烷,2,2-二甲基丁烷,2,3-二甲基丁烷,甲基环戊烷和环己烷在三氟化钴(iii)上的全氟化,在每种情况下,除了环己烷外,还会得到直链,支链的混合物和环状的c 6-碳氟化合物:骨架重排的程度(不包括环己烷)从大约 7%(甲基环戊烷)至96%(2,2-二甲基丁烷).提出了一种碳平衡机制,该机制无法进行平衡.
DOI:10.1039/p29910000445

专利信息

专利号:US-5446211-A
优先权日:1994-04-01
标 题 :Chlorination of difluoromethyl methyl ether
发明人：O'NEILL GERALD J; BULKA ROBERT J
权利人:HAMPSHIRE CHEMICAL CORP
摘要:The synthesis of fluorinated dimethyl ethers of the formula CF 2 HOCCl x F y H 3- (x+y) wherein x is 0, 1 or 2; y is 1, 2 or 3; and wherein (x+y) is 1, 2 or 3. The process involves chlorination of methyl difluoromethyl ether in the presence of a solvent to form a chlorinated reaction product of the formula CF 2 HOCH 3-z Cl z wherein z is 1, 2 or 3. The process may also be carried out in the presence of oxygen in order to inhibit the formation of CF 2 HOCCl 3 . The resulting compound(s) is then fluorinated with HF before or after separation, to give a fluorinated reaction product including the aforementioned fluorinated dimethyl ethers.

专利号:US-5026929-A
优先权日:1990-02-08
标题:Synthesis of highly fluorinated aromatic compounds
发明人：MARSELLA JOHN A; PEZ GUIDO P; COUGHLIN ANNE M
权利人:AIR PROD & CHEM
摘要:A process is disclosed for making a highly fluorinated aromatic compound by contacting a perfluorocycloalkane, such as perfluorodecahydronaphthalene, with a complex of a metal from Groups IA and IIA of the Periodic Table and an organic electron acceptor. The reaction is carried out in an organic solvent and under reducing conditions which are relatively moderate. Best results are obtained using a perfluorocycloalkane having 2-4 condensed rings and a complex of either sodium or lithium and benzophenone thereby making a perfluorinated condensed ring aromatic compound such as perfluoronaphthalene or perfluorophenanthrene.

专利号:US-6849701-B2
优先权日:2001-03-02
标 题:Droplet polymerization method for synthesis of molecularly imprinted polymers
发明人：NORTON TUCKER
权利人:DU PONT
摘要:A droplet polymerization process is provided to create efficacious molecularly imprinted polymers (MIPs). Such imprinted polymers have increased surface area for adsorptive or catalytic reactions. This method provides for monomer-template interactions in the absence of a suspending medium, thereby permitting formation of MIPs with increased template selectivity and substantial processing advantages. The process is particularly useful for separating isoflavones from soy whey.

专利号:WO-9925385-A1
优先权日:1997-11-17
标 题:A method of increasing nucleic acid synthesis with ultrasound
发明人：UNGER EVAN C; MCCREERY THOMAS; SADEWASSER DAVID
权利人:IMARX PHARMACEUTICAL CORP
摘要:The present invention is directed to a method of increasing nucleic acid synthesis in a cell comprising administering to the cell a therapeutically effective amount of ultrasound for a therapeutically effective time such that said administration of said ultrasound results in said increased nucleic acid synthesis. The nucleic acid sequence may comprise an endogenous sequence or an exogenous sequence.

专利号:US-2002198349-A1
优先权日:2001-03-02
标 题:Droplet polymerization method for synthesis of molecularly imprinted polymers

专利号:US-2002001821-A1
优先权日:1994-02-10
标 题:Methods for direct synthesis of compounds having complementary structure to a desired molecular entity and use thereof