CAS: 15196-73-3; 15-(Tert-Butyl)-2,3,5,6,8,9,11,12-Octahydrobenzo[b][1,4,7,10,13]Pentaoxacyclopentadecine

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

1,11-dichloro-3,6,9-trioxaundecane 4-tert-Butylcatechol 2,3,5,6,8,9,11,12-°Ctahydro-1,4,7,10,13-benzopentaoxacyclopentadecin tert-butyl alcoholtert-butyl alcohol

合成工艺路线路线简述

    📜苯并-15-冠醚-5,叔丁醇置于ppa体系中,化学反应 5.0H,以95%的收率获得4-叔丁基苯并-15-冠-5
    参考文献:某些芳族冠醚衍生物的合成及其离子选择电极性能
    标题:某些芳族冠醚衍生物的合成及其离子选择电极性能
    摘要:已经报道了苯并-15-冠-5,苯并18-冠-6和萘15-冠-5的烷基,硝基和卤代衍生物的合成.还制备了一些新颖的酯型双(冠醚).在pvc膜离子选择电极中,某些化合物已被表征为电活性物质.
    Doi:10.1016/s0040-4020(01)82027-5

    海关参考信息

    专利信息


    专利号:CN-104470547-B
    优先权日:2012-05-24
    标题 :Utilize the method for tubular article synthesis of radiopharmaceuticals

    专利号:US-9550704-B2
    优先权日:2012-05-24
    标 题 :Method for synthesizing radiopharmaceuticals using a cartridge
    发明人:CHI DAE YOON; LEE BYOUNG SE; LEE JAE HAK; CHU SO YOUNG; JUNG WOON JUNG
    权利人:FUTURECHEM CO LTD
    摘要:The present invention relates to a method for synthesizing a radiopharmaceutical using a cartridge, which makes it possible to carry out several steps of reaction required for synthesizing a radiopharmaceutical in the cartridge filled with a polymer. A method for synthesizing a radiopharmaceutical according to the present invention enables each step's reaction to be carried out with the solution confined in the cartridge so as not to flow out, thus being simplified compared to the conventional methods for synthesizing radiopharmaceuticals, and expediting the synthesis thereof.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Synthesis Of 3′- Or 4′-Alkenylbenzocrown Ethers
    作者:Kiyoshi Kikukawa,Shinji Takamura,Hiroshi Hirayama,Hiroshi Namiki,Fumio Wada,Tsutomu Matsuda |发布日期:1980.5.5
    摘要:Palladium(0) Catalyzed Alkenylation Of 3′- Or 4′-Iodo- (Or Bromo-) Benzocrown Ethers Are Found To Be A Convenient Procedure For The Introduction Of Alkenyl Groups (-Ch=ch-R; R=ph, Cooet And Cooh). Iodination At 3′-Position Of Benzocrown Ethers Could Be Achieved In Good Yield By The Use Of 4′-T-Butyl Derivatives.

    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知