CAS: 13450-92-5; Germanium(Iv) Bromide

该化合物是一种高纯度无机化合物,主要用于半导体制造,化学蒸汽沉降(CVD),并用作基于基材料的前体,其主要优点包括高热稳定性,连续反应性,与精密沉降工艺的兼容性,使之适合先进的电子和光电子应用;该化合物在有机溶剂中表现出极好的溶解性,便于对含有的胶片或纳米结构进行有控制的合成;GeBr4具有明确界定的分子结构,确保研究和工业环境中产生可复制的结果;建议在惰性条件下进行适当的处理,因为其湿度敏感;在不同纯度下,它符合专门化学和材料科学应用的严格要求.

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CAS号7440-56-4 锗粉 | CAS号7726-95-6 溴素 | CAS号10038-98-9 氯化锗 | CAS号10035-10-6 氢溴酸 | CAS号7789-33-5 一溴化碘 | CAS号74-95-3 二溴甲烷 | CAS号75-62-7 三氯溴甲烷 | CAS号75-25-2 三溴甲烷 | CAS号106052-17-9 methyl 2-methyl... | CAS号35369-95-0 tribromo-(2,3,4... | CAS号10177-65-8 dibromo-bis(2,3... | CAS号3005-32-1 三苯基溴化锗 | CAS号1074-28-8 phenyltribromog... | CAS号1080-42-8 Germane,dibromo... | CAS号4713-59-1 dibromo(dipheny... | CAS号7726-95-6 溴素 | CAS号3124-22-9 dibromo(dibutyl...

合成工艺路线路线简述

    📜四氯化锗置于氢溴酸体系中,用 氢溴酸 用作溶剂,化学反应生成溴化锗
    参考文献:Microwave-Assisted Lewis Acid Catalysis: Application To The Synthesis Of Alkyl-Or Arylhalogermanes
    标题:Microwave-Assisted Lewis Acid Catalysis: Application To The Synthesis Of Alkyl-Or Arylhalogermanes
    摘要:Under Microwave Irradiation,Alkyl-Or Arylhalogermanes Rngex4,(R = Et,Bu,Ph; X = Cl,Br) Are Obtained By Redistribution Reactions Of R4Ge With Gex4. These Experimental Conditions Permit The Synthesis Of Such Compounds In Good Yield In A Few Minutes At Atmospheric Pressure. The Direct Friedel-Crafts Germylation Of Benzene And Toluene By Germanium Tetrachloride Also Has Been Performed,But Yields Were Low.
    Doi:10.1021/om00018A050

    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-4565896-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
    发明人:KNIFTON JOHN F; DURANLEAU ROGER G
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

    专利号:US-4609768-A
    优先权日:1984-10-22
    标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
    发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

    专利号:US-4568780-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.

    专利号:US-2024166514-A1
    优先权日:2022-11-21
    标题:Rapid synthesis of a sulfide-based solid electrolyte
    发明人:FRANCISCO BRIAN E; OBERWETTER SAMUEL
    权利人:SOLID POWER OPERATING INC
    摘要:Provided herein are methods for synthesizing sulfide-based solid electrolytes, including those with an Argyrodite phase. The methods generally comprise mixing electrolyte precursors in a blend of solvents comprising a catalytic solvent and a spectator solvent.

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    合成参考文献


    摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#02624
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