2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-Heptan-1-Ol; Compound With Triethyl-Amine置于氯化亚砜体系中,用 氯仿 用作溶剂,化学反应生成甲基丙烯酸十二氟庚酯
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摘要:The Interaction Of Polyfluorinated Alcohols With Triethylamine And The Kinetics Of The Reaction Of The Resulting Triethylamine Complexes With Thionyl Chloride Were Studied,The Mechanism Of Formation Of Polyfluoroalkyl Chlorosulfites Was Considered,And The Optimal Reaction Conditions Were Found. The Alkylating Power Of Polyfluoroalkyl Chlorosulfites Was Studied In Reactions With Alkali Metal Halides (To Obtain Polyfluorohaloalkanes),In Synthesis Of Acrylic And Methacrylic Acid Esters,And In Synthesis Of Polyfluoroalkyl Ethers (With Polyfluoroalkyl 1-Adamantyl Ethers As Example).
Doi:10.1023/a:1020788902312