CAS: 334-56-5; 1-Fluorodecane

相似化合物

463-11-6 1511-79-1 1120-21-4

上下游产品

CAS号112-30-1 正癸醇 | CAS号5509-08-0 decyl 4-methylb... | CAS号2050-77-3 1-碘癸烷 | CAS号112-29-8 溴代正癸烷 | CAS号1002-69-3 1-氯癸烷 | CAS号41233-29-8 decyl methanesu... | CAS号110-53-2 1-溴戊烷 | CAS号2050-77-3 1-碘癸烷 | CAS号64154-08-1 2-iododecane | CAS号768-93-4 亚硫酸氢钠穿心莲内酯 | CAS号112-40-3 正十二烷 | CAS号111-65-9 正辛烷 | CAS号111-84-2 正壬烷 | CAS号124-18-5 正癸烷 | CAS号104-72-3 癸基苯 | CAS号4537-13-7 decan-2-ylbenzene | CAS号4537-11-5 decan-5-ylbenzene

📜癸醇置于iodine Pentafluoride,Triethylamine Tris(Hydrogen Fluoride)体系中,用 正庚烷 用作溶剂,化学反应 48.0H,以32%的收率获得1-氟癸
参考文献:Novel Fluorination Reagent: If5/ Et3N-3Hf
标题:Novel Fluorination Reagent: If5/ Et3N-3Hf
摘要:在et3N-3Hf体系中,发现if5是一种稳定,无危险,易于操作且价格低廉的试剂,能够在温和条件下对有机化合物进行有效且选择性的氟化反应.
Doi:10.1246/cl.2001.222

专利信息

专利号:US-5541273-A
优先权日:1993-11-12
标 题 :Method for preparing poly(vinyl trifluoroacetate) and poly(vinyl trifluoroacetate/vinyl ester) in the absence of chlorofluorocarbon solvent
发明人：EIAN GILBERT L
权利人:MINNESOTA MINING & MFG
摘要:A method for the production of poly(vinyl trifluoroacetate) and copolymers thereof with vinyl esters is described. Poly(vinyl trifluoroacetate) (PVTFA) is obtained in essentially quantitative yield under mild conditions by using non-chlorofluorocarbon solvents comprising siloxanes or perfluorinated fluid. Hexamethyl disiloxane is a particularly useful example of such solvents. Synthesis of syndiotactic PVTFA on a commercial scale without the use of environmentally-harmful solvents is made possible by the invention, which provides a convenient commercial route to syndiotactic polyvinyl alcohol.

专利号:US-9790377-B2
优先权日:2011-09-21
标题:Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane (“F-POSSâ€?)
发明人：HADDAD TIMOTHY S; MABRY JOSEPH M; RAMIREZ SEAN
权利人:US AIR FORCE
摘要:A method of manufacturing a fluorinated polyhedral oligomeric silsesquioxane. The method for manufacture includes opening a single edge of a closed-cage F-POSS and bridging the opened, single edge with a sulfate group. The sulfate group is converted to a disilanol, which is then reacted with a functional dichlorosilane having an organic functional group comprising at least three carbon atoms.

专利号:US-2011009612-A1
优先权日:2007-06-22
标题 :Automated solution-phase iterative synthesis
发明人：POHL NICOLA LUCIA; PARK GISUN
权利人:UNIV IOWA STATE RES FOUND INC
摘要:The first method for iterative solution-phase biomolecule synthesis is described. The method requires only 3 or fewer equivalents of building block at each coupling cycle, and incorporates a FSPE step at the end of each coupling/deprotection sequence to eliminate most byproducts.

专利号:US-2020179977-A1
优先权日:2011-09-21
标 题:Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane ('f-poss')

专利号:US-10550271-B2
优先权日:2011-09-21
标题 :Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane (“F-POSSâ€?)

专利号:US-7307177-B2
优先权日:2004-12-17
标题:Metallocene complexes, their synthesis and use in catalyst systems for olefin polymerization
发明人：HUANG LEGAL REPRESENTATIVE JIL; CANICH JO ANN M; COKER CATALINA L
权利人:EXXONMOBIL CHEM PATENTS INC
摘要:A metallocene complex is represented by the the formulan n(C p R 5 ) n MX k n nwhere C p (each occurrence) is a cyclopentadienyl group; each of the five R substituents on the or each cyclopentadienyl group is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and SiR′ 2 NR″ 2 where each of the two R′ substituents is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R′ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and each of the two R″ substituents is independently selected from C 2 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R″ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure; n is 1 or 2; M is a metal of valence m from Groups 4 to 11 of the Periodic Table of Elements, k is equal to m minus n and the or each X substituent is a univalent anionic ligand, or two X substituents are joined and bound to the metal atom to form a metallocycle ring, or two X substituents are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand, provided that at least one R substituent on the or one cyclopentadienyl group is SiR′ 2 NR″ 2 , provided that at least one R substituent on at least one C p is SiR′ 2 NR″ 2 and provided that one or the C p may be bridged by a bridging group to another C p group, or a heteroatom containing group, where the bridging group replaces one R group on the C p group(s) or a hydrogen on a heteratom containing group.