CAS: 34143-74-3; 1H,1H,2H,2H-Perfluorodecanethiol

该化合物是一个氟化有机化合物,具有长碳链和多种氟化碳替代物的特征.该化合物在碳链的一端具有硫醇功能组(-SH),具有独特的反应力和特性.许多氟原子的存在助长了其疏水性和脂性,使其对水和油具有很强的抗药性.这一特性经常被地表处理和涂层等应用所利用,而地面处理和涂层的特性是低地表能和非粘液态的特性.此外,硫醇组可以参与各种化学反应,包括硫醇反应和金属协调,增强其在材料科学和有机合成中的效用.由于碳-氟联结的强度很大,因此其稳定性一般很高,尽管它可能敏感于强力氧化剂.

结构式图片

相似化合物

34451-26-8 200112-75-0 2043-53-0

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号2043-53-0 全氟辛基乙基碘 | CAS号42977-21-9 bis(3,3,4,4,5,5... | CAS号125640-21-3 1h,1h,2h,2h- pe... | CAS号507-63-1 全氟辛基碘烷 | CAS号36880-07-6 3-(3,3,4,4,5,5,... | CAS号36880-12-3 2-((3,3,4,4,5,5... | CAS号42977-21-9 bis(3,3,4,4,5,5...

合成工艺路线路线简述

  • 合成目标产物 1H,1H,2H,2H-Perfluorodecanethiol 主要起始原料 1-Iodo-1H,1H,2H,2H-Perfluorodecane
  • (文献来源)合成步骤主要原料 1-Iodo-1H,1H,2H,2H-Perfluorodecane
1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷置于硫脲体系中,用 乙醇 用作溶剂,化学反应 72.0H,以52%的收率获得3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
参考文献:超临界co(2)中的分子篮.
标题:超临界co(2)中的分子篮.
摘要:杯芳烃是合成的大环化合物,被称为"分子篮",因为它们具有高离子选择性,并与许多重要的离子客体形成包合物.在我们的初步工作中,在下部边缘未官能化的六聚和四聚叔丁基杯芳烃显示在二醇柱上使用甲醇/氯仿修饰的co(2)作为超临界流体色谱是可分离的.研究了这些杯芳烃的容量因子随改性剂组成的变化.但是,这些分子篮在未改性的超临界co(2)中的溶解度通过上缘的氟化作用得以增强.例如,当通过与七氟癸烷硫醇的硫醇-烯加成反应将对烯丙基杯[4]芳烃衍生化时,Cf(3)(cf(2))(7)(ch(2))(2)sh的溶解度为> 0.在60摄氏度和200个大气压下对对十七氟癸基硫代-正丙基杯[4]芳烃进行了超临界co(2)中12摩尔l(-)(1)的测量.然而,随后的较低边缘官能化以形成四氢氧肟酸酯衍生物,同时降低了溶解度,使得可以研究氟化杯[4]芳烃配体的超临界流体萃取fe(III)随温度和压力的变化,并使用uv /
Doi:10.1021/ac960850Q

海关参考信息

专利信息


专利号:US-2021369846-A1
优先权日:2018-10-26
标 题 :New Ammonium Salts Of Fluorinated Organic Acids, Method Of Their Synthesis and Application
发明人:STEFANEK AGATA; CIACH TOMASZ; LECZYCKAWILK KATARZYNA; CZARNOCKA-SNIADALA SYLWIA; GRAFSTEIN JOANNA; DRESLER MAGDALENA; NOWAK ALEKSANDRA; WGLINKSKI JAKUB
权利人:NANOSANGUIS
摘要:The exemplary arrangements relate to ammonium salts of partially fluorinated organic acids. The exemplary arrangements also relate to methods of synthesis of the ammonium salts of partially fluorinated organic acids. The exemplary arrangements also relate to methods of use of the ammonium salts of partially fluorinated organic acids to produce stabilizing emulsions of the oil-in-water and/or water-in-oil type. The exemplary arrangements also relate to methods of use and applications of the ammonium salts of partially fluorinated organic acids, for example use as stabilizing agents in blood substitute preparations.

专利号:US-12397530-B2
优先权日:2019-02-15
标 题:Patterned, dendrimeric substrate surfaces and production and use thereof
发明人:BENZ MAXIMILIAN; LEVKIN PAVEL A
权利人:KARLSRUHER INST TECHNOLOGIE
摘要:The present invention relates to a patterned substrate comprising first regions having first dendrimer structures and second regions having second dendrimer structures on a surface of the substrate, as well as a to method for manufacturing a patterned substrate and the use of a patterned substrate for the chemical synthesis of a chemical synthesis product, as a characterizing platform and/or as a platform for cell treatment and/or cell cultivation.

专利号:WO-2023113033-A1
优先权日:2021-12-16
标题 :Gas diffusion electrode
发明人:KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
权利人:NISSAN CHEMICAL CORP
摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.

专利号:US-7576245-B2
优先权日:2002-07-11
标题:Fluorous tagging and scavenging reactants and methods of synthesis and use thereof
发明人:ZHANG WEI; LUO ZHIYONG
权利人:FLUOROUS TECHNOLOGIES INC
摘要:The present invention includes methods and compositions for increasing the fluorous nature of an organic compound by reacting it with at least one fluorous compound to produce a fluorous tagged organic compound. The increased fluorous nature of the fluorous tagged organic compound can then be utilized to separate the fluorous organic compound from untagged reagents, reactants, catalysts and/or products derived therefrom. The resultant fluorous tagged organic compound can be subjected to subsequent chemical transformations, wherein the fluorous nature of the tagged compound is utilized to increase the ease of separation of the fluorous tagged organic compound from untagged reagents, reactants, catalysts and/or products derived therefrom, after each chemical transformation. The chemical transformations result in a second fluorous tagged organic compound wherein the fluorous nature of the second fluorous tagged organic compound can then be reduced by removing the fluorous group therefrom, thereby producing a second organic compound that may be employed as a pharmaceutical compound or intermediate, or a combinatorial library component.

专利号:US-9751071-B2
优先权日:2013-12-27
标题:Continuous microwave-assisted segmented flow reactor for high-quality nanocrystal synthesis
发明人:KIM KI-JOONG; HOSTETLER ERIC BRADLEY; HERMAN GREGORY SCOTT; PETERSON DANIEL ALAN; CHANG CHIH-HUNG; FLYNN BRENDAN THOMAS; PAUL BRIAN KEVIN; OLEKSAK RICHARD PAUL
权利人:State of Oregon acting by and through the State Board of Higher Education on behalf of OSU; STATE OF OREGON ACTING BY AND THROUGH THE STATE BOARD OF HIGHER EDUCATION ON BEHALF OF OREGON STATE
摘要:Systems and methods for synthesizing high-quality nanocrystals via segmented, continuous flow microwave-assisted reactor were developed.

专利号:US-4158672-A
优先权日:1976-01-26
标题 :Polyfluoroalkylthio alcohols, esters and useful compositions therefrom
发明人:DEAR ROBERT E A; BRACE NEAL O
权利人:CIBA GEIGY CORP
摘要:Polyfluoroalkylthio alcohols and esters thereof are disclosed with utility as intermediates for the synthesis of fluorochemicals with low free surface energies having oil and water repellent properties. The novel alcohols and esters are obtained by a free radical catalyzed addition of polyfluoroalkylthiols to acetylenic alcohols or esters thereof. The alcohols are employed in preparation of fluorine containing polyurethanes which are useful as finishes to provide oil and water repellency to textiles and as additives to plastics to provide mold release and other desirable properties.
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全氟己基乙基硫醇
Perfluorohexyl ethyl mercaptan
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250kg/drum
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主要参考文献

[参考文献]: Michael E Kurczy, Et Al. Comprehensive Bioimaging With Fluorinated Nanoparticles Using Breathable Liquids. Nat Commun. 2015 Jan 20:6:5998.

合成参考文献


摘要:von Angerer, S., Science of Synthesis Knowledge Updates, (2011) 1, 403.
摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775
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